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1. 发明公开

EP0427508A1 method for production of acrylic acid 失效转让
标题翻译： Verfahren zur Herstellung vonAcrylsäure。
公开(公告)号：EP0427508A1
公开(公告)日：1991-05-15
申请号：EP90312130.9
申请日：1990-11-06
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： Kawajiri, Tatsuya , Uchida, Shinichi , Hironaka, Hideyuki
IPC分类号： C07C57/055 , B01J23/88
CPC分类号： B01J23/8885 , B01J23/002 , B01J23/885 , B01J23/8877 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/48 , B01J2523/55 , B01J2523/68 , B01J2523/69 , B01J2523/24 , B01J2523/47 , B01J2523/25 , B01J2523/3712 , B01J2523/22 , B01J2523/23
摘要： A method for the production of acrylic acid by the vapor-phase oxidation of acrolein with a molecular oxygen-containing gas in the presence of a catalyst formed of an oxide or a composite oxide of a metal element composition represented by the following formula I:
Mo a V b W c Cu d X e Y f (I)
wherein X is at least one element selected from the group consisting of Zr, Ti and Ce, Y is at least one element selected from the group consisting of Mg, Ca, Sr and Ba, and the subscripts a, b, c, d, e, and f are such that b = 2 to 14, 0
摘要翻译：在由下式I表示的金属元素组合物的氧化物或复合氧化物形成的催化剂存在下，用含分子氧气体气相氧化丙烯醛的方法：MoaVbWcCudXeYf （I）其中X是选自Zr，Ti和Ce中的至少一种元素，Y是选自Mg，Ca，Sr和Ba中的至少一种元素，下标a，b，c ，d，e和f使得b = 2〜14,0

2. 发明公开

EP1336598A1 Method for production of methacrylic acid 有权
标题翻译：生产甲基丙烯酸的方法
公开(公告)号：EP1336598A1
公开(公告)日：2003-08-20
申请号：EP03250676.8
申请日：2003-02-03
申请人： Nippon Shokubai Co., Ltd.
发明人： Uhara, Hiroyuki , Anyouji, Kazou , Hironaka, Hideyuki , Onodera, Hideo
IPC分类号： C07C51/25 , C07C51/215 , C07C51/21 , B01J8/06
CPC分类号： C07C51/252 , B01J8/001 , B01J8/067 , B01J23/002 , B01J23/8876 , B01J27/188 , B01J27/198 , B01J2208/00106 , B01J2208/00212 , B01J2208/00548 , B01J2208/00699 , B01J2208/00707 , B01J2208/00716 , B01J2523/00 , C07C57/04 , B01J2523/15 , B01J2523/17 , B01J2523/48 , B01J2523/51 , B01J2523/55 , B01J2523/68
摘要： This invention is related to a shell-and-tube type reactor provided with reaction tubes packed with a catalyst and adapted to circulate a heat medium to the fluid outside the tubes and is characterized by a method introducing a gas into the catalyst beds so as to retain the relative humidity of the catalyst in the range of more than 40% while elevating the temperature of the reactor thereby starting up the reactor. This method prevents the catalyst from degradation of activity due to absorption of moisture, exalts the service life of the catalyst, and permits stable production of methacrylic acid.
摘要翻译：本发明涉及具备填充有催化剂的反应管的管壳式反应器，该反应管适用于使热介质循环至管外的流体，并且其特征在于将气体引入催化剂床中以便保持催化剂的相对湿度在40％以上的范围内，同时升高反应器的温度，从而启动反应器。该方法防止催化剂由于吸收水分而降低活性，提高了催化剂的使用寿命，并且允许稳定生产甲基丙烯酸。

