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1. 发明公开

EP3112411A4 GLOVE AND GLOVE COMPOSITION 有权转让
标题翻译： HANDSCHUH UND HANDSCHUHZUSAMMENSETZUNG
公开(公告)号：EP3112411A4
公开(公告)日：2017-08-09
申请号：EP15755812
申请日：2015-02-27
申请人： MIDORI ANZEN CO LTD , KOSSAN SDN BHD
发明人： ENOMOTO NORIHIDE , OGAWA TAICHI , SATO YUSUKE , LIM LAWRENCE SIAU TIAN , LEE SEEK PING , ONG ENG LONG
IPC分类号： C08L13/02 , A41D19/00 , A41D19/04 , C08K3/22 , C08L9/04
CPC分类号： C08L9/04 , A41D19/0082 , A41D2600/20 , C08K3/22 , C08L2201/52 , C08L2205/02 , C08L13/02
摘要： An emulsion composition includes (1) a carboxylated acrylonitrile butadiene elastomer containing an acrylonitrile residue in an amount of 23 to 30 wt% and an unsaturated carboxylic acid residue in an amount of 3 to 8 wt%, and (2) a polyacrylonitrile butadiene elastomer containing an acrylonitrile residue in an amount of 20 to 50 wt% and having a weight average molecular weight (in terms of styrene) of 7,000 to 50,000. The weight ratio of the component (1)/ the component (2) is from 70/30 to 90/10.
摘要翻译：一种乳液组合物，其中含有（1）含有23〜30重量％的丙烯腈残基和3〜8重量％的不饱和羧酸残基的羧化丙烯腈丁二烯弹性体，和（2）含有丙烯腈丁二烯弹性体 20〜50重量％的丙烯腈残基，重均分子量（以苯乙烯计）为7,000〜50,000。组分（1）/组分（2）的重量比为70/30至90/10。

2. 发明公开

EP2623529A4 ELASTOMER RUBBER AND ELASTOMER PRODUCT THAT DO NOT USE VULCANIZATION ACCELERATOR OR SULFUR 有权
标题翻译：弹性体合成橡胶及设备无硫化促进剂或硫
公开(公告)号：EP2623529A4
公开(公告)日：2014-06-18
申请号：EP11829443
申请日：2011-09-30
申请人： KOSSAN SDN BHD , MIDORI ANZEN CO LTD
发明人： KHOO SIONG HUI , LIM LAWRENCE SIAU TIAN , LEE SEEK PING , ONG ENG LONG , ENOMOTO NORIHIDE
IPC分类号： C08F236/06 , C08F2/44 , C08K3/22 , C08L9/02 , C08L33/20
CPC分类号： C08L9/02 , A41D19/0055 , C08K3/22 , C08K5/095 , C08L9/00 , C08L13/00
摘要： An elastomer composition comprising, an emulsion which comprises 25-30 weight % of acrylonitrile, 62-71 weight % of butadiene and 4-8 weight % of unsaturated carboxylic acid (total 100 weight %), wherein crosslink is formed by a bond through at least a part of substituent which is possessed by said unsaturated carboxylic acid, and residual substituent of at least one part of substituent which is possessed by said unsaturated carboxylic acid is left in state of free, further Mooney viscosity (ML (1+4) (100°C)) of the crosslinked product is 100-220, wherein thin film gloves composed of said elastomer does not contain sulfur which is a crosslinking agent and sulfur composition which is a vulcanization accelerator, thickness is 0.05-0.15mm, gloves swelling ratio at gloves formation is 240-320, tensile stress is 22-35 MPa, elongation to break is 480-620% and tensile stress at 500% elongation is 15-35 MPa.

