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    • 2. 发明公开
    • BIS (FLUORINE-CONTAINING PHTHALIC ANHYDRIDE) AND METHOD FOR PRODUCTION THEREOF
    • BIS(氟维他命PHILALISÄUREANHYDRID)UND VERFAHREN ZU DESSEN HERSTELLUNG
    • EP1640370A1
    • 2006-03-29
    • EP04746298.1
    • 2004-06-17
    • NIPPON SHOKUBAI CO., LTD.
    • MASUDA, GoOKUMURA, YasunoriNISHIMAE, ShinjiNARAYA, Toshihiro
    • C07D307/89C08G73/10C08L79/08
    • C07C253/30C07D307/89C07D407/12C08G73/1039C07C255/54
    • It is an object of the present invention to provide fluorinated bis(phthalic anhydride) which has less coloration and higher solubility in comparison with conventional compounds, and a method for producing the same. Further, it is also an object of the present invention to provide a method for producing a fluorinated bis(phthalonitrile) compound, which is an intermediate raw material compound of the method for producing the fluorinated bis(phthalic anhydride), and a polyamic acid and a polyimide, which are produced from the fluorinated bis(phthalic anhydride). A fluorinated bis(phthalic anhydride) of the present invention is the fluorinated bis(phthalic anhydride) represented by the following formula (I 1 ), wherein its specific surface area is 3.0 m 2 /g or larger. It is also characterized in that its molar absorption coefficient is 0.6 L/mol-cm or less at a wavelength of 360 nm.

      [wherein, m and n independently represent integers of 1 to 3, and Z 1 represents a single bond group or a bivalent organic group.]
    • 本发明的目的是提供与常规化合物相比具有较少着色度和较高溶解度的氟化双(邻苯二甲酸酐)及其制备方法。 此外,本发明的另一个目的是提供一种制备氟化双(邻苯二甲腈)化合物的方法,该化合物是制备氟化双(邻苯二甲酸酐)的方法的中间体原料化合物,以及聚酰胺酸和 由氟化双(邻苯二甲酸酐)制备的聚酰亚胺。 本发明的氟化双(邻苯二甲酸酐)是由下式(I 1)表示的氟化双(邻苯二甲酸酐),其比表面积为3.0m 2 / g以上。 其特征还在于其波长360nm下的摩尔吸光系数为0.6L / mol-cm以下。 [其中,m和n独立地表示1〜3的整数,Z 1表示单键或2价的有机基。