3. 发明公开

EP0979813A1 Production process for acrylic acid 有权
标题翻译：丙烯酸生产工艺
公开(公告)号：EP0979813A1
公开(公告)日：2000-02-16
申请号：EP99306288.4
申请日：1999-08-09
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： Nakamura, Daisuke , Hironaka, Hideyuki , Tanimoto, Michio
IPC分类号： C07C51/25 , C07C57/055
CPC分类号： C07C51/252 , C07C57/04
摘要： A process for the catalytic vapour phase oxidation of acrolein or an acrolein-containing gas to produce acrylic acid wherein the temperature, T 0 , of the acrolein or the acrolein-containing gas in an inlet to a catalyst layer is greater than the temperature, T 1 , in an inlet part of the catalyst layer and the temperature, T 2 , in an outlet part of the catalyst layer is greater than T 1 .
摘要翻译：一种丙烯醛或含丙烯醛气体催化汽相氧化生产丙烯酸的方法，其中丙烯醛或含丙烯醛气体在催化剂层入口处的温度T 0大于温度T 1，在催化剂层的入口部分中，并且在催化剂层的出口部分中的温度T 2大于T 1。

4. 发明授权

EP1074538B1 Process for producing acrolein and acrylic acid 有权
标题翻译：生产丙烯醛和丙烯酸的方法
公开(公告)号：EP1074538B1
公开(公告)日：2003-05-21
申请号：EP00306667.7
申请日：2000-08-03
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： Tanimoto, Michio , Yunoki, Hiromi , Hironaka, Hideyuki , Kimura, Naomasa
IPC分类号： C07C45/35 , C07C47/22 , C07C51/25 , C07C57/04
CPC分类号： C07C51/252 , B01J23/002 , B01J23/8876 , B01J23/8885 , B01J2523/00 , C07C45/35 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/847

5. 发明公开

EP1074538A2 Process for producing acrolein and acrylic acid 有权
标题翻译： Verfahren zur Herstellung von Acrolein undAcrylsäure
公开(公告)号：EP1074538A2
公开(公告)日：2001-02-07
申请号：EP00306667.7
申请日：2000-08-03
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： Tanimoto, Michio , Yunoki, Hiromi , Hironaka, Hideyuki , Kimura, Naomasa
IPC分类号： C07C45/35 , C07C47/22 , C07C51/25 , C07C57/04
CPC分类号： C07C51/252 , B01J23/002 , B01J23/8876 , B01J23/8885 , B01J2523/00 , C07C45/35 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/847
摘要： A process comprising producing acrolein and acrylic acid by vapor-phase catalytic oxidation of propylene with molecular oxygen or molecular oxygen-containing gas in a fixed-bed multitubular reactor, wherein

(a) the catalysts are compound oxide catalysts of formula

Mo a W b Bi c Fe d A e B f C g D h O x (I)

wherein Mo is molybdenum; W is tungsten, Bi is bismuth; Fe is iron; A is one or more element selected from cobalt and nickel; B is one or more element selected from phosphorus, antimony, boron, tin, cerium, niobium, lead, chromium and zinc; C is one or more element selected from alkali metals and thallium; D is one or more element selected from silicon, aluminum, titanium and zirconium; O is oxygen; a, b, c, d, e, f, g, h and x are the atomic ratios of Mo, W, Bi, Fe, A, B, C, D and O, respectively; such that when a is 12, b is from 0 to 5, c is from 0.1 to 10, d is from 0.1 to 10, e is from 1 to 20, f is from 0 to 5, g is from 0.001 to 3, h is from 0 to 30, and x has a value determined by the oxidation state of each element, and
(b) the catalysts are filled in each reaction tube so as to provide two or more reaction zones disposed along the axis of the tube and such that the ratio of Bi and Fe atomic content to Mo atomic content for the catalyst in the reaction zone on the gas outlet side (M 1 ) is less than the ratio of Bi and Fe atomic content to Mo atomic content for the catalyst in the reaction zone on the gas inlet side (M 2 ).
摘要翻译：一种方法，其包括在固定床多管式反应器中通过气相催化氧化丙烯与分子氧或分子含氧气体制备丙烯醛和丙烯酸，其中（a）催化剂是式MoaWbBicFedAeBfCgDhOx的复合氧化物催化剂，其中Mo是钼 ; W是钨，Bi是铋; 铁是铁 A是选自钴和镍中的一种或多种元素; B是选自磷，锑，硼，锡，铈，铌，铅，铬和锌中的一种或多种元素; C是选自碱金属和铊的一种或多种元素; D是选自硅，铝，钛和锆中的一种或多种元素; O是氧; a，b，c，d，e，f，g，h和x分别为Mo，W，Bi，Fe，A，B，C，D和O的原子比; 使得当a为12时，b为0至5，c为0.1至10，d为0.1至10，e为1至20，f为0至5，g为0.001至3，h 为0〜30，x为由各元素的氧化态决定的值，（b）在各反应管中填充催化剂，以提供沿管轴设置的2个以上的反应区域，气体出口侧（M1）的反应区域中的催化剂中Bi和Fe原子含量与Mo原子含量的比例小于反应区域中催化剂的Bi原子含量与Fe原子含量与Mo原子含量的比例在气体入口侧（M2）。

