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1. 发明公开

EP0409520A2 Novel dialkyl peroxides, production method and use thereof 失效
标题翻译：二烷基过氧化物，Verfahren zu ihrer Herstellung und ihre Verwendung。
公开(公告)号：EP0409520A2
公开(公告)日：1991-01-23
申请号：EP90307737.8
申请日：1990-07-16
申请人： NIPPON OIL AND FATS COMPANY, LIMITED
发明人： Higuchi, Yoshiki , Suyama, Shuji
IPC分类号： C07C409/08 , C07C409/16 , C07C409/18 , C07C407/00 , C08K5/14
CPC分类号： C08F4/34 , C07C409/16
摘要： A novel dialkyl peroxide is represented by a general formula (I):

This peroxide is produced by particular methods and used as a photolysis type or pyrolysis type radical forming agent.
摘要翻译：新型二烷基过氧化物由通式（I）表示：该过氧化物通过特定方法制备，并用作光解型或热解型自由基形成剂。

2. 发明公开

EP0384660A2 Ester-type polymeric peroxides 失效
标题翻译：聚合物过氧化物呕吐物
公开(公告)号：EP0384660A2
公开(公告)日：1990-08-29
申请号：EP90301692.1
申请日：1990-02-16
申请人： NIPPON OIL AND FATS COMPANY, LIMITED
发明人： Suyama, Shuji , Higuchi, Yoshiki
IPC分类号： C08F4/36 , C08G67/00
CPC分类号： C08F4/36 , C08G67/00
摘要： A novel polymeric peroxide used as a free radical polymerization initiator for vinyl monomers is a compound alternately bonding the two particular structural units in random form and having two different thermal decomposition rates.
摘要翻译：用作乙烯基单体的自由基聚合引发剂的新型聚合物过氧化物是以两种不同的热分解速率随机形式交替结合两种特定结构单元的化合物。

3. 发明授权

EP0478214B2 Novel peroxy ester, and polymerization initiator and curing agent using the ester 失效
标题翻译： Peroxyester和seine Verwendung als Polymerisationsinitiator undHärtungsmittel
公开(公告)号：EP0478214B2
公开(公告)日：2004-04-14
申请号：EP91308505.6
申请日：1991-09-18
申请人： NIPPON OIL AND FATS COMPANY, LIMITED
发明人： Suyama, Shuji , Katoh, Mitsukuni , Nishikawa, Tooru
IPC分类号： C07C409/38 , C08F4/34
CPC分类号： C08F4/34 , C07C409/38 , C07C2601/14

4. 发明授权

EP0461767B1 Polymeric peroxide, polymerization initiator and method for production of block copolymer 失效
标题翻译： Polymerperoxid，用于制备嵌段共聚物的聚合引发剂和方法
公开(公告)号：EP0461767B1
公开(公告)日：1996-08-14
申请号：EP91304526.6
申请日：1991-05-20
申请人： NIPPON OIL AND FATS COMPANY, LIMITED
发明人： Suyama, Shuji , Ishigaki, Hideyo , Watanabe, Yasumasa , Kumura, Hiromi
IPC分类号： C08F4/36 , C08F2/00
CPC分类号： C08F4/36

5. 发明公开

EP0478214A3 Novel peroxy ester, and polymerization initiator and curing agent using the ester 失效
标题翻译：新型过氧化物酶，聚合引发剂和使用酯酶的固化剂
公开(公告)号：EP0478214A3
公开(公告)日：1992-07-01
申请号：EP91308505.6
申请日：1991-09-18
申请人： NIPPON OIL AND FATS COMPANY, LIMITED
发明人： Suyama, Shuji , Katoh, Mitsukuni , Nishikawa, Tooru
IPC分类号： C07C409/38 , C08F4/34
CPC分类号： C08F4/34 , C07C409/38 , C07C2601/14
摘要： A 1-cyclohexyl-1-methylethyl peroxy ester, a novel compound, represented by the formula:

wherein R¹ stands for one member selected from the group consisting of H and alkyl groups and R² and R³ independently stand for an alkyl group, provided that R² and R³ each stand for an alkyl group of 1 to 5 carbon atoms and the sum of the carbon atoms of R² and R³ is in the range of from 2 to 6 where R¹ is H and R¹, R², and R³ each stand for an alkyl group of 1 to 9 carbon atoms and the sum of the carbon atoms of R¹, R², and R³ is in the range of from 3 to 11 where R¹ is an alkyl group, a polymerization initiator for a vinyl group-containing compound monomer and a curing agent for an unsaturated polyester resin, which polymerization initiator and curing agent both contain as an active component thereof the ester mentioned above.
摘要翻译： 1-环己基-1-甲基乙基过氧酯，由式：CHEM表示的新型化合物，其中R 1表示选自H和烷基中的一个，R 2和R 2， 3>独立地代表烷基，条件是R 2和R 3各自代表1至5个碳原子的烷基，R 2和R 3的碳原子之和为在2至6的范围内，其中R 1是H且R 1，R 2和R 3各自代表1至9个碳原子的烷基，并且碳原子的总和 R 1，R 2和R 3的范围为3〜11，其中R 1为烷基，含乙烯基的化合物单体的聚合引发剂和固化剂对于不饱和聚酯树脂，该聚合引发剂和固化剂均含有上述酯作为其活性组分。

