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    • 7. 发明公开
    • Spectrally sensitized silver halide photographic materials
    • Silekhalalsidibilisierte photoische Silberhalogenidmaterialien。
    • EP0607478A1
    • 1994-07-27
    • EP93100646.4
    • 1993-01-18
    • MINNESOTA MINING AND MANUFACTURING COMPANY
    • Delprato, IvanoVacca, AlbertoMana, Stefano
    • G03C1/29G03C1/26
    • G03C1/29G03C1/26
    • The present invention refers to a silver halide photographic material containing a support having coated thereon at least a silver halide emulsion layer spectrally sensitized with a first sensitizing dye according to the formula (I):

      wherein Z₁ and Z₂ each independently represents the atoms necessary to complete a substituted or unsubstituted 5-membered nitrogen-containing heterocyclic group; R and R₁ each independently represents a substituted or unsubstituted alkyl group; Q and Q₁ in combination represent the atoms required to complete a thiazolidinone nucleus; L₁, L₂ and L₃ each represents a methine group or a substituted methine group of the formula:

      wherein R₂ is an optionally substituted alkyl group having 1 to 6 carbon atoms or an optionally substituted aryl group having 6 to 10 carbon atoms; X⁻ is an anion and each of m, n and p is 0 or 1, provided that p is 0 when the dye forms an intramolecular salt;
      and a second sensitizing dye according to the formula (II):

      wherein Z₃ represents the atoms necessary to complete a 6-membered nitrogen-containing heterocyclic group; Z₄ represents the atoms necessary to complete a 5-membered nitrogen-containing heterocyclic group; R₃ and R₄ each represents a hydrogen atom, an alkyl group or a phenyl group; R, R₁, m, n, X and p have the same meaning of formula (I).
      The silver halide photographic material has the advantage to have a broad sensitivity in the red portion of the spectrum. It can be exposed to laser beam sources in the range of 600-700 nm.
    • 本发明涉及一种含有载体的卤化银照相材料,其上至少涂覆有根据式(I)的第一增感染料光谱增感的卤化银乳剂层:其中Z 1和Z 2各自独立地表示原子 必要的是完成取代或未取代的5元含氮杂环基团; R和R 1各自独立地表示取代或未取代的烷基; Q和Q1组合表示完成噻唑烷酮核所需的原子; L1,L2和L3各自表示下式的次甲基或取代的次甲基:其中R2是任选取代的具有1至6个碳原子的烷基或任选取代的具有6至10个碳原子的芳基; X - 是阴离子,m,n和p各自为0或1,条件是当染料形成分子内盐时p为0; 和根据式(II)的第二增感染料:其中Z 3表示完成6元含氮杂环基团所必需的原子; Z4表示完成5元含氮杂环基所必需的原子; R3和R4各自表示氢原子,烷基或苯基; R,R 1,m,n,X和p具有与式(I)相同的含义。 卤化银照相材料具有在光谱的红色部分具有宽的灵敏度的优点。 它可以暴露于600-700nm范围内的激光束源。