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1. 发明授权

EP0834521B1 Fluoroelastomer and its cross-linkable composition 失效
标题翻译：含氟弹性体及其固化性组合物
公开(公告)号：EP0834521B1
公开(公告)日：2000-03-22
申请号：EP97114461.3
申请日：1997-08-21
申请人： NIPPON MEKTRON, LTD.
发明人： Enokida, Takashi , Akimoto, Hajime , Tatsu, Haruyoshi
IPC分类号： C08F214/22
CPC分类号： C08F214/222

2. 发明公开

EP0845482A1 Process for producing fluorine-containing elastomer 失效
标题翻译： Verfahren zur Herstellung eines Fluor-haltigen弹性体
公开(公告)号：EP0845482A1
公开(公告)日：1998-06-03
申请号：EP97120935.8
申请日：1997-11-28
申请人： NIPPON MEKTRON, LTD.
发明人： Saito, Satoru , Kawasaki, Kuniyoshi , Tatsu, Haruyoshi
IPC分类号： C08F214/18 , C08F214/22
CPC分类号： C08F214/22 , C08F214/184 , C08F2438/01
摘要： A peroxide-vulcanizable fluorine-containing elastomer containing iodines as cross-linking sites, capable of producing vulcanization products having a distinguished heat resistance is produced by polymerization reaction of a fluorinated olefin having 2 to 8 carbon atoms in the presence of a diiodide compound represented by the following general formula:

I-R-I

where R is a divalent fluorohydrocarbon group, chlorofluorohydrocarbon group or hydrocarbon group, having 2 to 8 carbon atoms, respectively, and 2,2-difluoroiodoethylene.
摘要翻译：通过在二碘化合物的存在下，在具有2-8个碳原子的氟化烯烃的存在下，通过聚合反应生成含有碘作为交联部位的可过氧化物硫化的含氟弹性体，其能够生产具有显着耐热性的硫化产物，以下通式：IRI其中R是二价氟代烃基，氯氟烃基或碳原子数为2至8的烃基，和2,2-二氟碘乙烯。

3. 发明公开

EP0754721A3 Fluorine-containing elastomer composition 失效
标题翻译：弹性体组合物含有含氟
公开(公告)号：EP0754721A3
公开(公告)日：1997-03-26
申请号：EP96111051.7
申请日：1996-07-09
申请人： NIPPON MEKTRON, LTD.
发明人： Saito, Satoru , Tatsu, Haruyoshi , Sokolov, Sergei Vasil'evich , Kollar, Alexandre Nikolaevich , Sterlin, Sergei Rafailovich , Zeifman, Yurii Vilovich , Postovoi, Sergei Anatol'evich
IPC分类号： C08K5/29 , C08L27/12
CPC分类号： C08K5/29 , C08L27/12
摘要： A fluorine-containing elastomer composition comprising a fluorine-containing elastomer having a cyano group as a cross-linkable group and a bisamidrazone compound represented by the following general formula as a vulcanizing agent:
wherein
Rf is one of the following groups:
(CF 2 )n, CFX(OCF 2 CFX)mO(CF 2 )n and
CFX(OCF 2 CFX)pO(CF 2 )nO(CFXCF 2 O)qCFX has considerably improved roll kneadability and processability during the vulcanization-molding, and gives vulcanization products having good heat resistance and solvent resistance.

4. 发明公开

EP0606883A1 Fluorine-containing elastomer composition 失效
标题翻译：氟橡胶弹性体。
公开(公告)号：EP0606883A1
公开(公告)日：1994-07-20
申请号：EP94100290.9
申请日：1994-01-11
申请人： NIPPON MEKTRON, LTD.
发明人： Saito, Satoru , Tatsu, Haruyoshi , Murata, Hiroaki
IPC分类号： C08K5/18 , C08L27/12
CPC分类号： C08K5/18 , C08L27/12
摘要： A fluorine-containing elastomer composition comprising a terpolymer of tetrafluoroethylene, perfluoro(lower alkyl vinyl ether) and perfluoro(ω-cyanoalkyl vinyl ether) and a bisaminophenyl compound represented by the following general formula as a curing agent:

