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    • 2. 发明公开
    • Radiation-sensitive resin composition
    • 辐射敏感性树脂组合物
    • EP0365318A3
    • 1990-11-14
    • EP89310735.9
    • 1989-10-18
    • JAPAN SYNTHETIC RUBBER CO., LTD.
    • Miyashita, SatoshiYamanouchi, AkihiroNozue, IkuoMiura, Takao
    • G03F7/023
    • C08G8/08G03F7/0236
    • A radiation-sensitive resin composition comprising an alkali-soluble novolak resin and a 1,2-quinonediazide compound, wherein the alkali-soluble novolak resin comprises a mixture of:
      95-50 parts by weight of Resin A having a standard polystyrene-reduced weight-average molecular weight of 4,000-20,000 [Resin A is at least one resin selected from the group consisting of a resin obtained by polycondensation of m-cresol and at least one phenol represented by the structural formula (I) or (I′):
      wherein m is 2 or 3, with at least one aldehyde and a resin obtained by polycondensation of m-cresol, p-cresol and at least one phenol repreented by the above structural formula (I) or (I′) with at least one aldehyde] and
      5-50 parts by weight of Resin B having a standard polystyrene-reduced weight-average molecular weight of 200-2,000 [Resin B is a resin obtained by polycondensation of at least one phenol represented by the structural formula (II):
      wherein n is 0, 1, 2 or 3, with at least one aldehyde].
      In the resin composition, the mixture of Resin A and Resin B may further contain Resin C which is an ester of Resin B with a 1,2-quinonediazidesulfonic acid. The radiation-­sensitive resin compopsition is suitable for use as a positive type resist having high sensitivity, excellent developability, high resolution and excellent heat resistance.
    • 3. 发明公开
    • Radiation-sensitive resin composition
    • Strahlungsempfindliche Harzzusammensetzungen。
    • EP0365318A2
    • 1990-04-25
    • EP89310735.9
    • 1989-10-18
    • JAPAN SYNTHETIC RUBBER CO., LTD.
    • Miyashita, SatoshiYamanouchi, AkihiroNozue, IkuoMiura, Takao
    • G03F7/023
    • C08G8/08G03F7/0236
    • A radiation-sensitive resin composition comprising an alkali-soluble novolak resin and a 1,2-quinonediazide compound, wherein the alkali-soluble novolak resin comprises a mixture of:
      95-50 parts by weight of Resin A having a standard polystyrene-reduced weight-average molecular weight of 4,000-20,000 [Resin A is at least one resin selected from the group consisting of a resin obtained by polycondensation of m-cresol and at least one phenol represented by the structural formula (I) or (I′):
      wherein m is 2 or 3, with at least one aldehyde and a resin obtained by polycondensation of m-cresol, p-cresol and at least one phenol repreented by the above structural formula (I) or (I′) with at least one aldehyde] and
      5-50 parts by weight of Resin B having a standard polystyrene-reduced weight-average molecular weight of 200-2,000 [Resin B is a resin obtained by polycondensation of at least one phenol represented by the structural formula (II):
      wherein n is 0, 1, 2 or 3, with at least one aldehyde].
      In the resin composition, the mixture of Resin A and Resin B may further contain Resin C which is an ester of Resin B with a 1,2-quinonediazidesulfonic acid. The radiation-­sensitive resin compopsition is suitable for use as a positive type resist having high sensitivity, excellent developability, high resolution and excellent heat resistance.
    • 一种包含碱溶性酚醛清漆树脂和1,2-醌二叠氮化合物的辐射敏感性树脂组合物,其中碱溶性酚醛清漆树脂包括:95-50重量份具有标准聚苯乙烯缩小重量的树脂A - 平均分子量为4,000-20,000 [树脂A为选自由间甲酚和至少一种由结构式(I)表示的苯酚或(Imin)表示的苯酚获得的树脂中的至少一种树脂: 其中m为2或3,与至少一种醛和通过间甲酚,对甲酚和至少一种由上述结构式(I)或(I min)表示的苯酚缩聚而得到的树脂与 至少一种醛]和5-50重量份具有标准聚苯乙烯换算的重均分子量为200-2,000的树脂B [树脂B是通过至少一种由结构式(II)表示的苯酚缩聚得到的树脂 ):其中n为0,1,2或3, h至少一种醛]。 在树脂组合物中,树脂A和树脂B的混合物可以进一步含有作为树脂B与1,2-醌二叠氮磺酸的酯的树脂C. 辐射敏感性树脂组合物适合用作具有高灵敏度,优异显影性,高分辨率和优异耐热性的正型抗蚀剂。