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    • 3. 发明公开
    • SECONDARY BATTERY USING HYDROXIDE ION-CONDUCTIVE CERAMIC SEPARATOR
    • 二次电池使用氢氧离子导电陶瓷分离器
    • EP3220468A1
    • 2017-09-20
    • EP15858299.9
    • 2015-08-31
    • NGK Insulators, Ltd.
    • HAYASHI HiroshiKITOH KenshinYAMADA Naohito
    • H01M10/28H01M2/16H01M2/18H01M4/24H01M4/42H01M4/52H01M10/30H01M12/08
    • H01M2/1646H01M2/1686H01M2/18H01M4/244H01M4/32H01M4/52H01M10/28H01M10/30H01M12/08H01M2300/0014H01M2300/0071Y02E60/128
    • Provided is a secondary battery including a positive electrode, a negative electrode, an alkaline electrolytic solution, a separator structure exhibiting water impermeability and separating the positive electrode from the negative electrode, and a container accommodating at least the negative electrode and the alkaline electrolytic solution. The separator structure includes a porous substrate-supported ceramic separator, and a reinforcement having a lattice structure having openings and reinforcing the periphery and/or at least one surface of the porous substrate-supported ceramic separator. The porous substrate-supported ceramic separator includes a ceramic separator composed of an inorganic solid electrolyte having hydroxide ion conductivity in the form of a membrane or layer densified enough to have water impermeability, and a porous substrate disposed on at least one surface of the separator. The battery includes a porous substrate-supported ceramic separator with hydroxide ion conductivity having a high strength meeting an increase in the area of the separator.
    • 本发明提供一种二次电池,其包括正极,负极,碱性电解液,具有不透水性并将正极与负极分离的隔板结构,以及容纳至少负极和碱性电解液的容器。 隔膜结构包括多孔基材支承陶瓷隔膜和具有格子结构的增强物,所述增强物具有开口并增强多孔基材支承陶瓷隔膜的周边和/或至少一个表面。 多孔基材支承陶瓷隔膜包括陶瓷隔膜和多孔基材,所述陶瓷隔膜由具有充分致密化以具有不透水性的膜或层形式的氢氧根离子传导性的无机固体电解质和设置在隔膜的至少一个表面上的多孔基材构成。 该电池包括具有高强度的氢氧根离子导电性的多孔基材支承陶瓷隔膜,以满足隔膜面积的增加。
    • 4. 发明公开
    • NICKEL-ZINC BATTERY
    • 镍锌电池
    • EP3168920A1
    • 2017-05-17
    • EP15819722.8
    • 2015-05-27
    • NGK Insulators, Ltd.
    • HAYASHI HiroshiYAMADA NaohitoKITOH Kenshin
    • H01M10/28H01M2/16H01M2/18H01M10/30
    • H01M10/30C22C18/00H01M2/0202H01M2/0237H01M2/16H01M2/1646H01M2/1686H01M2/18H01M4/244H01M4/30H01M4/32H01M4/38H01M4/42H01M4/48H01M4/52H01M10/26H01M10/28H01M2220/10H01M2220/20H01M2220/30H01M2300/0014H01M2300/0068H01M2300/0088H01M2300/0094
    • Provided is a highly reliable nickel-zinc battery including a separator exhibiting hydroxide ion conductivity and water impermeability. The nickel-zinc battery of the present invention includes a separator exhibiting hydroxide ion conductivity and water impermeability. The separator is disposed in a hermetic container so as to separate a positive-electrode chamber accommodating a positive electrode and a positive-electrode electrolytic solution from a negative-electrode chamber accommodating a negative electrode and a negative-electrode electrolytic solution. The positive-electrode chamber has an extra positive-electrode space having a volume that meets at least part of a variation in amount of water in association with reaction at the positive electrode during charge and discharge of the battery, and the negative-electrode chamber has an extra negative-electrode space having a volume that meets at least part of a variation in amount of water in association with reaction at the negative electrode during charge and discharge of the battery. The battery further includes a gas-liquid flow channel that connects the extra positive-electrode space to the extra negative-electrode space, and the gas-liquid flow channel allows the electrolytic solution and gas in the positive-electrode and negative-electrode chambers to pass through the flow channel in response to a variation in amount of water caused by charge and discharge reactions.
    • 提供一种包括具有氢氧离子传导性和不透水性的隔膜的高可靠性镍 - 锌电池。 本发明的镍 - 锌电池包括具有氢氧离子传导性和不透水性的隔膜。 分隔件设置在密封容器中,以将容纳正极和正极电解液的正极室从容纳负极和负极电解液的负极室分离。 正电极室具有额外的正电极空间,该正电极空间具有与在电池充电和放电期间在正电极处的反应相关的水量变化的至少一部分相符的体积,并且负电极室具有 在电池的充电和放电期间具有满足与负电极处的反应相关的水量变化的至少一部分的体积的额外的负电极空间。 电池还包括将额外的正电极空间连接到额外的负电极空间的气液流动通道,并且气液流动通道允许正电极室和负电极室中的电解液和气体到 响应由充放电反应引起的水量变化而通过流道。
    • 6. 发明公开
    • NICKEL-ZINC BATTERY
    • 镍ZINK-BATTERIE
    • EP3076477A1
    • 2016-10-05
    • EP15818894.6
    • 2015-05-21
    • NGK Insulators, Ltd.