wherein A is an alkylidene group having 1 to 6 carbon atoms, a perfluoroalkylidene group having 1 to 10 carbon atoms, a SO₂ group, an O group, a CO group, or a carbon-carbon bond capable of directly coupling two benzene rings; and X and Y each are a hydroxyl group or an amino group can give a rubbery vulcanization product with a good processability and good physical properties by a commercially available cross-linking agent free from any safety problem.
摘要翻译：包含四氟乙烯，全氟（低级烷基乙烯基醚）和全氟（ω-氰基烷基乙烯基醚）的三元共聚物和由以下通式表示的二氨基苯基化合物作为固化剂的含氟弹性体组合物：其中A是具有1至6个碳原子的亚烷基，具有1至10个碳原子的全氟亚烷基，可以直接键合两个苯环的SO 2基团，O基团，CO基团或碳 - 碳键; 并且X和Y各自为羟基或氨基可以通过市售的没有任何安全问题的交联剂得到具有良好加工性和良好物理性能的橡胶状硫化产品。

6. 发明公开

EP0849392A2 Fluoroalkylated allylurethane, its copolymer and water- and oil-repellent, anti-soiling processing agent containing the copolymer as an effective component 失效
标题翻译： Fluoroalkylierte烯丙基氨基甲酸乙酯，制成的共聚物构成，且水，油和含有该共聚物作为有效成分的防污防水处理剂
公开(公告)号：EP0849392A2
公开(公告)日：1998-06-24
申请号：EP97122276.5
申请日：1997-12-17
申请人： NIPPON MEKTRON, LTD.
发明人： Saito, Satoru , Kawasaki, Kuniyoshi , Tatsu, Haruyoshi
IPC分类号： D06M15/356 , D06M15/576 , C08F16/28 , C07C271/24 , C07C271/28
CPC分类号： D06M13/428 , C07C271/24 , C07C271/28 , C07C2601/14 , C08F216/1458 , D06M15/248 , D06M15/263 , D06M15/353 , D06M15/3562 , D06M15/576 , D06M2200/11 , D06M2200/12
摘要： A fluoroalkylated allylurethane represented by the following general formula:

RfROCONHR'NHCOOC n H 2n OCH 2 CH=CH 2

where Rf is a perfluoroalkyl group having 2 to 20 carbon atoms, R is a divalent organic group, R' is a diisocyanate residue, and n is an integer of 2 to 6, can undergo emulsion polymerization with at least one of a methacrylate ester, an acrylate ester and vinylidene chloride to give an effective aqueous copolymer emulsion for a water- and oil-repellent, anti-soiling processing agent.

7. 发明公开

EP0735095A1 Fluorine-containing elastomer composition 失效
标题翻译：含氟弹性体组合物
公开(公告)号：EP0735095A1
公开(公告)日：1996-10-02
申请号：EP96104883.2
申请日：1996-03-27
申请人： NIPPON MEKTRON, LTD.
发明人： Saito, Satoru , Kumiya, Futoshi , Tatsu, Haruyoshi
IPC分类号： C08L27/18 , C08K3/00 , C08K5/00
CPC分类号： C08K3/24 , C08K5/098 , C08L27/18
摘要： A fluorine-containing elastomer composition comprising a terpolymer of tetrafluoroethylene, perfluoro(lower alkyl vinyl ether) and cyano group-containing (perfluorovinylether), and a less expensive of the ammonium salt of organic or inorganic acid as a curing agent produce a vulcanization product having good heat resistance and solvent resistance, and when no carbon black, etc. are contained in the composition for curing, transparent vulcanization product having satisfactory physical properties are obtainable.
摘要翻译：包含四氟乙烯，全氟（低级烷基乙烯基醚）和含氰基（全氟乙烯基醚）的三元共聚物和较便宜的有机或无机酸铵盐作为固化剂的含氟弹性体组合物生成硫化产物，良好的耐热性和耐溶剂性，并且当用于固化的组合物中不含有炭黑等时，可获得具有令人满意的物理性能的透明硫化产品。

