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1. 发明公开

EP2635661A1 CATALYTIC HYDROPYROLYSIS OF ORGANOPHILIC BIOMASS 审中-公开
标题翻译：催化加氢亲有机生物量
公开(公告)号：EP2635661A1
公开(公告)日：2013-09-11
申请号：EP11838414.8
申请日：2011-10-04
申请人： KiOR, Inc.
发明人： BARTEK, Robert , BRADY, Michael , STAMIRES, Dennis
IPC分类号： C10L1/02
CPC分类号： C10G11/18 , C10G1/02 , C10G1/065 , C10G1/083 , C10G45/02 , C10G47/00 , C10G47/02 , C10G49/007 , C10G2300/1011 , C10G2300/1014 , C10G2300/1044 , C10G2300/1059 , C10G2300/107 , C10G2300/1077 , C10G2300/4006 , C10G2300/4012 , C10G2300/4081 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L5/44 , C10L9/083 , Y02E50/10 , Y02E50/15 , Y02E50/30 , Y02P30/20
摘要： A process for producing fuel from biomass is disclosed herein. The process includes torrefying biomass material at a temperature between 80° C. and 300° C. to form particulated biomass having a mean average particle size from about 1 μm to about 1000 μm. The particulated biomass is mixed with a liquid to form a suspension, wherein the liquid comprises bio-oil, wherein the suspension includes between 1 weight percent to 40 weight percent particulated biomass. The suspension is fed into a hydropyrolysis reactor; and at least a portion of the particulated biomass of the suspension is converted into fuel.

2. 发明公开

EP2534424A1 IMPROVED BIOMASS FEED SYSTEM/PROCESS 审中-公开
标题翻译：生物质促进提高了系统/程序
公开(公告)号：EP2534424A1
公开(公告)日：2012-12-19
申请号：EP11742668.4
申请日：2011-02-08
申请人： KiOR, Inc.
发明人： BARTEK, Robert
IPC分类号： F23K3/00
CPC分类号： B01J3/02 , B65G53/04 , B65G53/66 , F23G5/027 , F23G5/444 , F23G2205/00 , F23G2205/14 , F23G2205/18 , F23G2205/20 , F23G2209/26 , F23G2900/55006 , F23K2201/505 , F23K2203/104
摘要： The invention relates generally to the conversion of biomass to oxygenated hydrocarbons. More particularly, an improved biomass feed system or process for conveying biomass to a reactor for conversion to oxygenated hydrocarbons is provided. The provided system or process utilizes a spool piece adapted to convey solid particulate biomass from a lower pressure to a higher pressure. The spool piece conveys the solid particulate biomass material either directly to a reactor operated at or below the higher pressure or first to a vibratory feeder and then to such reactor. The vibratory feeder can include a bowl and an outlet spout extending tangentially from the bowl.

3. 发明公开

EP2342169A1 BIOMASS CONVERSION PROCESS 审中-公开
标题翻译：生物质转化过程
公开(公告)号：EP2342169A1
公开(公告)日：2011-07-13
申请号：EP09825358.6
申请日：2009-11-04
申请人： KiOR, Inc.
发明人： BARTEK, Robert , YANIK, Steve , O'CONNOR, Paul
IPC分类号： C07C1/00
CPC分类号： C10L1/04 , C10G1/08 , C10G1/083 , C10G2300/1011 , C10G2300/4006 , C10G2300/708 , Y02E50/14 , Y02P30/20
摘要： A process is disclosed including: contacting solid biomass with a first catalyst stream in a first reaction zone operated at a temperature T1 (from about 250 to about 400°C), for conversion of a portion of the solid biomass and forming a first gaseous product stream; downwardly passing unconverted biomass to a second reaction zone for contact with a second catalyst stream charged to the second reaction zone operated at a temperature T2, for conversion to form a second gaseous product stream and a spent catalyst; burning coke off the spent catalyst in a regenerator to form a regenerated catalyst; charging a portion of the regenerated catalyst to each of the first and second reaction zones, as the first and second catalyst streams, respectively; upwardly passing the second gaseous product stream to the first reaction zone; and removing both first and second gaseous product streams from the first reaction zone.
摘要翻译：公开了一种方法，包括：使固体生物质与在温度T1（约250至约400℃）下操作的第一反应区中的第一催化剂物流接触，以转化一部分固体生物质并形成第一气体产物流; 将未转化的生物质向下传递至第二反应区用于与加入到在温度T2操作的第二反应区的第二催化剂物流接触以转化形成第二气体产物流和废催化剂; 将再生器中的废催化剂焦化掉以形成再生催化剂; 作为第一和第二催化剂流分别装入一部分再生催化剂到第一和第二反应区中的每一个; 向上通过第二气态产物流到第一反应区; 并从第一反应区中除去第一和第二气态产物流。

