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    • 4. 发明公开
    • Water-soluble dye
    • 水溶性染料
    • EP0219232A2
    • 1987-04-22
    • EP86307167.6
    • 1986-09-17
    • IMPERIAL CHEMICAL INDUSTRIES PLC
    • Baxter, Anthony Gerard WilliamBostock, Stephen BernardGreenwood, David
    • C09B50/00C09B56/10C09D11/02
    • C09D11/328C09B50/00C09B56/10
    • A water-soluble dye, free from cellulose-reactive groups, of the formula:
      wherein R' is -(C a H 2a O) m (C b H 2b O) n H,

      R 2 is H or -(C a H2 a O) m (C b H 2b O) n H, or
      R 1 & R 2 together with the nitrogen atom form a morpholine ring;
      a & b are different and from 1 to 8
      m is from 1 to 10; n is from 0 to 9;
      M is H, ammonium or a monovalent metal;
      X is (i) NR 1 R 2 , (ii) NR 3 R 4 , in which R 3 and R 4 are each independently selected from H, alkyl and aryl, or (iii) a mono- or dis-azo chromophore comprising benzene, naphthalene or mono- or bi-cyclic heteroaryl diazo and coupling components linked to the triazine nucleus through an amino linking group;
      R 5 & R 6 are selected from S0 3 M and H provided at least one is S0 3 M;
      R 7 is H, halogen, C 1-4 alkyl, C 1-4 alkoxy, SO 3 M or COOM; and R 8 is H or S0 3 M, a printing ink containing the dye and a method of printing.
    • 不含纤维素反应性基团的水溶性染料,其结构式为:其中R'为 - (CaH2aO)m(CbH2bO)nH,R2为H或 - (CaH2aO)m(CbH2bO)nH或R1和R2一起 与氮原子形成吗啉环; a和b是不同的,1到8m是1到10; n是从0到9; M是H,铵或一价金属; X是(i)NR 1 R 2,(ii)NR 3 R 4,其中R 3和R 4各自独立地选自H,烷基和芳基,或(iii)包含苯,萘或单 - 或双 - 通过氨基连接基团与三嗪核连接的环状杂芳基重氮基和偶合组分; R5和R6选自SO3M和H,条件是至少一个是SO3M; R7是H,卤素,C1-4烷基,C1-4烷氧基,SO3M或COOM; R8是H或SO3M,含有染料的印刷油墨和印刷方法。
    • 10. 发明公开
    • Water-soluble dye
    • 水溶性染料
    • EP0173476A2
    • 1986-03-05
    • EP85305518.4
    • 1985-08-02
    • IMPERIAL CHEMICAL INDUSTRIES PLC
    • Baxter, Anthony Gerard WilliamBostock, Stephen BernardGreenwood, David
    • C09B47/26C09D11/02
    • C09D11/328C09B47/26
    • A water-soluble dye, free fom cellulose reactive groups, of the formula:
      wherein

      R I is -(C a H2 a O) m (C b H 2b O) n H,
      R 2 is H or -(C a H 2a O) m (C b H 2bO ) n H, or
      R 1 & R 2 together with the nitrogen atom form a morpholine ring
      a & b are different and from 1 to 8
      m is from 1 to 10;
      n is from 0 to 9;
      Y is the residue of a copper phthalocyanine sulphonic acid of the formula:

      p is from 1 to 3
      q is from 1 to 3
      p + q is from 3 to 4
      M is H, ammonium, or a monovalent metal;
      X is NR 1 R 2 , alkoxy, NR 3 R 4 in which R 3 and R 4 are each independently selected from H, alkyl and aryl, or the residue of a mono- or dis-azo chromophore comprising benzene, naphthalene or mono- or bi-cyclic heteroaryl diazo and coupling components, linked to the triazine nucleus through a primary or secondary amine linking group;
      and Z is a divalent linking group,
      which is suitable for the preparation of a printing ink, especially for ink jet printing.
    • 具有下式的游离纤维素反应性基团的水溶性染料:其中R1是 - (CaH2aO)m(CbH2bO)nH,R2是H或 - (CaH2aO)m(CbH2bO)nH,或R1和R2与 氮原子形成吗啉环a和b是不同的,1至8m是1至10; n是从0到9; Y是具有下式的铜酞菁磺酸的残基:p为1至3,q为1至3,p为3至4; M为H,铵或单价金属; X是NR 1 R 2,烷氧基,NR 3 R 4,其中R 3和R 4各自独立地选自H,烷基和芳基,或者包含苯,萘或单环或双环杂芳基重氮偶联和偶联的单或双偶氮发色团的残基 通过伯胺或仲胺连接基团与三嗪核连接的组分; Z是二价连接基团,适用于制备印刷油墨,特别是用于喷墨印刷。