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1. 发明公开

EP2439214A1 POLYMERIZATION INITIATOR FOR LIVING RADICAL POLYMERIZATION 有权
标题翻译：聚合物酸性聚合物LEBENDER RADIKALE
公开(公告)号：EP2439214A1
公开(公告)日：2012-04-11
申请号：EP10783160.4
申请日：2010-06-03
申请人： Kyoto University
发明人： GOTO, Atsushi , KIM, Jeong Sik , TSUJII, Yoshinobu , FUKUDA, Takeshi
IPC分类号： C08F4/40 , C08F2/00
CPC分类号： C08F2/38 , C08F4/04 , C08F4/40 , C08F293/005
摘要： Provided is a method of living radical polymerization which does not necessitate complicated and intricate synthesis of a dormant species and which is highly efficient. A halogenated derivative compound is used as a dormant species for initiating living radical polymerization. The derivative compound is obtained by halogenating an alcohol compound having a non-conjugated structure or an amine compound having a non-conjugated structure with a halogenating agent capable of halogenating an alcohol or amine. A radical produced by elimination of halogen from the halogenated derivative compound is allowed to react with the unsaturated bond of the monomer. Thus, the monomer, which has a radical-reactive unsaturated bond, is polymerized by living radical polymerization. Preferably, the halogenating agent is a compound (NIS or the like) which also has a function as a catalyst.
摘要翻译：提供了一种活性自由基聚合的方法，其不需要复杂且复杂的合成休眠物质并且是高效的。卤化衍生物用作起始活性自由基聚合的休眠物质。衍生化合物是通过使具有非共轭结构的醇化合物或具有非共轭结构的胺化合物与能够卤化醇或胺的卤化剂卤化而得到的。通过从卤化衍生物化合物中除去卤素而产生的自由基与单体的不饱和键反应。因此，具有自由基反应性不饱和键的单体通过活性自由基聚合而聚合。优选地，卤化剂是还具有催化剂功能的化合物（NIS等）。

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