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    • 5. 发明公开
    • Thin-layer chromatography flame ionization detector for quantitative analysis of chromatographically-separated substances
    • ChromatographischerDünnschicht-Flammionisationsdetektorfürdiemengenmässige分析von色谱仪getrennten Substanzen。
    • EP0286757A2
    • 1988-10-19
    • EP87309930.3
    • 1987-11-10
    • IATRON LABORATORIES, INC.
    • Ogasawara, Minoru
    • G01N30/68G01N27/62
    • G01N30/68G01N2030/8417
    • A flame ionization detector is used for carrying out a quantitative analysis of chromatographically-­separated substances in thin-layer chromatography. The detector comprises a gas burner (1) form forming a hydrogen flame (4). A thin-layer chromatographic element (9) or a rod-like element which carries the chromatographically0­separated substances is passed through the hydrogen flame (4) so that the separated substances are burned and ionized. The detector further comprises an electrode (5) which is disposed above the hydrogen flame (4) and exposed to the ionized gas generated by the burning of the separated substances. A voltage is applied between the gas burner (1) and the electrode (5) so that the former is given a positive polarity and the latter a negative polarity. An electric current which is caused by the exposure of the negative electrode (5) to the ionized gas is detected and amplified. A third electrode (8) disposed to surround the negative electrode (5) so that an amount of each of the separated substances can be proportioned to the amplified output value thereof.
    • 火焰离子化检测器用于在薄层色谱中进行色谱分离物质的定量分析。 检测器包括形成氢火焰(4)的气体燃烧器(1)。 携带色谱分离物质的薄层色谱元件(9)或棒状元件通过氢火焰(4),使分离的物质燃烧和电离。 检测器还包括设置在氢火焰(4)上方并暴露于由分离物质燃烧产生的电离气体的电极(5)。 在气体燃烧器(1)和电极(5)之间施加电压,使得前者具有正极性,后者为负极性。 检测并放大由负极(5)暴露于电离气体引起的电流。 设置成围绕负电极(5)的第三电极(8),使得每个分离的物质的量可以与其放大的输出值成比例。