6. 发明公开

EP0384660A3 Ester-type polymeric peroxides 失效
标题翻译：酯类聚合物过氧化物
公开(公告)号：EP0384660A3
公开(公告)日：1991-06-05
申请号：EP90301692.1
申请日：1990-02-16
申请人： NIPPON OIL AND FATS COMPANY, LIMITED
发明人： Suyama, Shuji , Higuchi, Yoshiki
IPC分类号： C08F4/36 , C08G67/00
CPC分类号： C08F4/36 , C08G67/00
摘要： A novel polymeric peroxide used as a free radical polymerization initiator for vinyl monomers is a compound alternately bonding the two particular structural units in random form and having two different thermal decomposition rates.

7. 发明授权

EP0409520B1 Novel dialkyl peroxides, production method and use thereof 失效
标题翻译：二烷基过氧化物，其制备方法及其用途。
公开(公告)号：EP0409520B1
公开(公告)日：1994-09-14
申请号：EP90307737.8
申请日：1990-07-16
申请人： NIPPON OIL AND FATS COMPANY, LIMITED
发明人： Higuchi, Yoshiki , Suyama, Shuji
IPC分类号： C07C409/08 , C07C409/16 , C07C409/18 , C07C407/00 , C08K5/14
CPC分类号： C08F4/34 , C07C409/16

8. 发明公开

EP0461767A3 Polymeric peroxide, polymerization initiator and method for production of block copolymer 失效
标题翻译：聚合过氧化物，聚合引发剂和生产嵌段共聚物的方法
公开(公告)号：EP0461767A3
公开(公告)日：1992-10-21
申请号：EP91304526.6
申请日：1991-05-20
申请人： NIPPON OIL AND FATS COMPANY, LIMITED
发明人： Suyama, Shuji , Ishigaki, Hideyo , Watanabe, Yasumasa , Kumura, Hiromi
IPC分类号： C08F4/36 , C08F2/00
CPC分类号： C08F4/36
摘要： An ester type polymeric peroxide has a peroxide group of the formula (I):

a group of the formula (I′)

and a group of the formula (II)

wherein X stands for one member selected from the group consisting of -CH₂-CH₂-, -C≡C- and

continuously bound such that I and I′ occur randomly in alternation with II, having a (I) : (I′) molar ratio in the range of from 9 : 1 to 1 : 9 and the [(I) + (I′)] : (II) molar ratio in the range of from 6 : 4 to 4 : 6, and having an average molecular weight in the range of from 1,000 to 20,000, a polyerization initiator for vinyl type monomer comprising said ester type polymeric peroxide and method for the production of a block copolymer of vinyl type monomer by said polymerization initiator.

9. 发明公开

EP0364169A3 Polymeric peroxy ester and its use 失效
标题翻译：聚合过氧化物酶及其用途
公开(公告)号：EP0364169A3
公开(公告)日：1991-06-12
申请号：EP89310238.4
申请日：1989-10-06
申请人： NIPPON OIL AND FATS COMPANY, LIMITED
发明人： Suyama, Shuji , Ishigaki, Hideyo , Taura, Katsuki
IPC分类号： C08G67/00 , C08F4/36
CPC分类号： C08G67/00 , C08F4/36
摘要： A polymeric peroxy ester, which consists of a structural unit represented by the formula (I):
and a structural unit represented by the general formula (II):
, wherein R represents -CH₂CH₂-, -C≡C- or
and has an average molecular weight of 1,000-15,000, said structural units (I) and (II) being bonded alternately in a molar ratio within the range of from 6:4 to 4:6, has a 10-hour half-life period temperature of 70-85°C and a high activity at relatively high temperature, is safe in the production and handling, is adapted to be used as a polymerization initiator in the polymerization of vinyl monomer, and can produce a vinyl polymer having a high molecular weight.

10. 发明公开

EP0395803A1 Method for producing 1,1,3,3, - tetramethylbutyl hydroperoxide 失效
标题翻译： Verfahren zur Herstellung von 1,1,3,3-四甲基丁基氢过氧化物。
公开(公告)号：EP0395803A1
公开(公告)日：1990-11-07
申请号：EP89303392.8
申请日：1989-04-06
申请人： NIPPON OIL AND FATS COMPANY, LIMITED
发明人： Suyama, Shuji , Takada, Jun , Kato, Mitsukuni , Okada, Hiroshi
IPC分类号： C07C409/04 , C07C407/00
CPC分类号： C07C409/04 , C07C407/00
摘要： High-purity 1,1,3,3-tetramethylbutyl hydroperoxide can be easily and safely produced without the formation of dangerous acetone peroxide, by the reaction of neopentyldimethylcarbinol with hydrogen peroxide in the presence of sulfuric acid.
摘要翻译：通过在硫酸存在下新戊基二甲基甲醇与过氧化氢的反应，可以容易且安全地生产高纯度1,1,3,3-四甲基丁基过氧化氢，而不会形成危险的丙酮过氧化物。

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