    • HAYASHI HiroshiYAMADA NaohitoKITOH Kenshin
    • H01M10/30H01M2/16H01M10/28H01M10/34
    • H01M10/30H01M2/14H01M2/1646H01M2/166H01M2/1686H01M2/18H01M4/38H01M4/42H01M4/48H01M4/52H01M10/28H01M10/34H01M2300/0014H01M2300/0068
    • Provided is a highly reliable nickel-zinc battery including a separator exhibiting hydroxide ion conductivity and water impermeability. The nickel-zinc battery includes a positive electrode containing nickel oxide and/or nickel oxyhydroxide; a positive-electrode electrolytic solution in which the positive electrode is immersed, the electrolytic solution containing an alkali metal hydroxide; a negative electrode containing zinc and/or zinc oxide; a negative-electrode electrolytic solution in which the negative electrode is immersed, the electrolytic solution containing an alkali metal hydroxide; a hermetic container accommodating the positive electrode, the positive-electrode electrolytic solution, the negative electrode, and the negative-electrode electrolytic solution; the separator exhibiting hydroxide ion conductivity and water impermeability and disposed in the hermetic container to separate a positive-electrode chamber accommodating the positive electrode and the electrolytic solution from a negative-electrode chamber accommodating the negative electrode and the electrolytic solution; and a porous substrate on a surface of the separator facing toward the positive electrode.
    • 提供了一种高可靠性的镍 - 锌电池,其包括显示氢氧根离子传导性和不透水性的隔膜。 镍 - 锌电池包括含有氧化镍和/或氢氧化正镍的正电极; 浸渍有正极的正极电解液,含有碱金属氢氧化物的电解液; 含有锌和/或氧化锌的负极; 浸渍有负极的负极电解液,含有碱金属氢氧化物的电解液; 容纳正极,正极电解液,负极和负极电解液的密封容器; 所述分离器具有氢氧离子传导性和不透水性,并且设置在所述密封容器中,以将容纳所述正极和所述电解液的正极室与容纳所述负极和所述电解液的负极室分离; 以及在隔板的面向正极的表面上的多孔基材。
    • 7. 发明公开
    • NICKEL-ZINC BATTERY
    • 镍锌电池
    • EP3076476A1
    • 2016-10-05
    • EP15818260.0
    • 2015-05-21
    • NGK Insulators, Ltd.
    • HAYASHI HiroshiYAMADA NaohitoKITOH Kenshin
    • H01M10/30H01M2/16H01M10/28H01M10/34
    • H01M10/30H01M2/14H01M2/1646H01M2/166H01M2/1686H01M2/18H01M4/38H01M4/42H01M4/48H01M4/52H01M10/28H01M10/34H01M2300/0014H01M2300/0068
    • Provided is a highly reliable nickel-zinc battery including a separator exhibiting hydroxide ion conductivity and water impermeability. The nickel-zinc battery of the present invention includes a positive electrode containing nickel oxide and/or nickel oxyhydroxide; a positive-electrode electrolytic solution in which the positive electrode is immersed, the electrolytic solution containing an alkali metal hydroxide; a negative electrode containing zinc and/or zinc oxide; a negative-electrode electrolytic solution in which the negative electrode is immersed, the electrolytic solution containing an alkali metal hydroxide; a hermetic container accommodating the positive electrode, the positive-electrode electrolytic solution, the negative electrode, and the negative-electrode electrolytic solution; and the separator exhibiting hydroxide ion conductivity and water impermeability and disposed in the hermetic container so as to separate a positive-electrode chamber accommodating the positive electrode and the positive-electrode electrolytic solution from a negative-electrode chamber accommodating the negative electrode and the negative-electrode electrolytic solution.
    • 提供一种包括具有氢氧离子传导性和不透水性的隔膜的高可靠性镍 - 锌电池。 本发明的镍 - 锌电池包括含有氧化镍和/或羟基氧化镍的正极; 浸渍正极的正极电解液,含有碱金属氢氧化物的电解液, 含有锌和/或氧化锌的负极; 浸渍负极的负极电解液,含有碱金属氢氧化物的电解液; 容纳正极,正极电解液,负极和负极电解液的气密容器; 所述隔膜具有氢氧根离子传导性和不透水性,并设置在所述密封容器中,以便将容纳所述正极和所述正极电解液的正极室从容纳所述负极和所述负极电极的负极室分离, 电极电解液。