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    • 6. 发明公开
    • Powder coating composition
    • 粉末涂料组合物
    • EP0504732A2
    • 1992-09-23
    • EP92104226.3
    • 1992-03-11
    • Nippon Paint Co., Ltd.
    • Toyoda, YujiUenaka, AkimitsuUeno, TasaburoIchimura, HidekiTsutsui, Koichi
    • C09D163/00C09D133/00C09D167/00C08G59/68C08G59/18
    • C09D163/00C08G59/188C08G59/686C09D167/00C08L2666/02C08L2666/28C08L2666/22
    • A powder coating composition, for use as a film coating having an excellent outer appearance, superior storing stability and excellent low temperature cure. The coating composition comprises a base resin, curing agent and curing catalyst. One of the base resin and curing agent includes at least one of a compound and resin containing two or more of a carboxyl group in one molecule, the other of them includes at least one of a compound and resin containing two or more of a glycidyl group in one molecule. The functional group-equivalent ratio of the glycidyl group to the carboxyl group in both the base resin and curing agent is in a range of from 0.5 to 2.0. The curing catalyst comprises an amine compound in a complex form enveloped in both or one of a compound and resin. The ratio of curing catalyst to the base resin and curing agent is 0.05 to 3.0 % by weight.
    • 粉末涂料组合物,用作具有优异的外观,优异的储存稳定性和优异的低温固化的薄膜涂层。 该涂料组合物包含基础树脂,固化剂和固化催化剂。 基础树脂和固化剂中的一种包括在一个分子中含有两个或更多个羧基的化合物和树脂中的至少一种,另一种包括化合物和含有两个或更多个缩水甘油基的树脂中的至少一种 在一个分子中。 基础树脂和固化剂两者中的缩水甘油基与羧基的官能团当量比在0.5至2.0的范围内。 固化催化剂包含包封在化合物和树脂中的一种或两种中的复合形式的胺化合物。 固化催化剂与基础树脂和固化剂的比例为0.05-3.0重量%。
    • 10. 发明公开
    • A heat-curing type resinuous composition and powder coating containing the same
    • 一种加热固化型基体组合物和含有该组合物的粉末涂料
    • EP0379809A3
    • 1990-12-05
    • EP89313705.9
    • 1989-12-29
    • NIPPON PAINT CO., LTD.
    • Uenaka, AkimitsuToyoda, YujiInoue, TsugunoriTsutsui, Koichi
    • C08G59/42C09D163/00C08G59/68
    • C08L63/00C08G59/42C09D163/00C08L2666/02
    • A heat-curable resinous composition comprises
      (1) at least one polycarboxylic acid component selected from:
      (A) carboxyl group containing resins having 2 or more carboxyl groups in the molecule and having a number average molecular weight of from 1,000 to 30,000 and (B) polycarboxylic acids having 2 or more carboxyl groups in the molecule and having a number average molecular weight of less that 1,000; and (2) at least one polyepoxy component selected from:
      (C) epoxy resinins having 2 or more epoxy groups in the molecule and having a number average molecular weight of from 1,000 to 30,000; and (D) polyepoxy compounds having 2 or more epoxy groups in the molecule and having a number average molecular weight of less than 1,000, with the Proviso that the combination of (B) and (D) is excluded; and further containing a monoalkyl stannate as a hardening catalyst.
    • 热固性树脂组合物包含(1)至少一种选自以下的多元羧酸成分:(A)分子中具有2个以上羧基的含羧基的树脂,数均分子量为1,000〜30,000,(B )在分子中具有2个或更多个羧基并且数均分子量小于1,000的多元羧酸; 和(2)选自以下的至少一种聚环氧成分:(C)分子中具有2个以上环氧基的环氧树脂,数均分子量为1000〜30,000; 和(D)分子中具有2个以上环氧基且具有小于1,000的数均分子量的聚环氧化合物,其中(B)和(D)的组合被排除在外; 并且还含有作为硬化催化剂的锡烷酸单烷基酯。