6. 发明公开

EP0614872A1 Process for removal of solid organic matters 有权
标题翻译： Verfahren zur Entfernung von festen organischen Stoffen。
公开(公告)号：EP0614872A1
公开(公告)日：1994-09-14
申请号：EP94103677.4
申请日：1994-03-10
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： Kawajiri, Tatsuya , Hironaka, Hideyuki , Uekawa, Kazuyuki , Tanimoto, Michio , Yunoki, Hiromi , Kudoh, Tsuyoshi
IPC分类号： C07C51/487 , B01J38/16
CPC分类号： C07C51/487 , B01J23/94 , B01J38/06 , B01J38/12 , Y02P20/584
摘要： A process for removal of solid organic matters formed and deposited in the reaction system when an unsaturated aldehyde or an unsaturated aldehyde-containing gas is subjected to catalytic gaseous oxidation in the presence of an oxidizing catalyst to prepare an unsaturated carboxylic acid corresponding thereto, which process comprises contacting the solid organic matters with a mixed gas containing at least 3 volume % of molecular oxygen and at least 0.1 volume % of steam at a temperature of 260 to 450°C.
摘要翻译：当在氧化催化剂存在下使不饱和醛或不饱和含醛气体进行催化气态氧化以制备与其对应的不饱和羧酸时，去除在反应体系中形成和沉积的固体有机物质的方法，该方法包括在260至450℃的温度下使固体有机物与含有至少3体积％分子氧和至少0.1体积％蒸汽的混合气体接触。

7. 发明授权

EP0979813B1 Production process for acrylic acid 有权
标题翻译：一种生产丙烯酸的方法
公开(公告)号：EP0979813B1
公开(公告)日：2002-10-30
申请号：EP99306288.4
申请日：1999-08-09
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： Nakamura, Daisuke , Hironaka, Hideyuki , Tanimoto, Michio
IPC分类号： C07C51/25 , C07C57/055
CPC分类号： C07C51/252 , C07C57/04

