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    • 8. 发明公开
    • METHOD FOR PREPARING METAL OXIDE-SILICA COMPOSITE AEROGEL AND METAL OXIDE-SILICA COMPOSITE AEROGEL PREPARED BY MEANS OF SAME
    • 制备金属氧化物 - 硅酸盐复合气凝胶和金属氧化物 - 硅酸盐复合气凝胶的方法
    • EP3305725A1
    • 2018-04-11
    • EP16803734.9
    • 2016-06-01
    • LG Chem, Ltd.
    • KIM, Jong HunLEE, Je Kyun
    • C01B33/14C01D1/02C01F5/06B01J20/04
    • Provided are a method of preparing a metal oxide-silica composite aerogel which includes preparing a silicate solution by dissolving water glass at a concentration of 0.125 M to 3.0 M, after adding and mixing a metal salt solution having a metal ion concentration of 0.125 M to 3.0 M to the silicate solution, precipitating metal oxide-silica composite precipitates by adjusting a pH of a resulting mixture to be in a range of 3 to 9, and separating and drying the metal oxide-silica composite precipitates, wherein the metal salt solution includes a magnesium (Mg)-containing metal salt in an amount such that an amount of magnesium ions is greater than 50 mol% based on a total mole of metal ions in the metal salt solution, and a metal oxide-silica composite aerogel having low tap density and high specific surface area prepared by the method.
    • 本发明提供一种金属氧化物 - 二氧化硅复合型气凝胶的制备方法,其包括:将水玻璃以0.125M〜3.0M的浓度溶解后,添加金属离子浓度为0.125M的金属盐溶液, 通过将所得混合物的pH调节至3至9的范围内,并将金属氧化物 - 二氧化硅复合沉淀物分离并干燥,从而沉淀出金属氧化物 - 二氧化硅复合沉淀物,其中金属氧化物 - 二氧化硅复合沉淀物包括3.0M 基于金属盐溶液中的金属离子的总摩尔数,镁离子的量大于50摩尔%的含镁(Mg)金属盐和具有低抽头的金属氧化物 - 二氧化硅复合气凝胶 密度和由该方法制备的高比表面积。
    • 9. 发明公开
    • METHOD FOR PREPARING HYDROPHOBIC METAL OXIDE-SILICA COMPOSITE AEROGEL, AND HYDROPHOBIC METAL OXIDE-SILICA COMPOSITE AEROGEL PREPARED THEREBY
    • 制备疏水性金属氧化物 - 二氧化硅复合气凝胶的方法及其制备的疏水性金属氧化物 - 二氧化硅复合气凝胶
    • EP3202712A1
    • 2017-08-09
    • EP16858476.1
    • 2016-10-18
    • LG Chem, Ltd.
    • JEON, Hyun WooKIM, Jong HunLEE, Je Kyun
    • C01B33/158
    • C01B33/1585B01J13/0091C01B33/158C01P2006/10C01P2006/12
    • The present invention relates to a method of preparing a hydrophobic metal oxide-silica composite aerogel, in which a degree of hydrophobicity may be controlled while having a high specific surface area and a low tap density, and a hydrophobic metal oxide-silica composite aerogel prepared thereby. The preparation method according to the present invention may not only have excellent productivity and economic efficiency due to a relatively simpler preparation process and shorter preparation time than the related art, but may also perform an effective surface modification reaction by using a small amount of a surface modifier. Thus, since the surface modification reaction may be easily performed by using only a very small amount of the surface modifier, a hydrophobic metal oxide-silica composite aerogel containing about 1 wt% to 2 wt% of carbon may be prepared.
    • 本发明涉及一种制备疏水性金属氧化物 - 二氧化硅复合气凝胶的方法,其中可以控制疏水性程度,同时具有高比表面积和低堆积密度,并且制备疏水性金属氧化物 - 二氧化硅复合气凝胶 从而。 根据本发明的制备方法不仅可以由于制备工艺相对简单且制备时间短于相关技术而具有优异的生产率和经济效率,而且还可以通过使用少量表面进行有效的表面改性反应 修改。 因此,由于表面改性反应可以通过仅使用非常少量的表面改性剂容易地进行,所以可以制备含有约1重量%至2重量%的碳的疏水性金属氧化物 - 二氧化硅复合气凝胶。