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    • 6. 发明公开
    • A reversible electrode
    • 可逆的Elektrode。
    • EP0569038A1
    • 1993-11-10
    • EP93107486.8
    • 1993-05-07
    • MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.
    • Uemachi, HiroshiSato, YoshikoSotomura, TadashiTakeyama, Kenichi
    • H01M4/60H01M10/40
    • H01M4/60H01M6/181
    • A reversible electrode of the present invention includes, as a main component thereof, a thiourea compound represented by the following formula (I):

      (where R¹, R², R³, and R⁴ are independently selected from the group consisting of hydrogen, halogen, a hydroxyl group, a cyano group, a carboxyl group, an amino group, an aryl group, an allyl group, an alkyl group, an alkoxy group, a group containing a mercapto group, a group containing a phenyl group, a group having a hetero ring containing O, and a group having a hetero ring containing N) or a polymer having the thiourea compound as its main polymer unit; the reversible electrode utilizing reversible electrochemical oxidation-reduction of sulfur atoms of the thiourea compound or the polymer.
    • 本发明的可逆电极作为其主要成分,含有下述式(I)表示的硫脲化合物:(其中R 1,R 2,R 3,R 3, 4“独立地选自氢,卤素,羟基,氰基,羧基,氨基,芳基,烯丙基,烷基,烷氧基,含有 巯基,含苯基的基团,含有O的杂环的基团和含有N的杂环的基团)或具有硫脲化合物作为主要聚合物单元的聚合物; 利用硫脲化合物或聚合物的硫原子的可逆电化学氧化还原的可逆电极。