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1. 发明公开

EP2321363A4 TELECHELIC OLEFIN METATHESIS POLYMERS FROM RENEWABLE FEEDSTOCKS 有权
标题翻译：电话OLEFINMETATHESEPOLYMERE AUS NACHWACHSENDEN ROHSTOFFEN
公开(公告)号：EP2321363A4
公开(公告)日：2012-11-28
申请号：EP09808527
申请日：2009-08-21
申请人： MATERIA INC
发明人： JONES SIMON C , MOTAMEDI FARSHAD J , WANG LI-SHENG , EDGECOMBE BRIAN , GIARDELLO MICHAEL A
IPC分类号： C08G61/00 , C08F4/42 , C08G61/08
CPC分类号： C08G61/08 , C08G2261/3322 , C08G2261/418
摘要： Olefin metathesis polymerization reactions are disclosed, and more particularly ring-opening metathesis polymerization of cyclic olefins with olefinic compounds, such as are derived from seed oils and the like, to form telechelic polymers. In one aspect, a method is provided for carrying out a catalytic ring-opening metathesis polymerization reaction, comprising contacting at least one olefinic compound with at least one cyclic olefin, in the presence of a ruthenium alkylidene olefin metathesis catalyst under conditions effective to allow ring-opening metathesis polymerization of the cyclic olefin, whereby the cyclic olefin polymer formed is terminated with the olefinic compound. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial chemistry.
摘要翻译：公开了烯烃易位聚合反应，更具体地说，环烯烃与烯烃化合物的衍生自种子油等的开环易位聚合反应形成遥爪聚合物。在一个方面，提供了一种进行催化开环易位聚合反应的方法，包括在钌亚烷基烯烃复分解催化剂存在下使至少一种烯烃化合物与至少一种环烯烃接触，所述条件有效地允许环开环环烯烃的易位聚合，由此形成的环烯烃聚合物用烯烃化合物终止。本发明可用于催化，有机合成，聚合物化学和工业化学领域。

2. 发明公开

EP2721106A4 ADHESION PROMOTERS AND GEL-MODIFIERS FOR OLEFIN METATHESIS COMPOSITIONS 有权
标题翻译：粘结促进剂和凝胶MODIFIERS烯烃复分解组合物
公开(公告)号：EP2721106A4
公开(公告)日：2015-09-23
申请号：EP12801260
申请日：2012-06-17
申请人： MATERIA INC
发明人： WANG LI-SHENG , STEPHEN ANTHONY R , BOOTHE PAUL W , SCHULZE TESSA , GIARDELLO MICHAEL A , TRIMMER MARK S , CRUCE CHRISTOPHER J , MOTAMEDI FARSHAD J , EDGECOMBE BRIAN
IPC分类号： C08G61/08 , C08F32/02 , C08K5/00 , C08K5/14 , C08K5/16 , C08K5/29 , C08L45/00 , C08L65/00
CPC分类号： C03C25/30 , C08F32/02 , C08G61/08 , C08G2261/3325 , C08G2261/418 , C08K5/0025 , C08K5/14 , C08K5/29 , C08K2201/014 , C08L65/00
摘要： This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials, pre-treating substrate materials to improve the adhesion of resin compositions to the substrate materials, and/or controlling gel formation of resin compositions. More particularly, the invention relates to compositions and methods for improving the adhesion of ring opening metathesis polymerization (ROMP) compositions to substrate materials using adhesion promoters containing isocyariate groups in a resin composition. The invention also relates to methods for improving the adhesion of resin compositions to substrate materials by pre-treating substrate materials with adhesion promoters containing isocyanate groups. The invention further relates to a method of providing a gel-modified ROMP composition, in which a hydroperoxide is added to a ROMP polymerizable resin composition in order to control gel formation of the polymerizing resin. An improved ROMP composition is further disclosed, comprising a cyclic olefin, a ROMP metathesis catalyst, an adhesion promoter, and an added hydroperoxide gel modifier. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

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