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1. 发明公开

EP0475351A1 Iron-antimony-molybdenum containing oxide catalyst composition and process for preparing the same 失效
标题翻译：催化铁 - 锑 - 钼组合物和用于制备方法相同的方法。
公开(公告)号：EP0475351A1
公开(公告)日：1992-03-18
申请号：EP91115276.7
申请日：1991-09-10
申请人： NITTO CHEMICAL INDUSTRY CO., LTD.
发明人： Sasaki, Yutaka, c/o Nitto Chem.Ind.Co.,Ltd. , Yamamoto, Hiroshi, c/o Nitto Chem.Ind.Co.,Ltd. , Mizutani, Koichi, c/o Nitto Chem.Ind.Co.,Ltd. , Moriya, Kiyoshi, c/o Nitto Chem.Ind.Co.,Ltd. , Mori, Kunio, c/o Nitto Chem.Ind.Co.,Ltd.
IPC分类号： B01J23/88 , B01J27/19 , B01J27/192
CPC分类号： B01J23/8872 , B01J23/881 , B01J23/887 , B01J23/8876 , B01J27/192 , B01J35/0006 , C01C3/0216 , C01C3/0241
摘要： An iron-antimony-molybdenum-containing oxide catalyst composition for oxidation reactions, comprising a crystalline iron antimonate having a crystallite size of 100 A or more, said catalyst being represented by the following empirical formula:

wherein L represents at least one element selected from the group consisting of Bi and Te; M represents at least one element selected from the group consisting of Cu, Mg, Zn, La, Ce, Al, Cr, Mn, Co, Ni and Sn; N represents at least one element selected from the group consisting of Be, Ca, Sr, Ba, Y, Pr, Nd, Th, U, Ti, Zr, Hf, Nb, Ta, Re, Ru, Os, Rh, lr, Pd, Pt, Ag, Au, Cd, Al, Ga, In, Ge and Pb; Q represents at least one element selected from the group consisting of V and W; R represents at least one element selected from the group consisting of Li, Na, Rb, Cs and TI; T represents at least one element selected from the group consisting of B, P, As and Se; a, b, c, d, e, m, n, q, r, t and x each is an atomic ratio, wherein when a is 10, b is 5 to 60, c is 5 to 30, d is 0.01 to 10, e is 0.01 to 5, m is 0 to 30, n is 0 to 10, q is 0 to 5, r is 0 to 3, t is 0 to 5, and x is a number of oxygen atoms as determined corresponding to the oxides formed by combining the above mentioned components.
摘要翻译：一种用于氧化反应的氧化催化剂组合物，其包含具有100埃或更大，所述催化剂被代表由以下经验式的微晶尺寸的结晶锑酸铁的含铁锑 - 钼 - ：FeaSbbMocLdKeMmNnQqRrTtOx worin大号darstellt至少选自Bi和Te中选择的一种元素; 选自铜，镁，锌，镧，铈，铝，铬，锰，钴，镍和锡的选择的M darstellt的至少一种元素; Ñdarstellt选自铍，钙，锶，钡，Y，镨，钕，钍，铀，钛，锆，铪，铌，钽中，Re，钌，锇，铑，铱中选择的至少一种元素，钯，铂，银，金，镉，铝，镓，铟，锗和铅; 选自V和W中选择的Q darstellt的至少一种元素; 选自锂，钠，铷，铯和铊的选择的R darstellt的至少一种元素; Ťdarstellt选自B的选择的至少一种元素，P，As和Se; A，B，C，D，E，M，N，Q，R，T和X各自的原子比，worin当a为10，b为5至60，c是5〜30，d为0时01分至10 e是0时01分至5，m是0〜30，n为0至10，q为0至5，r为0至3，t是0至5，并且x是一个数字氧原子的确定性开采对应于形成的氧化物通过组合上述部件。

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