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    • 3. 发明公开
    • Transparent adhesive sheet and image display device
    • Transparente Haftfolie und Bildanzeigevorrichtung
    • EP2650340A2
    • 2013-10-16
    • EP13175855.9
    • 2009-10-08
    • MITSUBISHI PLASTICS, INC.
    • Inenaga, Makoto
    • C09J7/00B32B27/00G02F1/1335B32B7/06B32B7/12B32B27/08B32B27/30B32B27/36G06F3/041G06F3/045B32B7/02G02F1/1333
    • C09J7/02B32B7/02B32B7/06B32B7/12B32B27/08B32B27/30B32B27/36B32B2307/412B32B2457/20C09J7/00C09J7/10C09J2201/134C09J2201/36C09J2203/318C09J2433/00G02F1/13338G02F2201/50G02F2202/28G06F3/041G06F3/045Y10T428/1462Y10T428/24942Y10T428/24967Y10T428/28Y10T428/2839
    • Provided is a novel transparent adhesive sheet with which the cut edge is not sticky over time when a laminated body that has been bonded via the adhesive sheet is cut, which can be adhered without generating residual air bubbles, even when the surface of an adherend is uneven, and which can be adhered without foaming, even when the adherend is a material such as plastic that can generate outgas. Suggested is a transparent adhesive sheet for an image display device comprising:
      one or more layers of a first adhesive layer; and
      one or more layers of of a second adhesive layer,
      wherein the first and second adhesive layers exhibit different viscoelastic behaviors and the layers are integrally laminated, and;
      wherein the first adhesive layer is comprised of a composition comprising acrylic acid ester and cross-linking agents which are multifunctional organic functional group resins having two or more organic functional groups selected from an isocyanate group, an epoxy group, a melamine group, a glycol group, a siloxane groups and an amine group, and;
      wherein a dynamic shear storage modulus G' (measured with use of a device for measuring viscoelasticity in a shear method under the conditions Jig: Φ25 mm parallel plate, strain level: 0.5%, frequency: 1 Hz, temperature: -70 to 200 °C (measured at 3 °C/min temperature elevation rate from -70 °C), sample thickness: 250 µm) as to the adhesive sheet integrally laminated is within the ranges described below when measured with a 1 Hz frequency temperature dispersion:
      • G'(20°C) is 2 x 10 4 to 5 x 10 5 Pa; and
      • G'(150°C) is 1 x 10 4 to 1 x 10 5 Pa.
    • 提供了一种新颖的透明粘合片,当经过粘合片粘合的层叠体被切割时,切割边缘不会随着时间的推移而粘附,即使当被粘物的表面为 即使当被粘物是能够产生废气的诸如塑料的材料时,也可以粘附而不发泡。 提出一种用于图像显示装置的透明粘合片,其包括:一层或多层第一粘合剂层; 和一层或多层第二粘合剂层,其中第一和第二粘合剂层表现出不同的粘弹性行为,并且层被一体层压, 其特征在于,所述第一粘合剂层由包含丙烯酸酯和交联剂的组合物构成,所述组合物为具有选自异氰酸酯基,环氧基,三聚氰胺基,二醇基中的两个以上有机官能团的多官能有机官能团树脂 ,硅氧烷基和胺基,和 其中动态剪切储能模量G'(使用剪切方法测量粘弹性的装置,在平行平板上的| 25mm平行板,应变水平:0.5%,频率:1Hz,温度:-70-200 当以1Hz频率的温度分散度测量时,整体层压的粘合片的℃(以3℃/分钟的升温速度从-70℃测量),样品厚度:250μm)在下述范围内 ¢G'(20℃)为2×10 4〜5×10 5 Pa; 和G'(150℃)为1×10 4〜1×10 5 Pa。