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    • 1. 发明公开
    • LIVING RADICAL POLYMERIZATION INITIATOR, METHOD FOR PRODUCING POLYMER, AND POLYMER
    • 活性自由基聚合引发剂,生产聚合物的方法和聚合物
    • EP3190131A1
    • 2017-07-12
    • EP15838864.5
    • 2015-08-07
    • Kyoto UniversityGodo Shigen Co., Ltd.
    • GOTO, AtsushiMIYAMOTO, MichihikoKOMATSU, HirotoYAMAGUCHI, YuJITSUKAWA, Takuya
    • C08F4/00C07C69/63C07C69/65C07C69/73C08F293/00
    • A living radical polymerization initiator represented by the following general formula (1), which uses a living radical polymerization initiator that contains, as initiating groups for reactions, two halogen atoms different from each other in reactivity, and which enables different living radical polymerization reactions to proceed with respect to the respective initiating groups: herein, R 1 represents an organic group which is linkable with two or more other organic groups, and which is selected from an aliphatic group having 1 to 12 carbon atoms, an aromatic group, a carbonyl group, a sulfonyl group and an organic group obtained by combining two or more of these groups, R 2 , R 3 , R 4 and R 5 are a hydrogen atom or an organic group selected from an aliphatic group having 1 to 12 carbon atoms, an aromatic group, a carbonyl group, a carboxyl group and a sulfonyl group, X and Y are a halogen atom, m and n are an integer of 1 or more, and the X and Y are in a state in which they are different from each other in reactivity with a monomer.
    • 由以下通式(1)表示的活性自由基聚合引发剂,其使用活性自由基聚合引发剂,该活性自由基聚合引发剂包含作为反应的引发基团的两个反应性彼此不同的卤素原子,并且能够进行不同的活性自由基聚合反应 对于各自的引发基团进行:在此,R 1表示可与两个或更多个其他有机基团连接的并且选自具有1至12个碳原子的脂族基团,芳族基团,羰基, 磺酰基和通过组合两个或更多个这些基团获得的有机基团,R 2,R 3,R 4和R 5是氢原子或选自具有1-12个碳原子的脂族基团的有机基团,芳族基团,羰基 基团,羧基和磺酰基,X和Y是卤原子,m和n是1或更大的整数,并且X和Y处于不同的状态 t与单体的反应性。