3. 发明公开

EP2622976A4 VULCANIZATION ACCELERATOR- AND SULFUR-FREE ELASTOMER RUBBER GLOVE FOR CLEAN ROOMS 有权
标题翻译： VULKANISIERUNGSBESCHLEUNIGER UND SCHWEFELFREIER ELASTOMER-GUMMIHANDSCHUHFÜRREINRÄUME
公开(公告)号：EP2622976A4
公开(公告)日：2016-09-28
申请号：EP11829442
申请日：2011-09-30
申请人： KOSSAN SDN BHD , MIDORI ANZEN CO LTD
发明人： KHOO SIONG HUI , LIM LAWRENCE SIAU TIAN , LEE SEEK PING , ONG ENG LONG , ENOMOTO NORIHIDE
IPC分类号： A41D19/00 , A41D19/04 , B29D99/00 , C08F2/44 , C08F236/06 , C08F236/14 , C08K3/22 , C08L9/02 , C08L13/00 , C08L33/20
CPC分类号： A41D19/0055 , A41D19/0062 , B29D99/0067 , C08F236/14 , C08K3/22 , C08L9/02 , C08L13/00
摘要： A gloves formed from elastomer comprising 25-30 weight% of acrylonitrile, 62-71 weight % of butadiene and 4-8 weight % of unsaturated carboxylic acid (total 100 weight%), wherein crosslink is formed by a bond through at least a part of substituent which is possessed by said unsaturated carboxylic acid, and residual substituent of at least one part of substituent possessed by said unsaturated carboxylic acid is crosslinked by bivalent metal, said elastomer does not contain sulfur which is a crosslinking agent and sulfur composition which is a vulcanization accelerator, Mooney viscosity (ML (1+4) (100°C)) of said elastomer crosslinked by a bond of at least one part of substituent possessing said unsaturated carboxyl group is 100-220, and thin film gloves prepared from said elastomer does not contain sulfur which is a crosslinking agent and sulfur composition which is a vulcanization accelerator, and thickness of the gloves is 0.05-0.15mm, glove swelling ratio at formation of the gloves is 240-320, tensile stress of the gloves is 22-35 MPa, elongation to break of the gloves is 480-620% and tensile stress at 500% elongation of the gloves is 15-35 MPa, further, surface of the glove which contacts with a hand of a user is in a state of loosing tackiness, surface of the glove which contacts with an object at working is smooth, metal or metallic salt contained in the glove as impurities are eluted and amount of content of metal, metallic salt and anion contained in the glove is decreased.
摘要翻译：由弹性体形成的手套包含25-30重量％的丙烯腈，62-71重量％的丁二烯和4-8重量％的不饱和羧酸（总计100重量％），其中交联通过粘结通过至少一部分形成的所述不饱和羧酸所具有的取代基，所述不饱和羧酸所具有的至少一部分取代基的残基取代基被二价金属交联，所述弹性体不含硫作为交联剂，硫组成为硫化促进剂，由具有所述不饱和羧基的至少一部分取代基的键交联的所述弹性体的门尼粘度（ML（1 + 4）（100℃））为100-220，由所述弹性体制备的薄膜手套不含作为硫化促进剂的交联剂和硫成分的硫，手套的厚度为0.05〜0.15mm，手套形成时的手套膨胀率为240-320，手套的拉伸应力为22-35MPa，手套伸长率为480-620％，手套伸长500％时的拉伸应力为15-35MPa，手套表面为与使用者的手的接触处于松散的粘性状态，杂质被洗脱时手套中包含的光滑的金属或金属盐与手套的接触表面，金属，金属盐的含量并且手套中所含的阴离子减少。

4. 发明公开

EP2891668A4 GLOVE HAVING EXCELLENT CHEMICAL RESISTANCE, AND COMPOSITION FOR SAID GLOVE 有权转让
标题翻译：手套随着对这种手套耐化学性能优异及组成
公开(公告)号：EP2891668A4
公开(公告)日：2016-03-30
申请号：EP13833395
申请日：2013-08-30
申请人： KOSSAN SDN BHD
发明人： ENOMOTO NORIHIDE , OGAWA TAICHI , LIM LAWRENCE SIAU TIAN , LEE SEEK PING , ONG ENG LONG
IPC分类号： C08F236/06 , A41D19/00 , C08K3/22 , C08K5/00 , C08L13/00
CPC分类号： C08L13/00 , A41D19/0055 , C08F236/06 , C08F236/12 , C08K5/0025 , C08L2203/02 , C08L2205/025

5. 发明公开

EP2507313A4 ELASTOMERIC RUBBER AND RUBBER PRODUCTS WITHOUT THE USE OF VULCANIZING ACCELERATORS AND SULFUR 有权
标题翻译：合成橡胶及橡胶制品，而无需使用硫化促进剂和硫
公开(公告)号：EP2507313A4
公开(公告)日：2016-03-02
申请号：EP09851897
申请日：2009-12-01
申请人： KOSSAN SDN BHD
发明人： KHOO SIONG HUI , LIM LAWRENCE SIAU TIAN , LEE SEEK PING , ONG ENG LONG
IPC分类号： C08L13/02 , A41D19/00 , B29C41/14 , C08J5/02 , C08K3/22 , C08L9/04
CPC分类号： C08J5/02 , C08J2309/04 , C08J2313/02 , C08K3/22 , C08L9/04
摘要： A composition for producing an elastomeric thin film comprising a carboxylated acrylonitrile polybutadiene latex which is vulcanized without the use of conventional sulphur and accelerators thereby reducing the possibility of contacting immediate Type I hypersensitivity and delay Type IV hypersensitivity caused by the presence of natural rubber latex proteins and accelerators respectively. The dipping process for making gloves by using a latex composition provided by: premixing carboxylated acrylonitrile polybutadiene latex with methacrylic acid, or alternatively using a self-crosslinked latex, adding zinc oxide, adjusted to 9 to 10 of the pH level, and diluted with water to obtain 18% to 30% by weight of total solid content; dipping the glove former into the composition to form a layer of thin film of the latex composition on the former; drying the thin latex film on the former and crosslinking the latex film on the former.
摘要翻译：一种用于在弹性体薄膜生产包括羧化的丙烯腈聚丁二烯胶乳组合物，所有这些是在不使用传统的硫的硫化剂和促进剂，从而减少接触立即I型超敏性和延迟延迟性过敏反应由天然橡胶胶乳蛋白的存在而引起的可能性和分别加速器。用于通过使用所提供的一种胶乳组合物使得手套浸渍过程：预混合羧化的丙烯腈聚丁二烯胶乳与甲基丙烯酸，或可替代地使用自交联的胶乳，加入氧化锌，调节至9的pH值水平的10，并用水稀释以获得18％至30％重量的总固体含量的; 浸渍手套模型入组合物，从而在前者的胶乳组合物的薄膜层; 干燥该胶乳薄膜对前和交联的成膜剂的胶乳。

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