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1. 发明公开

EP0675555A1 Negative electrode for use in lithium secondary battery and process for producing the same 失效
标题翻译：负极Elektrodefür锂Akkumulator和Verfahren zu dessen Herstellung。
公开(公告)号：EP0675555A1
公开(公告)日：1995-10-04
申请号：EP95104869.3
申请日：1995-03-31
申请人： Kabushiki Kaisha Toshiba , PETOCA, Ltd
发明人： Takami, Norio , Ohsaki, Takahisa , Tamaki, Toshio, c/o Petoca, Ltd. , Nakajima, Hideyuki, c/o Petoca, Ltd. , Katsuta, Yasushi, c/o Petoca, Ltd.
IPC分类号： H01M4/58
CPC分类号： H01M4/587
摘要： A negative electrode for use in a secondary battery which comprises milled graphite fibers derived from mesophase pitch each having circumferential, upper end and lower end faces, said milled graphite fibers each being composed of graphite layers having therebetween voids as inlets and outlets for lithium ions, all of said circumferential, upper end and lower end faces having openings of said voids between the graphite layers, which serve as inlets or outlets for lithium ions. This negative electrode for use in a secondary battery can be utilized to provide a lithium secondary battery of nonaqueous electrolyte which has large charge and discharge capacities and which permits setting the current density at charge or discharge high.
摘要翻译：一种用于二次电池的负极，其包括衍生自具有圆周，上端和下端面的中间相沥青的碾磨石墨纤维，所述碾磨石墨纤维各自由石墨层构成，所述石墨层具有用作锂离子的入口和出口，所有所述圆周，上端和下端面都具有石墨层之间的所述空隙的开口，其用作锂离子的入口或出口。用于二次电池的负极可用于提供具有大的充放电容量的非水电解质的锂二次电池，并且允许将充电或放电的电流密度设定得高。

2. 发明授权

EP0675555B1 Negative electrode for use in lithium secondary battery and process for producing the same 失效
标题翻译：对于它们的制备锂二次电池，并处理A负极
公开(公告)号：EP0675555B1
公开(公告)日：1999-07-28
申请号：EP95104869.3
申请日：1995-03-31
申请人： Kabushiki Kaisha Toshiba , PETOCA, Ltd
发明人： Takami, Norio , Ohsaki, Takahisa , Tamaki, Toshio, c/o Petoca, Ltd. , Nakajima, Hideyuki, c/o Petoca, Ltd. , Katsuta, Yasushi, c/o Petoca, Ltd.
IPC分类号： H01M4/58
CPC分类号： H01M4/587

3. 发明授权

EP0594301B1 Process for producing pitch based activated carbon fibers 失效
标题翻译：一种制备沥青基活性炭纤维的方法
公开(公告)号：EP0594301B1
公开(公告)日：1997-08-06
申请号：EP93307421.3
申请日：1993-09-20
申请人： PETOCA LTD.
发明人： Tamaki, Toshio, c/o Petoca, Ltd. , Nakajima, Hideyuki, c/o Petoca, Ltd. , Nishimura, Yoshiyuki, c/o Petoca, Ltd. , Ejiri, Hiroshi, c/o Petoca, Ltd.
IPC分类号： C10C3/00 , D01F9/145
CPC分类号： D01F9/145 , C10C3/00

