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    • 4. 发明公开
    • POLYCARBONATE RESIN COMPOSITION AND MOLDED OBJECT THEREOF
    • POLYCARBONATHARZZUSAMMENSETZUNG UND FORMARTIKEL DARAUS
    • EP2395052A1
    • 2011-12-14
    • EP10738387.9
    • 2010-01-07
    • Mitsubishi Engineering-Plastics Corporation
    • MONDEN, Toshiki
    • C08L69/00
    • C08K5/549C08G77/60C08K5/42C08K5/5419C08L27/12C08L69/00C08L83/16C08L83/00
    • In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.
    • 在含有聚碳酸酯树脂和聚碳硅烷化合物的聚碳酸酯树脂组合物中,使用聚碳硅烷化合物改性聚碳酸酯树脂组合物的表面性能,而不会对聚碳酸酯树脂的固有特性(例如透明性,耐热性和机械性能)产生不利影响 ,例如耐冲击性。 含有100质量份聚碳酸酯树脂,0.001〜1质量份金属盐化合物和0.005〜5质量份聚碳硅烷化合物的聚碳酸酯树脂组合物显着改善了阻燃性和高透明性,并且导致显着降低的除气 和模具污垢,而不损失耐冲击性和耐热性。
    • 8. 发明公开
    • FLAME-RETARDANT AROMATIC POLYCARBONATE RESIN COMPOSITION
    • 使用非卤素系金属盐的芳族磺酸作为阻燃剂FOR芳香族聚碳酸酯树脂组合物含
    • EP2103654A1
    • 2009-09-23
    • EP07849883.9
    • 2007-12-25
    • Mitsubishi Engineering-Plastics Corporation
    • MONDEN, ToshikiNAKANO, Hiroshi
    • C08L69/00C08K5/42
    • C08K5/42C08L69/00
    • The present invention relates to a polycarbonate resin composition having an excellent balance between various properties such as flame retardancy, transparency, hue and thermal stability. The flame-retardant aromatic polycarbonate resin composition comprises 100 parts by weight of an aromatic polycarbonate resin; and 0.001 to 0.5 parts by weight of a non-halogen-based aromatic sulfonic acid metal salt compound represented by the following general formula (1):

      wherein R 1 is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms; R 2 is a hydrogen atom, an alkyl group having 1 to 7 carbon atoms, an aralkyl group having 6 to 20 carbon atoms or an aryl group having 5 to 15 carbon atoms; and M is rubidium (Rb), cesium (Cs) or francium (Fr).
    • 本发明涉及一种具有各种性能之间的平衡优良的聚碳酸酯树脂组合物:如阻燃性,透明性,色相和热稳定性。 的阻燃性芳香族聚碳酸酯树脂组合物包括100份(重量)的芳族聚碳酸酯树脂; 和0.001〜0.5重量份由下述通式(1)表示的非卤素类芳香族磺酸金属盐化合物的:worin R 1为氢原子或烷基具有1至10个碳原子基团; R 2为氢原子,在具有1-7个碳原子芳烷基具有6至20个碳原子或在具有5至15个碳原子的芳基基团的烷基; 和M是铷(Rb),铯(Cs)或钫(FR)。