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1. 发明公开

EP0705857A3 A process for producing polymers of alpha,omega-unsaturated conjugated compounds 失效
标题翻译：一种用于α，ω-不饱和共轭化合物的聚合物的制备方法
公开(公告)号：EP0705857A3
公开(公告)日：1996-08-21
申请号：EP95114837.8
申请日：1995-09-21
申请人： HOECHST AKTIENGESELLSCHAFT
发明人： Stern, Roland, Dr. , VanDerZande, Dirk, Prof. Dr. , Louwet, Frank, Dr. , Gelan, Joanes, Prof. Dr. , Issaris, Anna , Van Der Broght, Michael
IPC分类号： C08G61/00 , C09K11/06 , H05B33/14 , C07C317/10 , C07C33/24
CPC分类号： C08G61/00 , C09K11/06 , H05B33/14
摘要： A process for producing polymers of α,ω-unsaturated conjugated compounds, which comprises reacting a precursor monomer of the formula (I),

wherein
P denotes -SR³, -SO-R³, -SO₂-R³, -COOR³, -NO₂, -CN, -CF₃ or R³; L denotes -Cl, -Br, -I, -O-tosylate, -O-mesylate, -O-triflate, -(NR³₃) ⊕ or -(SR³R⁴) ⊕ ; R¹, R² are the same or different and denote H, R³ or P; R³, R⁴ are independently, a straight chain or branched alkyl group with 1 to 20 carbon atoms, phenyl or benzyl, either of which can be substituted once or twice with -R³, -OR¹, -NO₂, -CN, Br, Cl, F; or R³ and R⁴ together are -(CH₂)₄ or -(CH₂)₅- and A an aromatic system comprising from 4 to 20 carbon atoms, which can optionally be substituted, with a base in a solvent, characterized in that on reaction of the base with the compound of the formula (I) a polymer is formed which is essentially soluble in said solvent, and a salt is formed as a by-product, which is essentially soluble in said solvent, and that said solvent comprises a compound selected from the group consisting of a) amides of the general formula (II)
R⁵-CO-NR⁶H (II) b) amines of the general formula (III)
R⁷₂-N-R⁸ (III) c) sulfones of the general formula (IV)
R⁸-SO₂-R⁹ (IV) d) sulfoxides of the general formula (V)
R⁸-SO-R⁹ (V) e) a solvent from the group consisting of alcohols, polyalcohols, glycols and polyethers; wherein
R⁵, R⁶ are the same or different and denote H, a straight chain or branched alkyl group, or R⁵ and R⁶ together are -(CH₂)₂-, -(CH₂)₃-or -(CH₂)₄-; R⁷ has the meaning of R⁵ or a phenyl group which is unsubstituted or substituted by halogen, methyl and methoxy groups and R⁸, R⁹ are the same or different and denote R⁷, except H, R⁸ and R⁹ together are -(CH₂)₂-, -(CH₂)₃-, -(CH₂)₄- or -CH₂-CH = CH-CH₂-. According to the novel process chemically and thermally stable, high molecular weight polymers of high purity and high regularity are obtained in good yield. If the products of the novel process carry groups that undergo elimination to form double bonds, high quality electroluminescent materials can be prepared.

2. 发明公开

EP0705857A2 A process for producing polymers of alpha,omega-unsaturated conjugated compounds 失效
标题翻译：一种用于α，ω-不饱和共轭化合物的聚合物的制备方法
公开(公告)号：EP0705857A2
公开(公告)日：1996-04-10
申请号：EP95114837.8
申请日：1995-09-21
申请人： HOECHST AKTIENGESELLSCHAFT
发明人： Stern, Roland, Dr. , VanDerZande, Dirk, Prof. Dr. , Louwet, Frank, Dr. , Gelan, Joanes, Prof. Dr. , Issaris, Anna , Van Der Broght, Michael
IPC分类号： C08G61/00 , C09K11/06 , H05B33/14 , C07C317/10 , C07C33/24
CPC分类号： C08G61/00 , C09K11/06 , H05B33/14
摘要： A process for producing polymers of α,ω-unsaturated conjugated compounds, which comprises reacting a precursor monomer of the formula (I),

wherein

P denotes -SR³, -SO-R³, -SO₂-R³, -COOR³, -NO₂, -CN, -CF₃ or R³;
L denotes -Cl, -Br, -I, -O-tosylate, -O-mesylate, -O-triflate, -(NR³₃) ⊕ or -(SR³R⁴) ⊕ ;
R¹, R² are the same or different and denote H, R³ or P;
R³, R⁴ are independently, a straight chain or branched alkyl group with 1 to 20 carbon atoms, phenyl or benzyl, either of which can be substituted once or twice with -R³, -OR¹, -NO₂, -CN, Br, Cl, F; or R³ and R⁴ together are -(CH₂)₄ or -(CH₂)₅- and
A an aromatic system comprising from 4 to 20 carbon atoms, which can optionally be substituted,
with a base in a solvent, characterized in that on reaction of the base with the compound of the formula (I) a polymer is formed which is essentially soluble in said solvent, and a salt is formed as a by-product, which is essentially soluble in said solvent, and that said solvent comprises a compound selected from the group consisting of

a) amides of the general formula (II)

R⁵-CO-NR⁶H (II)

b) amines of the general formula (III)

R⁷₂-N-R⁸ (III)

c) sulfones of the general formula (IV)

R⁸-SO₂-R⁹ (IV)

d) sulfoxides of the general formula (V)

R⁸-SO-R⁹ (V)

e) a solvent from the group consisting of alcohols, polyalcohols, glycols and polyethers;
wherein

R⁵, R⁶ are the same or different and denote H, a straight chain or branched alkyl group, or R⁵ and R⁶ together are -(CH₂)₂-, -(CH₂)₃-or -(CH₂)₄-;
R⁷ has the meaning of R⁵ or a phenyl group which is unsubstituted or substituted by halogen, methyl and methoxy groups and
R⁸, R⁹ are the same or different and denote R⁷, except H, R⁸ and R⁹ together are -(CH₂)₂-, -(CH₂)₃-, -(CH₂)₄- or -CH₂-CH = CH-CH₂-.

