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    • 9. 发明公开
    • POLYPROPYLENE FIBER, METHOD OF PRODUCING THE SAME AND UTILIZATION OF THE SAME
    • 聚丙烯,VERFAHREN ZU IHRER HERSTELLUNG UND IHRE ANWENDUNG
    • EP2130954A1
    • 2009-12-09
    • EP08722686.6
    • 2008-03-24
    • Kuraray Co., Ltd.
    • KATAYAMA, TakashiIWASAKI, YoshihiroNISHIYAMA, Masakazu
    • D01F6/06B29B11/16C04B16/06C04B28/02C08K7/02C08L23/12C08L101/00D02G3/44D02J1/22D03D15/00D04H1/42D07B1/02
    • D01F6/06B29K2023/12B29K2223/12B29L2031/707C04B16/0633C04B28/02C08L23/10D02J1/22D04H1/4291D07B1/02D07B2201/2006D07B2201/2007D07B2201/2009D07B2205/201Y10T428/29Y10T428/2913Y10T428/2976Y10T442/10Y10T442/3854Y10T442/40Y10T442/674C08L2666/02D07B2801/10
    • The present invention aims to provide a polypropylene fiber (PP fiber) excellent in strength, heat resistance, and water-absorption properties, a method of producing the same, and a hydraulic composition, a rope, a sheet-shaped fiber structure, and a composite material with an organic polymer each using the PP fiber. The present invention provides: a PP fiber having a fiber strength of 7 cN/dtex or more and having either or both of (i) DSC properties such that the endothermic peak shape by DSC is a single shape having a half width of 10°C or lower and the melt enthalpy change (ΔH) is 125 J/ g and (ii) irregular properties such that the single fiber fineness is 0.1 to 3 dtex and irregularities are formed on the surface, the irregularities having an average interval of 6.5 to 20 µm and an average height of 0.35 to 1 µm as a result of alternate presence of a protruded portion having a large diameter and a non-protruded portion having a small diameter along its fiber axis; a method of producing the PP fiber by pre-drawing an undrawn PP fiber having an IPF of 94% or more at 120 to 150°C at a drawing magnification of 3 to 10 times, and then post-drawing the resultant at 170 to 190°C and a drawing magnification of 1.2 to 3.0 times under the conditions of a deformation rate of 1.5 to 15 times/min and a draw tension of 1. 0 to 2.5 cN/dtex; and a hydraulic composition, a rope, a sheet-shaped fiber structure, and a composite material with an organic polymer each using the PP fiber.
    • 本发明的目的在于提供强度,耐热性和吸水性优异的聚丙烯纤维(PP纤维)及其制造方法,水硬性组合物,绳索,片状纤维结构体和 具有各自使用PP纤维的有机聚合物的复合材料。 本发明提供一种PP纤维,其纤维强度为7cN / dtex以上,并且具有(i)DSC性质中的任一者或两者,使得DSC的吸热峰形状为半宽度为10℃的单一形状 或更低,熔体焓变(H)为125J / g,(ii)单纤维纤度为0.1〜3dtex的不均匀性,表面形成凹凸,平均间隔为6.5〜 由于交替存在具有大直径的突出部分和沿其纤维轴线具有小直径的非突出部分的结果,平均高度为0.35至1μm,平均高度为0.35μm至1μm。 通过在120〜150℃下以3〜10倍的拉伸倍数预拉伸IPF为94%以上的未拉伸的PP纤维,然后在170〜190℃下拉伸所得的PP纤维的方法 ℃,拉伸倍数为1.5〜15次/ min,拉伸张力为1.0〜2.5cN / dtex的拉伸倍率为1.2〜3.0倍。 水硬性组合物,绳索,片状纤维结构体和具有各自使用PP纤维的有机聚合物的复合材料。