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    • 3. 发明授权
    • PROCESSES FOR THE PRODUCTION OF POLYCARBONATE
    • 生产聚碳酸酯的方法
    • EP0864597B1
    • 2002-02-06
    • EP96939301.6
    • 1996-11-22
    • Idemitsu Petrochemical Co., Ltd.
    • SHISHIKURA, Akihiro Idemitsu Petrochemical Co.Ltd.TAKAHASHI, Seiji
    • C08G64/20C08G64/30
    • C08G64/307C08G64/20
    • Processes for producing polycarbonate by solid phase polymerization which simplify the crystallization to be conducted prior to the solid phase polymerization to thereby permit further shortening in the treatment time. A process for producing polycarbonate is characterized in that an amorphous polycarbonate prepolymer prepared by transesterification of an aromatic dihydroxy compound with a diester of carbonic acid is polymerized in a solid phase in an atmosphere containing a gaseous swollen solvent while the prepolymer is kept in a fluid state. Another process for producing polycarbonate is characterized in that a mixture comprising an amorphous polycarbonate prepolymer prepared by transesterification of an aromatic dihydroxy compound with a diester of carbonic acid and a polycarbonate prepolymer which has undergone crystallization is polymerized in a solid phase in an atmosphere containing a gaseous swollen solvent.
    • 通过固相聚合生产聚碳酸酯的方法简化了在固相聚合之前进行的结晶,从而可以进一步缩短处理时间。 制备聚碳酸酯的方法的特征在于,通过芳族二羟基化合物与碳酸二酯的酯交换制备的无定形聚碳酸酯预聚物在含有气体溶胀溶剂的气氛中在固相中聚合,同时预聚物保持流体状态 。 另一种生产聚碳酸酯的方法的特征在于,将包含通过芳族二羟基化合物与碳酸二酯和已经结晶的聚碳酸酯预聚物进行酯交换反应制备的无定形聚碳酸酯预聚物的混合物在固相中在含有气态 溶胀的溶剂。