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    • 4. 发明公开
    • COMPLEX COMPRISING CRYSTALLINE HYBRID NANOPOROUS MATERIAL POWDER
    • KOMPLEX AUS EINEM KRISTALLINENNANOPORÖSENHYBRIDPULVER
    • EP2746226A2
    • 2014-06-25
    • EP12824012.4
    • 2012-08-14
    • Korea Research Institute of Chemical Technology
    • CHANG, Jong-SanLEE, U-HwangHWANG, Young KyuHWANG, Dong WonSEO, You-KyongLEE, Ji SunYoon, Ji WoongSHIM, Kyu Eun
    • C01G3/00C01G23/00C01G49/00B01J19/12B01J20/00
    • The present invention relates to a composite and a method for manufacturing same, the composite comprising: at least one crystalline hybrid nanoporous material powder, at least one organic polymeric additive and at least one optional inorganic additive; wherein said crystalline hybrid nanoporous material is prepared by coordinating at least one organic ligand and at least one optional anionic ligand to or with a metal ion or a metal ion cluster to which oxygen is bonded; wherein the composite has a spherical or pseudo-spherical shape and a size of 0.1 ∼ 100 mm; that the total void volume of the voids is at least 5 % by volume based on the sum of the total pore volume of the nanopores having a size of 10 nm or smaller in the composite and the total void volume of the voids having a size of 0.1 µ m or larger in the composite; and that the specific surface area per weight (m 2 /g) of the composite is at least 83% based on the specific surface area per weight (m 2 /g) of the nanoporous material powder.
    • 本发明涉及一种复合材料及其制造方法,所述复合材料包括:至少一种结晶混合纳米多孔材料粉末,至少一种有机聚合物添加剂和至少一种任选的无机添加剂; 其中所述结晶杂合纳米多孔材料通过将至少一种有机配体和至少一种任选的阴离子配体配位到或与金键合的金属离子或金属离子簇配位而制备; 其中所述复合物具有球形或假球形并且尺寸为0.1×100mm; 基于复合材料中具有10nm或更小尺寸的纳米孔的总孔体积的总和,空隙的总空隙体积为至少5体积%,并且具有尺寸为 复合材料为0.1μm以上; 并且,相对于纳米多孔材料粉末的比重(m 2 / g)的比表面积,复合材料的比表面积为(m 2 / g)为83%以上。