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1. 发明公开

EP2504325A1 PROCESS FOR THE MANUFACTURE OF PROPYLENE OXIDE 有权
标题翻译：制备环氧丙烷的方法
公开(公告)号：EP2504325A1
公开(公告)日：2012-10-03
申请号：EP10784453.2
申请日：2010-11-24
申请人： Momentive Specialty Chemicals Research Belgium S.A.
发明人： MUPPA, Prasad , SCHOOLDERMAN, Caspa , RENS VAN DER LEE, Sandra , POSTMA, Ron
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , Y02P20/52
摘要： A process for the manufacture of propylene oxide ("PO") by catalytic oxidation of propylene with an oxidant wherein the catalytic oxidation is performed in an aqueous reaction medium, comprising water with less than 10% by volume of cosolvents, wherein a water-soluble manganese complex is used as oxidation catalyst, characterized in that the water-soluble manganese complex is a mononuclear species of the general formula (I): [LMnX
3 ]Y (I) or a binuclear species of the general formula (II): [LMn( μ-X)
3 MnL]Y
2 (II) wherein Mn is a manganese; L or each L independently is a polydentate ligand, each X independently is a coordinating species and each μ-X independently is a bridging coordinating species, whereas Y is an non-coordinating counterion, and wherein the catalytic oxidation is carried out at a pH in the range of from 1.5 to 6.0.
摘要翻译：一种通过用氧化剂催化氧化丙烯制造环氧丙烷（“PO”）的方法，其中催化氧化在含水反应介质中进行，所述反应介质包含具有小于10体积％共溶剂的水，其中水溶性锰配合物用作氧化催化剂，其特征在于所述水溶性锰配合物是通式（I）的单核物质：[LMnX 3] Y（I）或通式（II）的双核物质： LMn（μ-X）3MnL] Y 2（II）其中Mn是锰; L或每个L独立地为多齿配体，每个X独立地为配位物质，并且每个μ-X独立地为桥连配位物质，而Y为非配位平衡离子，并且其中催化氧化在pH为范围从1.5到6.0。

2. 发明公开

EP2334660A1 PROCESS FOR THE MANUFACTURE OF EPICHLOROHYDRIN USING HYDROGEN PEROXIDE AND A MANGANESE COMPLEX 审中-公开
标题翻译：用于生产环氧氯丙烷过程中使用氢和漫画COMPLEX
公开(公告)号：EP2334660A1
公开(公告)日：2011-06-22
申请号：EP09802445.8
申请日：2009-07-09
申请人： Momentive Specialty Chemicals Research Belgium S.A.
发明人： POSTMA, Ron , MUPPA, Prasad
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , B01J21/00 , B01J23/34 , C07D255/02
摘要： The invention relates to a process for the manufacture of epichlorohydrin ("ECH") by catalytic oxidation of allyl chloride ("AC") with an oxidant wherein the catalytic oxidation is performed in an aqueous reaction medium, wherein a water-soluble manganese complex is used as oxidation catalyst, followed by the isolation of epichlorohydrin.

3. 发明公开

EP2324000A1 PROCESS FOR THE MANUFACTURE OF A 1, 2-EPOXIDE 有权转让
标题翻译：用于生产1,2-环氧化物
公开(公告)号：EP2324000A1
公开(公告)日：2011-05-25
申请号：EP09802446.6
申请日：2009-07-09
申请人： Momentive Specialty Chemicals Research Belgium S.A.
发明人： POSTMA, Ron , MUPPA, Prasad
IPC分类号： C07D301/12
CPC分类号： C07D301/12
摘要： The invention relates to a process for the manufacture of a 1, 2- epoxide by catalytic oxidation of a terminal olefin with hydrogen peroxide wherein the catalytic oxidation is performed in a biphasic system comprising an organic phase and an aqueous reaction medium, wherein a water-soluble manganese complex is used as oxidation catalyst, wherein a terminal olefin is used with a solubility at 20°C of at least 0,01 to 100 g in 1 liter water, and wherein the molar ratio of terminal olefin to hydrogen peroxide is in the range of from 1:0.1 to 1:2.

4. 发明公开

EP2723725A1 APPARATUS AND METHODS TO PRESERVE CATALYST ACTIVITY IN AN EPOXIDATION PROCESS 有权
标题翻译：设备和方法保留催化活性IN A环氧化
公开(公告)号：EP2723725A1
公开(公告)日：2014-04-30
申请号：EP12733412.6
申请日：2012-06-13
申请人： Momentive Specialty Chemicals Research Belgium S.A.
发明人： KAPELLEN, Mark , VAN DEN BERG, Bart , MUPPA, Prasad , HAESAKKERS, Paul
IPC分类号： C07D301/12
CPC分类号： B01J31/4092 , C07D301/12
摘要： Apparatus and methods are provided for forming and processing multiphasic systems. In one embodiment, the invention provides a process for the manufacture of an epoxide, including reacting an olefinically unsaturated compound with an oxidant in the presence of a buffer component and a water-soluble manganese complex disposed in an aqueous phase having a first pH level in a first multiphasic system, adjusting the pH of the aqueous phase to a second pH level less than the first pH level, isolating at least a portion of the aqueous phase from the first multiphasic system, adjusting the pH of the at least a portion of the aqueous phase to a third pH level greater than the second pH level, and introducing the at least a portion of the aqueous phase into a second multiphasic system.

