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1. 发明授权

EP0320211B1 Process for producing a tetracarboxylic acid anhydride having disiloxane linkage 失效
标题翻译：生产具有甲氧基苯环的四羧酸类抗坏血酸的方法
公开(公告)号：EP0320211B1
公开(公告)日：1993-06-16
申请号：EP88311546.1
申请日：1988-12-06
申请人： Hitachi Chemical Co., Ltd.
发明人： Kikuchi, Tohru , Kamijima, Koichi , Saito, Takayuki
IPC分类号： C07F7/08 , C08G59/42
CPC分类号： C07F7/0852 , C08G59/423

2. 发明公开

EP0292260A3 Process for producing 1,3-bis(dicarboxyphenyl)-disiloxane derivative or dianhydride thereof 失效
标题翻译： 1,3-双（二甲氧基苯基） - 二硅氧烷衍生物或其二氢化物的制备方法
公开(公告)号：EP0292260A3
公开(公告)日：1990-03-28
申请号：EP88304499.2
申请日：1988-05-18
申请人： Hitachi Chemical Co., Ltd.
发明人： Kikuchi, Tohru , Fujita, Toshiyuki , Kamijima, Koichi , Saito, Takayuki
IPC分类号： C07F7/08
CPC分类号： C07F7/0874 , C07F7/0889
摘要： A process for producing a compound of formula [V] or a dianhydride thereof
wherein R and R′ are the same or different and each is methyl or phenyl comprising
coupling a Grignard reagent of halo-o-xylene with a disubstituted halosilane
wherein X is halogen,
hydroxylating the product silane to form a hydroxysilane
dehydrating-condensing the hydroxysilane to form a 1,3-bisdimethylphenyl-disilane derivative oxidizing the 1,3-bis(dimethylphenyl)disilane derivative to yield the intended 1,3-bis(dicarboxyphenyl)disiloxane derivative. The dianhydride is formed by dehydration ring closure of this product and [VI], mixing the resulting isomeric mixture with an ether solvent, and recovering the formed precipitate to yield a white powder of the intended dianhydride.

3. 发明公开

EP0320211A2 Process for producing a tetracarboxylic acid anhydride having disiloxane linkage 失效
标题翻译：一种用于生产Tetracabonsäureanhydrids与二硅氧烷键的方法。
公开(公告)号：EP0320211A2
公开(公告)日：1989-06-14
申请号：EP88311546.1
申请日：1988-12-06
申请人： Hitachi Chemical Co., Ltd.
发明人： Kikuchi, Tohru , Kamijima, Koichi , Saito, Takayuki
IPC分类号： C07F7/08 , C08G59/42
CPC分类号： C07F7/0852 , C08G59/423
摘要： 1-(2,3-Dicarboxyphenyl)-3-(3,4 dicarboxyphenyl)-1,1,3,3-tetramethyldisiloxane dianhydride is useful as a curing agent for epoxy resins.
摘要翻译： 1-（2,3-二羧基苯基）-3-（3,4-二羧基苯基）-1,1,3,3-四甲基二硅氧烷二酐是作为固化剂的环氧树脂是有用的。

4. 发明授权

EP0311374B1 Dicylcohexyl-3,4,3'4'-tetra-carboxylic acid or dianhydride thereof and polyamide-acid and polymide obtained therefrom 失效
标题翻译： DICYLCOHEXYL-3,4,3'4'-四羧酸或其二羧酸和其中获得的聚酰胺和聚酰胺
公开(公告)号：EP0311374B1
公开(公告)日：1992-09-09
申请号：EP88309277.7
申请日：1988-10-05
申请人： Hitachi Chemical Co., Ltd.
发明人： Kikuchi, Tohru , Fujita, Toshiyuki , Saito, Takayuki , Kojima, Mitsumasa , Sato, Hidetaka , Suzuki, Hiroshi
IPC分类号： C07C61/12
CPC分类号： C08G73/1021 , C07C61/12 , C08G73/1028 , C08G73/106 , Y10T428/1018 , Y10T428/1023