8. 发明公开

EP0708139A1 Fluorine-containing elastomer composition 失效
标题翻译： Fluorhaltige Elastomerzusammensetzung
公开(公告)号：EP0708139A1
公开(公告)日：1996-04-24
申请号：EP95116111.6
申请日：1995-10-12
申请人： NIPPON MEKTRON, LTD. , The Central Synthetic Rubbers Research Institute named for S.V. Lebedev
发明人： Iwa, Riichi , Tatsu, Haruyoshi , Alexeevna, Volkova Margarita , Stefanovich, Rondarev Dmitrii , Vasilyevich, Sokolov Sergey , Peysakhovich, Greenblat Mark , Nikolaevich, Senyushov Lev
IPC分类号： C08K5/18 , C08L27/12
CPC分类号： C08K5/18 , C08L27/12
摘要： A fluorine-containing elastomer composition, which comprises a terpolymer of tetrafluoroethylene, perfluoro(lower alkyl vinyl ether) and a perfluoro unsaturated nitrile compound represented by the following general formula:

CF₂=CFO(CF₂)nOCF(CF₃)CN

, wherein n is an integer of 2 to 5, and a bis(aminophenyl) compound represented by the following general formula as a cross-linking agent:

, wherein A is an alkylidene group having 1 to 6 carbon atoms or a perfluoroalkylidene group having 1 to 10 carbon atoms and X and Y are a hydroxyl group or an amino group, can produce vulcanized products having good vulcanization physical properties and a good compression set.
摘要翻译：一种含氟弹性体组合物，其包含四氟乙烯，全氟（低级烷基乙烯基醚）和由以下通式表示的全氟不饱和腈化合物的三元共聚物：CF2 = CFO（CF2）nOCF（CF3）CN，其中n为 2〜5的整数以及作为交联剂的下述通式表示的双（氨基苯基）化合物：，其中A为碳原子数1〜6的亚烷基或1〜10的全氟亚烷基碳原子，X和Y是羟基或氨基，可以生产具有良好硫化物理性能和良好压缩永久变形的硫化产品。

9. 发明公开

EP0708084A1 Bisamidrazone compound and vulcanizing agent for fluorinecontaining elastomer comprising the same 失效
标题翻译：二氨基腙和硫化剂为含有它们的含氟弹性体
公开(公告)号：EP0708084A1
公开(公告)日：1996-04-24
申请号：EP95114799.0
申请日：1995-09-20
申请人： NIPPON MEKTRON, LTD.
发明人： Yamamoto, Yuichi , Saito, Satoru , Tatsu, Haruyoshi , Solomonovich, German Lev , Vilovich, Zeifman Yurii , Anatol'evich, Postovoi Sergei , Lvovich, Rusanov Alexandre
IPC分类号： C07C255/51 , C07C257/22 , C08K5/29 , C08L33/18 , C08L29/10
CPC分类号： C07C257/22 , C07C255/51 , C08K5/29 , C08L27/12
摘要： Novel compound, 2,2-bis(4-carboxyphenyl)hexafluoropropane bisamidrazone, obtained by conversion of the carboxy groups of 2,2-bis(4-carboxyphenyl)hexafluoropropane to acid chloride groups, followed by reaction with ammonia; dehydration reaction of the resulting 2,2-bis(4-carboxyphenyl)hexafluoropropane diamide; reaction of the thus obtained 2,2-bis(4-cyanophenyl)hexafluoropropane with alcohol; and reaction of the resulting 2,2-bis(4-carboxyphenyl)hexafluoropropane bisiminoalkyl ether with hydrazine is a useful vulcanizing agent for fluorine-containing elastomer having cyano group.
摘要翻译：新颖化合物，2,2-双（4-羧基苯基）六氟丙烷的双脒腙，由2,2-双（4-羧基苯基）六氟丙烷，以酰氯基团，接着与氨反应的羧基转换获得; 将所得的2,2-双（4-羧基苯基）六氟丙烷二酰胺的脱水反应; 将如此得到的2,2-双（4-氰基苯基）六氟丙烷与醇的反应; 并用肼将所得2,2-双反应（4-羧基苯基）六氟丙烷bisiminoalkyl醚为具有氰基的含氟弹性体的有用硫化剂。

10. 发明授权

EP0845482B1 Process for producing fluorine-containing elastomer 失效
标题翻译：一种用于制造含氟弹性体的方法
公开(公告)号：EP0845482B1
公开(公告)日：2000-02-02
申请号：EP97120935.8
申请日：1997-11-28
申请人： NIPPON MEKTRON, LTD.
发明人： Saito, Satoru , Kawasaki, Kuniyoshi , Tatsu, Haruyoshi
IPC分类号： C08F214/18 , C08F214/22
CPC分类号： C08F214/22 , C08F214/184 , C08F2438/01

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