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    • 1. 发明公开
    • Process for producing quality-improved water-absorbent polymers and products
    • 生产质量改进的吸水聚合物和产品的方法
    • EP0386897A3
    • 1991-07-03
    • EP90301619.4
    • 1990-02-15
    • NIPPON SHOKUBAI CO., LTD.
    • Harada, NobuyukiOkuno, ToshihiroShimomura, Tadao
    • C08J3/03C08F6/00
    • C08J3/03A61L15/60C08J2300/10
    • This invention relates to a process for producing a quality-improved water-absorbent polymer in which the aqueous liquid ( I ), which is obtained by mixing in an aqueous medium at least one kind of a water-soluble salt ( A ) selected from a group of halogenated compounds, sulfates, acetates, and nitrates, which are derived from at least one kind of a polyvalent metal selected from a group of aluminum, calcium, and magnesium, with at least one kind of a water-soluble salt ( B ) selected from a group of monovalent metal salts and ammonium salts, which are derived from at least one kind of an oxyacid selected from a group of sulfurous acid and thiosulfuric acid, is mixed with a water-absorbent polymer ( II ) in a proportion of that the water-soluble salt of the polyvalent metal ( A ) is in a range of 0.1 ∼ 10 parts by weight against 100 parts by weight of the water-absorbent polymer ( II ) and the water-soluble salt of the oxyacid ( B ) is in a range of 0.­1 ∼ 10 parts by weight against 100 parts by weight of the water-absorbent polymer ( II ). The mixture which is obtained by mixing the aqueous liquid ( I ) with the water-­absorbent polymer ( II ) has relatively-improved capacities in the fluidity and the amount of residual monomers. This invention displays a more sufficient effect by compulsorily bringing the mixture into contact with an oxygen-containing gas.
    • 3. 发明公开
    • Process for producing quality-improved water-absorbent polymers and products
    • 一种用于生产改进的质量的吸水性聚合物和得到的产物的过程。
    • EP0386897A2
    • 1990-09-12
    • EP90301619.4
    • 1990-02-15
    • NIPPON SHOKUBAI CO., LTD.
    • Harada, NobuyukiOkuno, ToshihiroShimomura, Tadao
    • C08J3/03C08F6/00
    • C08J3/03A61L15/60C08J2300/10
    • This invention relates to a process for producing a quality-improved water-absorbent polymer in which the aqueous liquid ( I ), which is obtained by mixing in an aqueous medium at least one kind of a water-soluble salt ( A ) selected from a group of halogenated compounds, sulfates, acetates, and nitrates, which are derived from at least one kind of a polyvalent metal selected from a group of aluminum, calcium, and magnesium, with at least one kind of a water-soluble salt ( B ) selected from a group of monovalent metal salts and ammonium salts, which are derived from at least one kind of an oxyacid selected from a group of sulfurous acid and thiosulfuric acid, is mixed with a water-absorbent polymer ( II ) in a proportion of that the water-soluble salt of the polyvalent metal ( A ) is in a range of 0.1 ∼ 10 parts by weight against 100 parts by weight of the water-absorbent polymer ( II ) and the water-soluble salt of the oxyacid ( B ) is in a range of 0.­1 ∼ 10 parts by weight against 100 parts by weight of the water-absorbent polymer ( II ). The mixture which is obtained by mixing the aqueous liquid ( I ) with the water-­absorbent polymer ( II ) has relatively-improved capacities in the fluidity and the amount of residual monomers. This invention displays a more sufficient effect by compulsorily bringing the mixture into contact with an oxygen-containing gas.
    • 本发明涉及一种用于生产,其中从所选择的这是由在wässrige介质中的至少一种的水溶性盐(A)的混合中获得的wässrige液体(I),在所有质量改善的吸水性聚合物 卤代化合物,硫酸盐,乙酸盐和硝酸盐,由至少一种从一组铝,钙和镁中选出的多价金属的衍生其中,与至少一种水溶性盐的(B)的组 从一组一价金属盐和铵盐,由至少一种选自亚硫酸和硫代硫酸的选定的含氧酸的衍生哪个选择,与吸水性聚合物(II)中那样的比例混合 多价金属(A)的水溶性盐是在按重量计吸水性聚合物(II)和含氧酸(B)的水溶性盐的范围为0.1相似10重量份对100份 在由称重为0.1相似10份 吨相对于100重量份的吸水性聚合物(II)的。 这是由wässrige液体(I)与所述的吸水性聚合物(II)混合得到的混合物全部具有流动性相对改善的容量和残留单体的量。 本发明显示由在含有氧的气体强制地使所述混合物接触以更加充分的效果。