5. 发明公开

EP0391665A1 Amino compounds, amino resins obtained therefrom, production of amino resins and resin compositions for water-borne coatings 失效
标题翻译：从其氨基树脂，氨基树脂和水溶性涂料的树脂混合物的制备中获得的氨基化合物。
公开(公告)号：EP0391665A1
公开(公告)日：1990-10-10
申请号：EP90303560.8
申请日：1990-04-03
申请人： Hitachi Chemical Co., Ltd.
发明人： Semba, Reiko , Hasebe, Mariko , Moribe, Isamu , Narushima, Ryoichi, San Haitsu Taga 512 , Kikuchi, Tohru , Saito, Takayuki , Kobayashi, Akihiro
IPC分类号： C07D251/48 , C08G18/16 , C08G18/20 , C08G18/02
CPC分类号： C08G12/30 , C07D251/18 , C08K5/3492 , C08L61/20
摘要： An amino compound of formula (I):
wherein R₁, R₂, R₃, R₄, R₅, R₆, R₇ and R₈ are independently -H, -CH₂OH or -CH₂OCH₃, with the proviso that not all of R₁ through R₈ are simultaneously hydrogen.
摘要翻译：式（I）的氨基化合物： worin R1，R2，R3，R4，R5，R6，R7和R8是-Hunabhängig，-CH 2 OH或-CH 2 OCH 3，其条件没有全部R 1至R 8是同时为氢。

6. 发明公开

EP0373952A3 Photosensitive resin composition and photosensitive element using the same 失效
标题翻译：光敏树脂组合物和使用它的感光元素
公开(公告)号：EP0373952A3
公开(公告)日：1990-10-03
申请号：EP89313131.8
申请日：1989-12-15
申请人： Hitachi Chemical Co., Ltd.
发明人： Satoh, Kuniaki , Kojima, Yasunori , Tachiki, Shigeo , Kikuchi, Tohru , Ishimaru, Toshiaki , Hayashi, Nobuyuki , Kojima, Mitsumasa
IPC分类号： G03F7/038 , G03F7/075
CPC分类号： C08G77/54 , C08G69/42 , C08G73/1039 , C08G73/106 , G03F7/0387 , G03F7/0757
摘要： A photosensitive resin composition comprising a photoinitiator and polymer containing a repeating unit of formula (I)
wherein R 1 is a tetravalent organic group, R 2 is a divalent organic group, either one or both of R 1 and R 2 contains at least one silicon atom and/or at least one fluorine atom, Y, is a monovalent group having an ethylenic unsaturated group; n is zero or 1, m is 1 or 2, and n + m = 2.

7. 发明授权

EP0373952B1 Photosensitive resin composition and photosensitive element using the same 失效
标题翻译：一种光敏树脂组合物和使用该组合物的感光元件。
公开(公告)号：EP0373952B1
公开(公告)日：1995-02-08
申请号：EP89313131.8
申请日：1989-12-15
申请人： Hitachi Chemical Co., Ltd.
发明人： Satoh, Kuniaki , Kojima, Yasunori , Tachiki, Shigeo , Kikuchi, Tohru , Ishimaru, Toshiaki , Hayashi, Nobuyuki , Kojima, Mitsumasa
IPC分类号： G03F7/038 , G03F7/075
CPC分类号： C08G77/54 , C08G69/42 , C08G73/1039 , C08G73/106 , G03F7/0387 , G03F7/0757