8. 发明公开

EP1074538A3 Process for producing acrolein and acrylic acid 有权
标题翻译：生产丙烯醛和丙烯酸的方法
公开(公告)号：EP1074538A3
公开(公告)日：2001-07-04
申请号：EP00306667.7
申请日：2000-08-03
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： Tanimoto, Michio , Yunoki, Hiromi , Hironaka, Hideyuki , Kimura, Naomasa
IPC分类号： C07C45/35 , C07C47/22 , C07C51/25 , C07C57/04
CPC分类号： C07C51/252 , B01J23/002 , B01J23/8876 , B01J23/8885 , B01J2523/00 , C07C45/35 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/847
摘要： A process comprising producing acrolein and acrylic acid by vapor-phase catalytic oxidation of propylene with molecular oxygen or molecular oxygen-containing gas in a fixed-bed multitubular reactor, wherein (a) the catalysts are compound oxide catalysts of formulaMoaWbBicFedAeBfCgDhOx wherein Mo is molybdenum; W is tungsten, Bi is bismuth; Fe is iron; A is one or more element selected from cobalt and nickel; B is one or more element selected from phosphorus, antimony, boron, tin, cerium, niobium, lead, chromium and zinc; C is one or more element selected from alkali metals and thallium; D is one or more element selected from silicon, aluminum, titanium and zirconium; O is oxygen; a, b, c, d, e, f, g, h and x are the atomic ratios of Mo, W, Bi, Fe, A, B, C, D and O, respectively; such that when a is 12, b is from 0 to 5, c is from 0.1 to 10, d is from 0.1 to 10, e is from 1 to 20, f is from 0 to 5, g is from 0.001 to 3, h is from 0 to 30, and x has a value determined by the oxidation state of each element, and (b) the catalysts are filled in each reaction tube so as to provide two or more reaction zones disposed along the axis of the tube and such that the ratio of Bi and Fe atomic content to Mo atomic content for the catalyst in the reaction zone on the gas outlet side (M1) is less than the ratio of Bi and Fe atomic content to Mo atomic content for the catalyst in the reaction zone on the gas inlet side (M2).
摘要翻译：一种包括通过在固定床多管式反应器中用分子氧或含分子氧气体汽相催化氧化丙烯生产丙烯醛和丙烯酸的方法，其中（a）所述催化剂是式MoaWbBicFedAeBfCgDhOx的复合氧化物催化剂，其中Mo是钼; 钨是钨，铋是铋; 铁是铁; A是选自钴和镍中的一种或多种元素; B是选自磷，锑，硼，锡，铈，铌，铅，铬和锌中的一种或多种元素; C是选自碱金属和铊中的一种或多种元素; D是选自硅，铝，钛和锆中的一种或多种元素; O是氧气; a，b，c，d，e，f，g，h和x分别是Mo，W，Bi，Fe，A，B，C，D和O的原子比; 使得当a为12时，b为0至5，c为0.1至10，d为0.1至10，e为1至20，f为0至5，g为0.001至3，h 为0〜30，x为由各元素的氧化状态决定的值，（b）在各反应管中填充催化剂，从而沿管轴设置2个以上的反应区域，在气体出口侧（M1）的反应区中催化剂的Bi和Fe原子含量与Mo原子含量之比小于反应区中催化剂中Bi和Fe原子含量与Mo原子含量之比在气体入口侧（M2）。

9. 发明授权

EP0614872B1 Process for removal of solid organic matters 有权
标题翻译：一种用于去除固体的有机物质的方法
公开(公告)号：EP0614872B1
公开(公告)日：1997-10-29
申请号：EP94103677.4
申请日：1994-03-10
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： Kawajiri, Tatsuya , Hironaka, Hideyuki , Uekawa, Kazuyuki , Tanimoto, Michio , Yunoki, Hiromi , Kudoh, Tsuyoshi
IPC分类号： C07C51/487 , B01J38/16
CPC分类号： C07C51/487 , B01J23/94 , B01J38/06 , B01J38/12 , Y02P20/584

10. 发明授权

EP0427508B1 method for production of acrylic acid 失效转让
标题翻译：一种生产丙烯酸的过程。
公开(公告)号：EP0427508B1
公开(公告)日：1995-02-01
申请号：EP90312130.9
申请日：1990-11-06
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： Kawajiri, Tatsuya , Uchida, Shinichi , Hironaka, Hideyuki
IPC分类号： C07C57/055 , B01J23/88
CPC分类号： B01J23/8885 , B01J23/002 , B01J23/885 , B01J23/8877 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/48 , B01J2523/55 , B01J2523/68 , B01J2523/69 , B01J2523/24 , B01J2523/47 , B01J2523/25 , B01J2523/3712 , B01J2523/22 , B01J2523/23

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