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1. 发明授权

EP2546224B1 METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS 有权转让
公开(公告)号：EP2546224B1
公开(公告)日：2018-09-26
申请号：EP12178208.0
申请日：2007-01-03
申请人： Honeywell International Inc.
发明人： Merkel, Daniel, C. , Tung, Hsueh, Sung , Van der Puy, Michael , Ma, Jing, Ji , Dubey Rajesh , Light, Barbara , Bortz, Cheryl , Phillips, Steven, D. , Mukhopahyay, Sudip
IPC分类号： C07C17/087 , C07C21/18
CPC分类号： C07C19/10 , C07C17/04 , C07C17/06 , C07C17/087 , C07C17/206 , C07C17/21 , C07C17/25 , C07C21/18 , C07C19/01 , C07C21/073
摘要： Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF 3 CF=CH 2 (1234yf). Three steps may be used in preferred embodiments in which a feedstock such as CCl 2 =CClCH 2 Cl (which may be purchased or synthesized from 1,2,3- trichloropropane) is fluorinated (preferably with HF in gas-phase in the presence of a catalyst) to synthesize a compound such as CF 3 CCl=CH 2 , preferably in a 80-96% selectivity. The CF 3 CCl=CH 2 is preferably converted to CF 3 CFClCH 3 (244-isomer) using a SbCl 5 as the catalyst which is then transformed selectively to 1234yf, preferably in a gas-phase catalytic reaction using activated carbon as the catalyst. For the first step, a mixture of Cr 2 O 3 and FeCl 3 /C is preferably used as the catalyst to achieve high selectivity to CF 3 CCl=CH 2 (96%). In the second step, SbCl 5 /C is preferably used as the selective catalyst for transforming 1233xf to 244-isomer, CF 3 CFClCH 3 . The intermediates are preferably isolated and purified by distillation and used in the next step without further purification, preferably to a purity level of greater than about 95%.

2. 发明公开

EP2546224A3 Method for producing fluorinated organic compounds 有权转让
标题翻译：一种制备氟化有机化合物的方法
公开(公告)号：EP2546224A3
公开(公告)日：2013-05-08
申请号：EP12178208.0
申请日：2007-01-03
申请人： Honeywell International Inc.
发明人： Merkel, Daniel, C. , Tung, Hsueh, Sung , Van der Puy, Michael , Ma, Jing, Ji , Dubey Rajesh , Light, Barbara , Bortz, Cheryl , Phillips, Steven, D. , Mukhopahyay, Sudip
IPC分类号： C07C17/087 , C07C21/19 , C09K5/00
CPC分类号： C07C19/10 , C07C17/04 , C07C17/06 , C07C17/087 , C07C17/206 , C07C17/21 , C07C17/25 , C07C21/18 , C07C19/01 , C07C21/073
摘要： Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF 3 CF=CH 2 (1234yf). Three steps may be used in preferred embodiments in which a feedstock such as CCl 2 =CClCH 2 Cl (which may be purchased or synthesized from 1,2,3- trichloropropane) is fluorinated (preferably with HF in gas-phase in the presence of a catalyst) to synthesize a compound such as CF 3 CCl=CH 2 , preferably in a 80-96% selectivity. The CF 3 CCl=CH 2 is preferably converted to CF 3 CFClCH 3 (244-isomer) using a SbCl 5 as the catalyst which is then transformed selectively to 1234yf, preferably in a gas-phase catalytic reaction using activated carbon as the catalyst. For the first step, a mixture of Cr 2 O 3 and FeCl 3 /C is preferably used as the catalyst to achieve high selectivity to CF 3 CCl=CH 2 (96%). In the second step, SbCl 5 /C is preferably used as the selective catalyst for transforming 1233xf to 244-isomer, CF 3 CFClCH 3 . The intermediates are preferably isolated and purified by distillation and used in the next step without further purification, preferably to a purity level of greater than about 95%.

3. 发明公开

EP2546224A2 Method for producing fluorinated organic compounds 有权转让
标题翻译：生产氟化有机化合物的方法
公开(公告)号：EP2546224A2
公开(公告)日：2013-01-16
申请号：EP12178208.0
申请日：2007-01-03
申请人： Honeywell International Inc.
发明人： Merkel, Daniel, C. , Tung, Hsueh, Sung , Van der Puy, Michael , Ma, Jing, Ji , Dubey Rajesh , Light, Barbara , Bortz, Cheryl , Phillips, Steven, D. , Mukhopahyay, Sudip
IPC分类号： C07C17/087 , C07C21/19 , C09K5/00
CPC分类号： C07C19/10 , C07C17/04 , C07C17/06 , C07C17/087 , C07C17/206 , C07C17/21 , C07C17/25 , C07C21/18 , C07C19/01 , C07C21/073
摘要： Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF 3 CF=CH 2 (1234yf). Three steps may be used in preferred embodiments in which a feedstock such as CCl 2 =CClCH 2 Cl (which may be purchased or synthesized from 1,2,3- trichloropropane) is fluorinated (preferably with HF in gas-phase in the presence of a catalyst) to synthesize a compound such as CF 3 CCl=CH 2 , preferably in a 80-96% selectivity. The CF 3 CCl=CH 2 is preferably converted to CF 3 CFClCH 3 (244-isomer) using a SbCl 5 as the catalyst which is then transformed selectively to 1234yf, preferably in a gas-phase catalytic reaction using activated carbon as the catalyst. For the first step, a mixture of Cr 2 O 3 and FeCl 3 /C is preferably used as the catalyst to achieve high selectivity to CF 3 CCl=CH 2 (96%). In the second step, SbCl 5 /C is preferably used as the selective catalyst for transforming 1233xf to 244-isomer, CF 3 CFClCH 3 . The intermediates are preferably isolated and purified by distillation and used in the next step without further purification, preferably to a purity level of greater than about 95%.
摘要翻译：公开了生产氟化烯烃的方法，优选适用于CF 3 CF = CH 2（1234yf）的商业化。在优选的实施方案中可以使用三个步骤，其中原料例如CCl 2 = CClCH 2 Cl（其可以购买或由1,2,3-三氯丙烷合成）被氟化（优选在存在催化剂的情况下与气相的HF一起）合成化合物如CF 3 CCl = CH 2，优选以80-96％的选择性。 CF 3 CCl = CH 2优选使用SbCl 5作为催化剂转化为CF 3 CFClCH 3（244-异构体），然后将其选择性地转化为1234yf，优选在使用活性炭作为催化剂的气相催化反应中。对于第一步，优选使用Cr 2 O 3和FeCl 3 / C的混合物作为催化剂以实现对CF 3 CCl = CH 2（96％）的高选择性。在第二步中，SbCl5 / C优选用作将1233xf转化成244-异构体CF3CFClCH3的选择性催化剂。中间体优选通过蒸馏分离和纯化，并且不经进一步纯化而用于下一步骤中，优选达到大于约95％的纯度水平。

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