8. 发明公开

EP0311374A3 Dicylcohexyl-3,4,3'4'-tetra-carboxylic acid or dianhydride thereof and polyamide-acid and polymide obtained therefrom 失效
标题翻译： DICYLCOHEXYL-3,4,3'4'-四羧酸或其二羧酸和聚酰胺酸及其获得的聚合物
公开(公告)号：EP0311374A3
公开(公告)日：1990-09-26
申请号：EP88309277.7
申请日：1988-10-05
申请人： Hitachi Chemical Co., Ltd.
发明人： Kikuchi, Tohru , Fujita, Toshiyuki , Saito, Takayuki , Kojima, Mitsumasa , Sato, Hidetaka , Suzuki, Hiroshi
IPC分类号： C07C61/12
CPC分类号： C08G73/1021 , C07C61/12 , C08G73/1028 , C08G73/106 , Y10T428/1018 , Y10T428/1023
摘要： A polyimide obtained from a polyamide-acid or polyamide-acid ester prepared by reacting dicyclohexyl-3,4,3′,4′-tetracarboxylic acid or dianhydride with a diamine is excellent in transparency, heat resistance and mechanical properties, said polyimide being able to be obtained at a lower temperature, and particularly suitable for an orientation film used in liquid crystal display device.

9. 发明公开

EP0320211A3 Process for producing a tetracarboxylic acid anhydride having disiloxane linkage 失效
标题翻译：具有邻苯二甲酸酯的四羧酸酐及其制备方法
公开(公告)号：EP0320211A3
公开(公告)日：1990-03-14
申请号：EP88311546.1
申请日：1988-12-06
申请人： Hitachi Chemical Co., Ltd.
发明人： Kikuchi, Tohru , Kamijima, Koichi , Saito, Takayuki
IPC分类号： C07F7/08 , C08G59/42
CPC分类号： C07F7/0852 , C08G59/423
摘要： 1-(2,3-Dicarboxyphenyl)-3-(3,4 dicarboxyphenyl)-1,1,3,3-tetramethyldisiloxane dianhydride is useful as a curing agent for epoxy resins.

10. 发明公开

EP0292260A2 Process for producing 1,3-bis(dicarboxyphenyl)-disiloxane derivative or dianhydride thereof 失效
标题翻译： Verfahren zur产品von 1,3-双（二羧基苯基）二硅氧烷衍生物，deren Dianhydriden。
公开(公告)号：EP0292260A2
公开(公告)日：1988-11-23
申请号：EP88304499.2
申请日：1988-05-18
申请人： Hitachi Chemical Co., Ltd.
发明人： Kikuchi, Tohru , Fujita, Toshiyuki , Kamijima, Koichi , Saito, Takayuki
IPC分类号： C07F7/08
CPC分类号： C07F7/0874 , C07F7/0889
摘要： A process for producing a compound of formula [V] or a dianhydride thereof
wherein R and R′ are the same or different and each is methyl or phenyl comprising
coupling a Grignard reagent of halo-o-xylene with a disubstituted halosilane
wherein X is halogen,
hydroxylating the product silane to form a hydroxysilane
dehydrating-condensing the hydroxysilane to form a 1,3-bisdimethylphenyl-disilane derivative
oxidizing the 1,3-bis(dimethylphenyl)disilane derivative to yield the intended 1,3-bis(dicarboxyphenyl)disiloxane derivative. The dianhydride is formed by dehydration ring closure of this product and [VI], mixing the resulting isomeric mixture with an ether solvent, and recovering the formed precipitate to yield a white powder of the intended dianhydride.
摘要翻译：制备式[Ⅴ]化合物或其二酐的方法，其中R和R min相同或不同，各自为甲基或苯基，包括将卤代邻二甲苯格氏试剂与二取代卤代硅烷偶联， CHEM>其中X是卤素，羟基化产物硅烷以形成羟基硅烷，使羟基硅烷脱水缩合，形成氧化1,3-双（二甲基苯基）乙硅烷衍生物的1,3-双（二甲基苯基）乙硅烷衍生物，得到预期的1,3 双（二羧基苯基）二硅氧烷衍生物。通过该产物和[VI]的脱水闭合形成二酐，将得到的异构体混合物与醚溶剂混合，并回收形成的沉淀物，得到所需二酐的白色粉末。

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