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    • 1. 发明公开
    • Alloy sheet for shadow mask and method for manufacturing thereof
    • LegistungfürSchattenmaske und Verfahren zu dessen Herstellung
    • EP0739992A1
    • 1996-10-30
    • EP96101338.0
    • 1993-12-15
    • NKK CORPORATION
    • Inoue, TadashiTsuru, KiyoshiHiasa, Michihito
    • C22C38/08C21D8/02
    • H01J9/142C21D8/0205C21D8/0236C21D8/0263C21D8/0268C21D8/0273C22C38/08H01J2229/0733
    • An alloy sheet for making a shadow mask consisting essentially of 34 to 38 wt.% Ni, 0.1 wt.% or less Si, 0.003 wt.% or less B, 0.003 wt.% or less O, less than 0.002 wt.% N, 0.05 to 3 wt.% Cr and the balance being Fe and inevitable impurities;
         said alloy sheet after annealing before press-forming having 0.2% proof stress of 27.5 kgf/mm 2 or less; and
         a gathering degree of {211} plane on a surface of said alloy sheet being 16% or less.
      A method for manufacturing an alloy sheet for shadow mask comprising the steps of:

      (a) preparing a hot-rolled sheet containing Fe, Ni and Cr;
      (b) annealing said hot-rolled sheet in a temperature range of 910 to 990°C;
      (c) cold-rolling said annealed hot-rolled sheet to produce a cold-rolled sheet:
      (d) a final recrystallization annealing step of annealing said cold-rolled sheet subjected to the cold-rolling;
      (e) a finish cold-rolling step of cold-rolling the cold-rolled sheet subjected to the final recrystallization annealing at the cold-rolling reduction ratio in response to an average austenite grain size D (µm) yieleded by the final recrystallization annealing, the cold-rolling reduction ratio R (%) satisfying the equations below; 16 ≦ R≦75, 6.38D-133.9 ≦ R ≦ 6.38D-51.0
      (f) a stress relief annealing step of annealing the cold-rolled sheet subjected to the finish cold rolling;
      (g) a softening annealing step of annealing said cold-rolled sheet subjected to the finish cold-rolling in a temperature range of 700 to less than 800 °C for 0.5 to less than 60 min. before press-forming and on conditions satisfying the equation below; T ≧ -48.1 logt + 785,    where T( °C) is the temperature and t (min.) is the time of the annealing.
    • 用于制造基本上由34至38重量%的Ni,0.1重量%或更少的Si,0.003重量%或更少的B,0.003重量%或更少的O,小于0.002重量%的N组成的荫罩的合金薄片 ,0.05〜3重量%的Cr,余量为Fe和不可避免的杂质; 所述合金板在压制成形之后的退火后具有27.5kgf / mm 2以下的0.2%的有限应力; 并且在所述合金板的表面上的聚集度为ä211ü平面为16%以下。 一种荫罩用合金薄板的制造方法,其特征在于,包括:(a)制备含有Fe,Ni,Cr的热轧板; (b)在910〜990℃的温度范围内退火所述热轧板; (c)冷轧所述退火的热轧板以制造冷轧板;(d)对经过冷轧的冷轧板退火的最终再结晶退火步骤; (e)根据通过最终再结晶退火得到的平均奥氏体晶粒尺寸D(μm),以冷轧压下率冷轧经过最终再结晶退火的冷轧板的精轧冷轧工序 ,满足以下等式的冷轧压下率R(%) (f)对经过精冷轧的冷轧板退火的应力消除退火工序; (g)软化退火工序,在700〜800℃的温度范围内对经过精冷轧的冷轧板进行0.5〜60分钟的退火。 在压制成形之前和满足以下等式的条件下进行。 其中T(℃)为温度,t(min。)为退火时间。