4. 发明公开

EP2340295A2 BIOMASS CONVERSION PROCESS 失效
标题翻译：用于生物质转化
公开(公告)号：EP2340295A2
公开(公告)日：2011-07-06
申请号：EP09829596.7
申请日：2009-10-27
申请人： KiOR, Inc.
发明人： BARTEK, Robert , YANIK, Steve , O'CONNOR, Paul , STAMIRES, Dennis , BRADY, Michael
IPC分类号： C10G1/08
CPC分类号： C10G1/08 , C10B49/22 , C10B53/02 , C10B57/02 , C10G1/006 , C10G3/42 , C10G3/57 , Y02E50/14 , Y02E50/32 , Y02P20/145 , Y02P30/20
摘要： A method for converting solid biomass into hydrocarbons includes contacting the solid biomass with a catalyst in a first riser operated at a temperature in the range of from about 50° C to about 200° C to thereby produce a first biomass-catalyst mixture and a first product comprising hydrocarbons; a) separating the first product from the first biomass-catalyst mixture; c) charging the first biomass-catalyst mixture to a second riser operated at a temperature in the range of from about 200° C to about 400° C to thereby produce a second biomass-catalyst mixture and a second product comprising hydrocarbons; d) separating the second product from the second biomass-catalyst mixture; e) charging the second biomass-catalyst mixture to a third riser operated at a temperature greater than about 450° C to thereby produce a spent catalyst and a third product comprising hydrocarbons; and 0 separating the third effluent from the spent catalyst.

5. 发明公开

EP2696979A1 IMPROVED CATALYST FOR THERMOCATALYTIC CONVERSION OF BIOMASS TO LIQUID FUELS AND CHEMICALS 有权转让
标题翻译：改进的催化剂用于液体燃料和化学品生物质热催化转化
公开(公告)号：EP2696979A1
公开(公告)日：2014-02-19
申请号：EP12771088.7
申请日：2012-04-13
申请人： KiOR, Inc.
发明人： ADKINS, Bruce , STAMIRES, Dennis , BARTEK, Robert , BRADY, Michael , HACKSKAYLO, John
IPC分类号： B01J29/40
CPC分类号： B01J29/40 , B01J37/0009 , B01J37/28 , B01J2229/18 , B01J2229/42 , C10G3/49 , C10G3/57 , C10G2300/1014 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/04 , C10L2200/0469 , C10L2290/02 , Y02P30/20
摘要： Catalyst compositions comprising a phosphorous-promoted ZSM-5 component and a silica-containing binder, and methods for making and using same, are disclosed. More specifically, processes for making a catalyst for biomass conversion are provided. The process includes: treating a ZSM-5 zeolite with a phosphorous-containing compound to form a phosphorous-promoted ZSM-5 component; preparing a slurry comprising the phosphorous-promoted ZSM-5 component and a silica-containing binder; and shaping the slurry into shaped bodies. Such catalysts can be used for the thermocatalytic conversion of particulate biomass to liquid products such as bio-oil, resulting in higher bio-oil yields and lower coke than conventional catalysts.

6. 发明公开

EP2683797A2 BIOMASS PRETREATMENT FOR FAST PYROLYSIS TO LIQUIDS 有权
标题翻译：生物质进行快速热解液体治疗
公开(公告)号：EP2683797A2
公开(公告)日：2014-01-15
申请号：EP12754769.3
申请日：2012-03-07
申请人： KiOR, Inc.
发明人： BARTEK, Robert , BRADY, Michael , STAMIRES, Dennis
IPC分类号： C10L1/00 , C10L5/00 , C10B57/12
CPC分类号： C10B53/02 , C10B49/16 , C10B57/08 , C10C5/00 , C10G1/02 , C10G1/08 , C10G2300/1011 , C10L1/02 , Y02E50/14 , Y02E50/30 , Y02P30/20
摘要： Aspects of the present invention relate to methods, systems, and compositions for preparing a solid biomass for fast pyrolysis. The method includes contacting the solid biomass with an inorganic material present in an effective amount for increasing fast pyrolysis yield of an organic liquid product (e.g., bio-oil). In various embodiments, the inorganic material is selected from the group consisting of aluminum sulfate, aluminum nitrate, aluminum chloride, aluminum hydroxide, ammonium hydroxide, magnesium hydroxide, potassium hydroxide, and combinations thereof.

