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    • 1. 发明公开
    • URETHANE ADHESIVE FOR OUTDOOR USE
    • URETHANKLEBSTOFFFÜRDEN AUSSENBEREICH
    • EP2647684A1
    • 2013-10-09
    • EP11845169.9
    • 2011-11-28
    • Henkel Japan Ltd.Henkel AG & Co. KGaA
    • MATSUKI, YuichiYOSHIDA, YoshioHAYAKAWA, Tadashi
    • C09J175/06C09J11/06H01L31/042
    • H01L31/0487C08G18/3851C09J175/04H01L31/049Y02E10/50
    • Provided are a urethane adhesive for outdoor use which has high peel strength and excellent weatherability, a solar-cell back sheet obtained using the adhesive, and a solar-cell module obtained using the solar-cell back sheet. The urethane adhesive for outdoor use comprises (A) a urethane resin obtained by reacting one or more isocyanate compounds (a1) with a polyol (a2) having an ester bond and (B) a hydroxyphenyltriazine compound, the isocyanate compounds (a1) comprising at least one compound selected from aliphatic isocyanates and alicyclic isocyanates. The adhesive has high peel strength and excellent weatherability. The urethane resin for outdoor use which further contains a silane compound is more preferable.
    • 本发明提供一种具有高剥离强度和优异的耐候性的户外用聚氨酯粘合剂,使用该粘合剂得到的太阳能电池背板,以及使用太阳能电池背板获得的太阳能电池组件。 用于室外的聚氨酯粘合剂包括(A)通过使一种或多种异氰酸酯化合物(a1)与具有酯键的多元醇(a2)反应得到的聚氨酯树脂和(B)羟基苯基三嗪化合物,异氰酸酯化合物(a1) 选自脂族异氰酸酯和脂环族异氰酸酯的至少一种化合物。 该粘合剂具有高的剥离强度和优异的耐候性。 进一步含有硅烷化合物的室外用聚氨酯树脂是更优选的。
    • 3. 发明公开
    • ADHESIVE FOR SOLAR CELL BACK SHEET
    • KLEBSTOFFFÜRRÜCKSEITIGEFOLIE EINER SOLARZELLE
    • EP2671930A1
    • 2013-12-11
    • EP11852737.3
    • 2011-12-22
    • Henkel AG & Co. KGaA
    • ITO, ShokoYOSHIDA, YoshioMATSUKI, Yuichi
    • C09J175/04C09J7/02H01L31/042
    • H01L31/0487C08G18/6225C08G18/73C08K5/3492C09J7/22C09J7/35C09J175/04C09J2203/322C09J2205/102C09J2475/00H01L31/049Y02E10/50
    • An object of the present invention is to provide an adhesive for solar battery backsheet, which has satisfactory initial adhesion to a film at the time of the production of the solar battery backsheet and satisfactory adhesive strength to a film after aging, and is also excellent in long-term weatherability and hydrolysis resistance. Further object is to provide a solar battery backsheet obtainable by using the adhesive, and a solar battery module obtainable by using the backsheet. Disclosed is an adhesive for solar battery backsheet obtainable by the reaction of an acrylic polyol (a1) with an isocyanate compound (a2), in which the acrylic polyol (a1) has a glass transition temperature of 20°C or lower. The adhesive has satisfactory initial adhesion to a film at the time of the production of the solar battery backsheet and satisfactory adhesive strength to a film after aging, and is also excellent in long-term weatherability and hydrolysis resistance. The adhesive for solar battery backsheet, in which the acrylic polyol (a1) has a hydroxyl value of 0.5 to 40 mgKOH/g, is more preferable.
    • 本发明的目的是提供一种用于太阳能电池背板的粘合剂,其在生产太阳能电池底片时对膜具有令人满意的初始粘合性,并且对于老化后的膜具有令人满意的粘合强度,并且还优异 长期耐候性和耐水解性。 另外的目的是提供一种通过使用该粘合剂获得的太阳能电池背板,以及通过使用该底片可获得的太阳能电池组件。 公开了通过丙烯酸多元醇(a1)与异氰酸酯化合物(a2)的反应获得的太阳能电池背板的粘合剂,其中丙烯酸多元醇(a1)的玻璃化转变温度为20℃以下。 粘合剂在制造太阳能电池背板时对膜具有令人满意的初始粘合性,并且在老化后对膜具有令人满意的粘合强度,并且长期耐候性和耐水解性也优异。 其中丙烯酸多元醇(a1)的羟值为0.5〜40mgKOH / g的太阳能电池底片用粘合剂是更优选的。
    • 4. 发明公开
    • OUTDOOR URETHANE ADHESIVE AGENT
    • AUSSEN-URETHANHAFTMITTEL
    • EP2679650A1
    • 2014-01-01
    • EP11853024.5
    • 2011-12-22
    • Henkel AG & Co. KGaA
    • MATSUKI, YuichiYOSHIDA, YoshioITO, Shoko
    • C09J175/04C08G18/42C08G18/62C09J11/06C09J175/06H01L31/042
    • H01L31/0487C08G18/4063C08G18/4211C08G18/4216C08G18/4286C08G18/6229C08G18/7642C08G18/792C08G18/8029C09J7/22C09J7/30C09J175/06C09J2203/322C09J2475/00H01L31/049Y02E10/50Y10T428/2896
    • Provided are: an outdoor urethane adhesive agent which has excellent initial adhesion properties, exhibits excellent adhesion properties after being cured, can be cured into a coating film having excellent flexibility, and preferably has superior weather resistance; a solar cell back sheet which is produced using the adhesive agent; and a solar cell module which is produced using the solar cell back sheet. An outdoor urethane adhesive agent (A) comprising a urethane resin (A) produced by the reaction of an isocyanate compound (a1) with a polyol (a2) having an ester bond, wherein the isocyanate compound (a1) comprises at least one compound selected from aliphatic isocyanates and alicyclic isocyanates, and the polyol (a2) comprises both a polyester polyol (a2-1) and an acrylic polyol (a2-2). The adhesive agent has excellent initial adhesion properties, exhibits excellent adhesion properties after being cured, and can be cured into a coating film. having excellent flexibility. When the adhesive agent additionally contains a hydroxyphenyltriazine-type compound, the adhesive agent can rarely undergo the change in color and can have superior weather resistance.
    • 提供:具有优异的初始粘合性,在固化后表现出优异的粘附性的室外聚氨酯粘合剂可以固化成具有优异柔性的涂膜,并且优选具有优异的耐候性; 使用粘合剂制造的太阳能电池背板; 以及使用太阳能电池背板制造的太阳能电池模块。 一种室外聚氨酯粘合剂(A),其包含通过异氰酸酯化合物(a1)与具有酯键的多元醇(a2)反应制备的聚氨酯树脂(A),其中所述异氰酸酯化合物(a1)包含至少一种选自 脂肪族异氰酸酯和脂环族异氰酸酯,多元醇(a2)包含聚酯多元醇(a2-1)和丙烯酸多元醇(a2-2)。 粘合剂具有优异的初始粘合性能,在固化后表现出优异的粘合性能,并且可以固化成涂膜。 具有极好的灵活性。 当粘合剂另外含有羟基苯基三嗪型化合物时,粘合剂很少会发生颜色变化,并且可以具有优异的耐候性。