4. 发明公开

EP0762522A1 Boron containing carbon material for lithium secondary battery and process for producing the same 失效
标题翻译： Borenthaltender KohlenstofffürLithium-Sekundär-Batterie und Verfahren zur Herstellung
公开(公告)号：EP0762522A1
公开(公告)日：1997-03-12
申请号：EP96113083.8
申请日：1996-08-14
申请人： PETOCA, Ltd
发明人： Tamaki, Toshio, c/o Petoca, Ltd. , Nishimura, Yoshiyuki, c/o Petoca, Ltd.
IPC分类号： H01M4/58 , C01B31/00 , H01M10/40
CPC分类号： H01M4/583 , C01B32/20 , C01P2002/60 , C01P2002/72 , C01P2002/74 , C01P2006/80 , H01M4/133 , H01M4/1393 , H01M10/052
摘要： A carbon material for use in a lithium secondary battery, which is obtained by graphitization conducted in the presence of a boric compound so as to contain boron in an amount ranging from 1,000 ppm to 30,000 ppm and which, when subjected to X-ray diffractometry, exhibits an interplanar spacing of 002 surface (d 002 ) of not greater than 0.338 nm, a crystallite size along c-axis (Lc) of at least 35 nm, a crystallite size along a-axis (La) of at least 50 nm and a ratio of diffraction peak (101) to diffraction peak (100), designated as P 101 /P 100 , of at least 1.0; a negative electrode and a lithium secondary battery each produced by using the above carbon material; and a process for producing the carbon material. This carbon material exhibits large charge and discharge capacities, so that it can provide a negative electrode for use in a lithium secondary battery which is excellent in charge and discharge cycle characteristics.
摘要翻译：一种用于锂二次电池的碳材料，其通过在硼化合物的存在下进行石墨化而获得，以便含有量为1,000ppm至30,000ppm的硼，并且当进行X射线衍射时，表现出不大于0.338nm的002表面（d002）的面间距离，沿c轴（Lc）至少35nm的微晶尺寸，沿a轴（La）至少50nm的微晶尺寸和衍射峰（101）与衍射峰（100）的比值，指定为P101 / P100，为至少1.0; 使用上述碳材料制造的负极和锂二次电池; 以及碳材料的制造方法。该碳材料具有大的充放电能力，因此可以提供充放电循环特性优异的锂二次电池用负极。

5. 发明授权

EP0762522B1 Boron containing carbon material for lithium secondary battery and process for producing the same 失效
标题翻译：含硼碳材料用于锂二次电池及其制造方法
公开(公告)号：EP0762522B1
公开(公告)日：2000-07-19
申请号：EP96113083.8
申请日：1996-08-14
申请人： PETOCA, Ltd
发明人： Tamaki, Toshio, c/o Petoca, Ltd. , Nishimura, Yoshiyuki, c/o Petoca, Ltd.
IPC分类号： H01M4/58 , C01B31/00 , H01M10/40
CPC分类号： H01M4/583 , C01B32/20 , C01P2002/60 , C01P2002/72 , C01P2002/74 , C01P2006/80 , H01M4/133 , H01M4/1393 , H01M10/052

6. 发明公开

EP0594301A1 Process for producing pitch based activated carbon fibers 失效
标题翻译：一种制备沥青基活性炭纤维的方法。
公开(公告)号：EP0594301A1
公开(公告)日：1994-04-27
申请号：EP93307421.3
申请日：1993-09-20
申请人： PETOCA LTD.
发明人： Tamaki, Toshio, c/o Petoca, Ltd. , Nakajima, Hideyuki, c/o Petoca, Ltd. , Nishimura, Yoshiyuki, c/o Petoca, Ltd. , Ejiri, Hiroshi, c/o Petoca, Ltd.
IPC分类号： C10C3/00 , D01F9/145
CPC分类号： D01F9/145 , C10C3/00
摘要： In accordance with the present invention, there are provided activated carbon fibers consisting of optically anisotropic components and optically isotropic components by spinning a spinning pitch into pitch fibers, and infusibilizing the resulting fibers, followed by activation treatment. The spinning pitch is prepared by melt mixing together (A) 100 parts by weight of an optically isotropic pitch having a softening point of 230-300°C obtained by heat treatment of a pitch while blowing an oxygen containing gas into the pitch and (B) 10-50 parts by weight of an optically isotropic pitch having a softening point of 200-270°C and preferably obtained by polymerization of naphthalene in the presence of a Lewis acid catalyst. Also according to the invention, carbon fibers consisting of optically anisotropic components and optically isotropic components are prepared by spinning the above-mentioned spinning pitch into fibers, and infusibilizing the resulting pitch fibers, followed by carbonization and/or graphitization.
摘要翻译：在本发明雅舞蹈，提供活化的碳纤维通过纺丝的纺丝沥青成沥青纤维，和难熔化所得到的纤维，随后活化处理由...组成的光学各向异性元件和光学各向同性分量。纺丝沥青通过熔融重量份（A）100份混合的光学各向同性沥青一起具有同时吹入含氧气体进入音调，并通过节距的热处理获得的230的软化点为300℃，制备（B ）10-50重量份的具有200的软化点为270℃，且优选通过萘的聚合在路易斯酸催化剂的存在下获得的光学各向同性沥青中。所以gemäß发明，其由光学各向异性元件和光学各向同性分量的碳纤维是通过上述的纺丝沥青纺成纤维，和难熔化所得沥青纤维制备，然后通过碳化和/或石墨化。

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