7. 发明公开

EP2352877A1 COMMINUTION AND DENSIFICATION OF BIOMASS PARTICLES 有权
标题翻译：方法用于转化固体生物质
公开(公告)号：EP2352877A1
公开(公告)日：2011-08-10
申请号：EP09829848.2
申请日：2009-11-30
申请人： KiOR, Inc.
发明人： BRADY, Michael , BARTEK, Robert , STAMIRES, Dennis , O'CONNOR, Paul
IPC分类号： D21B1/06
CPC分类号： D21B1/02 , D21B1/021 , Y02E50/14
摘要： A method is disclosed for reducing the mechanical strength of solid biυmass material, in particular ligno-cellulosic biomass The method comprises heating the solid biomass material Io a temperature in the range of 105
0 C to 200
0 C. The heat treatment, which is referred to as "toasting", significantly reduces the mechanical energy required for reducing the particle size of the solid biomass material. The method is particularly suitable as a pretreatmemt step to a conversion reaction of the solid biomass material

8. 发明授权

EP2340295B1 BIOMASS CONVERSION PROCESS 失效
标题翻译： VERFAHREN ZUR UMWANDLUNG VON BIOMASSE
公开(公告)号：EP2340295B1
公开(公告)日：2017-04-19
申请号：EP09829596.7
申请日：2009-10-27
申请人： KiOR, Inc.
发明人： BARTEK, Robert , YANIK, Steve , O'CONNOR, Paul , STAMIRES, Dennis , BRADY, Michael
IPC分类号： C10G1/08 , C10G3/00
CPC分类号： C10G1/08 , C10B49/22 , C10B53/02 , C10B57/02 , C10G1/006 , C10G3/42 , C10G3/57 , Y02E50/14 , Y02E50/32 , Y02P20/145 , Y02P30/20

9. 发明公开

EP2683476A1 PHYLLOSILICATE-BASED COMPOSITIONS AND METHODS OF MAKING THE SAME FOR CATALYTIC PYROLYSIS OF BIOMASS 有权转让
标题翻译：组合物PHYLLOSILICATBASIS和工艺及其对催化裂解生物质
公开(公告)号：EP2683476A1
公开(公告)日：2014-01-15
申请号：EP12754339.5
申请日：2012-03-07
申请人： KiOR, Inc.
发明人： BARTEK, Robert , BRADY, Michael , STAMIRES, Dennis
IPC分类号： B01J20/00
CPC分类号： B01J29/048 , B01J29/049 , B01J29/80 , B01J37/0045 , C10G3/44 , Y02P30/20
摘要： A process for producing catalyst for biomass catalytic cracking is disclosed herein. The process includes modifying a phyllosilicate to produce a modified phyllosilicate having an improved yield of a pyrolysis reaction. The modification of the phyllosilicate includes leaching the clay with an acid or basic solution to form a leached clay preparation, calcining the leached clay and contacting the treated clay with a suspension comprising metal ions for ion-exchange. The modified clay catalyst can then be mixed with inorganic materials such as zeolites and dried to form fluidizable microspheres.

10. 发明公开

EP2595915A1 METHOD AND APPARATUS FOR PYROLYSIS OF A BIOMASS 失效
标题翻译：方法和装置裂解生物质
公开(公告)号：EP2595915A1
公开(公告)日：2013-05-29
申请号：EP11810141.9
申请日：2011-06-30
申请人： KiOR, Inc.
发明人： BARTEK, Robert , CORDLE, Ronald, Lee
IPC分类号： C01B3/38 , C07C1/06
CPC分类号： C10B49/22 , C10B53/02 , C10C5/00 , Y02E50/14 , Y02E50/32 , Y02P20/145
摘要： A method and apparatus for effective pyrolysis of a biomass utilizing rapid heat transfer from a solid heat carrier or catalyst. Particularly, various embodiments of the present invention provide methods and apparatuses which incorporate progressive temperature quenching and rapid disengagement of the heat carrier material and reaction product.

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