5. 发明公开

EP2531495A1 EPOXIDATION PROCESS 有权
标题翻译：环氧化
公开(公告)号：EP2531495A1
公开(公告)日：2012-12-12
申请号：EP11701210.4
申请日：2011-01-26
申请人： Momentive Specialty Chemicals Research Belgium S.A.
发明人： MUPPA, Prasad , KAPELLEN, Mark , SCHOOLDERMAN, Caspar
IPC分类号： C07D301/12
CPC分类号： C07D301/12
摘要： Processes and compositions are provided for epoxidizing an olefinically unsaturated compound. In one embodiment, a process is provided for reacting an olefinically unsaturated compound with an oxidant in the presence of a catalyst at acidic conditions, wherein the catalyst is activated prior to the reaction at a pH that is higher than the pH during the reaction.

6. 发明公开

EP2539329A2 PROCESS FOR THE MANUFACTURE OF A 1,2-EPOXIDE AND A DEVICE FOR CARRYING OUT SAID PROCESS 审中-公开
标题翻译：用于制造1,2-环氧化物的方法和用于执行所述方法的装置
公开(公告)号：EP2539329A2
公开(公告)日：2013-01-02
申请号：EP11702144.4
申请日：2011-01-26
申请人： Momentive Specialty Chemicals Research Belgium S.A. , Momentive Specialty Chemicals Inc.
发明人： MUPPA, Prasad , POSTMA, Ron , VAN DEN BERG, Bart , STOCK, Juergen , WIEDERHOLD, Holger , RAUSCH, Hans , SCHALLENBERG, Jörg , BERNHARDT, Stefan
IPC分类号： C07D301/12
CPC分类号： C07D301/14 , B01D17/0208 , B01F5/061 , B01J4/00 , B01J19/2435 , B01J2219/00094 , B01J2231/72 , C07D301/03 , C07D301/12 , Y02P20/582
摘要： Apparatus and processes are provided for forming epoxide compounds. In one embodiment, a process for the manufacture of an epoxide is provided including adding an oxidant, a water-soluble manganese complex and a terminal olefin to form a multiphasic reaction mixture, reacting the terminal olefin with the oxidant in the multiphasic reaction mixture having at least one organic phase in the presence of the water-soluble manganese complex, separating the reaction mixture into the at least one organic phase and an aqueous phase, and reusing at least part of the aqueous phase. The invention is also related to a device for performing the above process.
摘要翻译：提供了形成环氧化合物的装置和方法。在一个实施方案中，提供了制造环氧化物的方法，包括加入氧化剂，水溶性锰配合物和末端烯烃以形成多相反应混合物，使末端烯烃与氧化剂在多相反应混合物中反应，至少一个有机相在水溶性锰络合物存在下反应，将反应混合物分离成至少一个有机相和水相，并重新使用至少部分水相。本发明还涉及用于执行上述过程的装置。

7. 发明公开

EP2531496A1 MANUFACTURE OF AN EPOXYETHYL CARBOXYLATE OR GLYCIDYL CARBOXYLATE 有权转让
标题翻译： HERSTELLUNG VON环氧乙烯羧酸酯谷氨酰胆碱
公开(公告)号：EP2531496A1
公开(公告)日：2012-12-12
申请号：EP11701942.2
申请日：2011-01-26
申请人： Momentive Specialty Chemicals Research Belgium S.A.
发明人： MUPPA, Prasad , POSTMA, Ron , SCHOOLDERMAN, Caspar , RENS, Sandra , STOITSAS, Kostas
IPC分类号： C07D301/12 , C07D303/16
CPC分类号： C07D301/12 , C07D303/48
摘要： The invention relates to a process for the manufacture of an epoxyethyl carboxylate or glycidyl carboxylate, including reacting a vinyl carboxylate or an allyl carboxylate using an oxidant and a water-soluble manganese complex in an aqueous reaction medium, and the water-soluble manganese complex comprises an oxidation catalyst, characterized in that the water-soluble manganese complex is a mononuclear species of the general formula (I): [LMnX
3 ]Y, or a binuclear species of the general formula (II): [LMn(μ-X)
3 MnL]Y
n , wherein Mn is a manganese; L is a ligand and each L is independently a polydentate ligand, each X is independently a coordinating species and each μ-X is independently a bridging coordinating species, Y is a non-coordinating counter ion, and wherein the epoxidation is carried out at a pH in the range of from 1.0 to 7.0.
摘要翻译：本发明涉及通过使用氧化剂，优选过氧化氢和锰络合物催化氧化乙烯基或烯丙基羧酸酯来制备环氧乙基羧酸酯或羧甲基缩水甘油酯的方法，其中催化氧化在含水反应介质中进行，包括使用少于10体积％共溶剂的水，其中使用水溶性锰络合物作为氧化催化剂，其特征在于所述水溶性锰络合物是通式（1）的单核物种：€ƒ€€ ƒ€ƒ€ƒ€ƒ€ƒ[LMnX 3] Y€ƒ€ƒ€ƒ€ƒ（I）或通式（II）的双核物种：€ƒ€ƒ€ƒ€ ƒ€ƒ€ƒ€ƒ[LMn（μ-X）3 MnL] Y 2€ƒ€ƒ€ƒ（ƒ）其中Mn是锰; L或每个L独立地是多齿配体，每个X独立地是配位物质，每个μ-X独立地是桥连配位物质，而Y是氧化稳定的抗衡离子，并且其中环氧化在范围从1.0。到7.0。本发明还涉及酸部分中具有5-30个碳原子的新酸的环氧乙酯。

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