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    • 4. 发明公开
    • Coating composition
    • Lackzusammensetzung。
    • EP0427293A1
    • 1991-05-15
    • EP90121514.5
    • 1990-11-09
    • KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA
    • Inoue, MasaharuFurukawa, HisaoKato, YasushiIsayama, Katsuhiko
    • C09D157/08C09D183/04C09D201/10
    • C09D143/04C08L43/04C08L83/04C08L2205/02C09D183/04C08L2666/02C08L2666/04
    • A curable coating composition comprising

      (A) from 10 to 99 parts by weight of a silyl group-containing vinylic polymer having a number average molecular weight of at least 3,000, the main chain thereof being substantially composed of a vinylic polymer chain and having at least one silicon atom bonded to a hydrolyzable group at a terminal of the main chain and/or at a side chain in each molecule,
      (B) from 1 to 90 parts by weight of an organic compound having a number average molecular weight of not larger than 3,000 and having at least one silicon atom bonded to a hydrolyzable group at a terminal in each molecule, and
      (C) from 1 to 500 parts by weight of silanol-containing organopolysiloxane having, on an average, at least one silanol group in one molecule to 100 parts by weight of the total amount of the component (A) and the component (B).
    • 一种可固化涂料组合物,其包含(A)10至99重量份数均分子量为至少3,000的含甲硅烷基的乙烯基聚合物,其主链基本上由乙烯基聚合物链组成并且至少具有 一个硅原子键合在主链末端和/或每个分子中的侧链上的可水解基团,(B)1至90重量份的数均分子量不大于 3,000,并且在每个分子中具有与可水解基团键合的至少一个硅原子,和(C)1至500重量份在一个分子中平均具有至少一个硅烷醇基团的含硅烷醇的有机聚硅氧烷 至100重量份的组分(A)和组分(B)的总量。 一世
    • 7. 发明公开
    • Curable composition for paint
    • HärtbareLackzusammensetzung。
    • EP0554684A1
    • 1993-08-11
    • EP93100500.3
    • 1993-01-15
    • KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA
    • Inoue, MasaharuOkimura, YoshihikoKawaguchi, HirotoshiFurukawa, Hisao
    • C09D143/04C08K5/10C08G18/71
    • C08G18/44C08G18/4277C08G18/718C08K5/5419C09D143/04C08L43/04C08L2666/14C08L2666/28
    • A curable composition for paint comprising

      (A) 10 to 99 parts by weight of a vinyl polymer having a number average molecular weight of not less than 2,000 and at least one silicon atom to which a hydrolyzable group is bonded at an end of the main chain and/or in a side chain thereof, in one molecule, wherein the main chain comprises substantially a vinyl polymer chain;
      (B) 1 to 90 parts by weight of a compound containing a carbonyldioxy group which is at least one of

      (i) a compound containing a hydrolyzable silyl group, the compound having at least one carbonyldioxy group in one molecule and at least one silicon atom to which a hydrolyzable group is bonded, in one molecule, and
      (ii) a polycarbonate polyol compound having at least one carbonyldioxy group and at least two hydroxyl groups in one molecule; and

      (C) 0.001 to 10 parts by weight of a curing catalyst on the basis of 100 parts by weight of the components (A) and (B) in total.

      This curable composition for paint has excellent high solid content and one package storage stability as well as superior scratch resistance and acid resistance.
    • 一种用于涂料的可固化组合物,其包含(A)10至99重量份数均分子量不小于2,000的乙烯基聚合物和至少一个可水解基团在主链的末端键合的至少一个硅原子 和/或在其侧链中,在一个分子中,其中所述主链基本上包含乙烯基聚合物链; (B)1〜90重量份含有羰基二氧基的化合物,其为(i)含有可水解甲硅烷基的化合物,在一个分子中具有至少一个羰基二氧基的化合物和至少一个硅原子 一个分子中可结合水解基团,和(ii)在一个分子中具有至少一个羰基二氧基和至少两个羟基的聚碳酸酯多元醇化合物; 和(C)基于100重量份的组分(A)和(B)的总量,0.001至10重量份的固化催化剂。 该用于涂料的可固化组合物具有优异的高固含量和一包装储存稳定性以及优异的耐擦伤性和耐酸性。
    • 9. 发明公开
    • Curable composition for paint
    • HärtbareLackzusammensetzung。
    • EP0594205A1
    • 1994-04-27
    • EP93117171.4
    • 1993-10-22
    • KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA
    • Inoue, MasaharuFurukawa, HisaoKawaguchi, HirotoshiOkimura, Yoshihiko
    • C09D143/04
    • C09D143/04C08L43/04C08L2205/02C08L2666/04C08L2666/28
    • A curable composition for paint containing:

      (A) 95 to 5 parts by weight of a vinyl copolymer having at least one specific hydrolyzable silyl group and at least one specific alcoholic hydroxyl group existing at an end of the main chain and/or in a side chain thereof in one molecule, in which the main chain contains substantially a vinyl copolymer chain and the alcoholic hydroxyl equivalent is from 180 to 2000 g/mol;
      (B) 5 to 95 parts by weight of a vinyl copolymer having at least one specific hydrolyzable silyl group at an end of the main chain and/or in a side chain thereof in one molecule and having no alcoholic hydroxyl group in the same molecule, in which the main chain contains substantially a vinyl copolymer chain; and
      (C) 0.001 to 10 parts by weight of a curing catalyst per 100 parts by weight of the total resin solids content.

      This curable composition for paint has well-balanced properties of good acid resistance, water resistance, scratch resistance, weathering resistance, and so forth.
    • 一种用于涂料的可固化组合物,其包含:(A)95至5重量份的具有至少一个具体的可水解甲硅烷基和至少一个特定的醇羟基的乙烯基共聚物,存在于主链的末端和/或侧面 其中主链含有基本上乙烯基共聚物链,醇羟基当量为180-2000g / mol; (B)5〜95重量份在一分子中在主链末端和/或侧链具有至少一个特定的可水解甲硅烷基并且在同一分子中不具有醇羟基的乙烯基共聚物, 其中主链含有基本上乙烯基共聚物链; 和(C)每100重量份总树脂固体含量为0.001〜10重量份的固化催化剂。 该用于涂料的可固化组合物具有良好的耐酸性,耐水性,耐擦伤性,耐候性等特性。