According to the novel process chemically and thermally stable, high molecular weight polymers of high purity and high regularity are obtained in good yield. If the products of the novel process carry groups that undergo elimination to form double bonds, high quality electroluminescent materials can be prepared.
摘要翻译：一种用于生产α，ω-不饱和共轭系化合物，该方法包括使式（I）的前体单体的聚合物的方法 worin P表示-SR <3>，-SO-R <3>， - SO2- [R <3>，COOR <3>，-NO 2，-CN，-CF 3或R <3>; L表示-Cl，-Br，-I，-O-甲苯磺酸酯，-O-甲磺酸酯，-O-三氟甲磺酸酯， - （NR <3> 3）<（+）>或 - （SR <3> [R <4> ）<（+）>; [R <1>，R <2>是相同的或不同的，并且表示H，R <3>或P; [R <3>，R <4>是unabhängig，直链或支链烷基具有1至20个碳原子，苯基或苄基，其任一的可substituiertem一次或两次-R <3>，-OR <1 >，-NO 2，-CN，溴，氯，F; 或R <3>和R <4>一起为 - （CH 2）4 - 或 - （CH 2）5和A与芳族系统的4至20个碳原子，其包括，其可以在溶剂中任选substituiertem，用碱其特征在于，做了与式（I）的化合物的聚合物形成的所有这是在所述溶剂基本上可溶的，和盐形成作为副产物，该碱的反应所有这一切在所述研究生基本上可溶的，并做所述溶剂包括选自组（II）R <5> -CO-NR <6> H b）（III）R通式的胺由......组成通式的）酰胺<7> 2-NR中的一种化合物 <8> c）该通式的砜（IV）R <8> -SO 2 -R <9> d）中通式（V）R <8> -SO-R <9> e）由溶剂的亚砜所述组包括醇，多元醇，乙二醇和聚醚; worinř<5> - [R <6>是相同的或不同的，并且表示H，直链或支链烷基，或R <5>和R <6>一起为 - （CH2）2-， - （CH2） 3-或 - （CH2）4-; [R <7>具有R的含义<5>或苯基所有这些是由卤素，甲基和甲氧基和R <8>，R <9>是相同的或不同的，并且表示 - [R <7> unsubstituiertem或substituiertem 除了H，R <8>和R <9>一起为 - （CH2）2-， - （CH2）3-， - （CH2）4-或-CH 2 -CH = CH-CH 2 - 。。根据该新方法化学和高纯度和高的规则性热稳定的，高分子量的聚合物，获得以良好的收率。如果该新方法进位组的产品确实经历消除以形成双键，高品质的电致发光材料可被制备。

3. 发明公开

EP0644217A1 A process for producing polymers of alpha,omega-unsaturated conjugated compounds, and high molecular weight conjugated polymers thus obtainable 失效
标题翻译：一种用于α-ω-不饱和化合物的聚合物和所获得的高分子的共轭聚合物的制备方法。
公开(公告)号：EP0644217A1
公开(公告)日：1995-03-22
申请号：EP94113883.6
申请日：1994-09-05
申请人： HOECHST AKTIENGESELLSCHAFT
发明人： Gelan, Joanes, Prof. Dr. , Vanderzande, Dirck, Prof. Dr. , Louwet, Frank, Dr.
IPC分类号： C08G61/02
CPC分类号： C08G61/02
摘要： A process for producing polymers of α,ω-unsaturated conjugated compounds, which comprises reacting a compound of the formula (I),

B-A-C (I)

wherein

B denotes a sp³-hybridized carbon atom carrying at least one hydrogen atom,
A denotes a conjugated-π-system or a -CH=CH-group, and
C denotes a carbon atom carrying at least one leaving group,
with a base in a solvent, is characterized in that on reaction of the base with the compound of the formula (I) a polymer is formed which is essentially soluble in said solvent and a solid is formed as a by-product which is essentially insoluble in said solvent, and that said solvent comprises a compound selected from the group consisting of

a) amides of the general formula (II)

R¹-CO-NR²R³ (II)

b) urea derivatives of the general formula (III)

R¹R³N-CO-NR²R⁴ (III)

c) carbonates of the general formula (IV)

R¹O-CO-OR² (IV)

d) nitroalkanes of the general formula (V)

R⁶-NO₂ (V)

e) nitriles of the general formula (VI)

R⁶-CN (VI)

f) amines of the general formula (VII)

R⁵₂-N-R⁶ (VII)

g) sulfones of the general formula (VIII)

R⁶-SO₂-R⁶ (VIII)

h) sulfoxides of the general formula (IX)

R⁶-SO-R⁶ (IX)

i) phosphoramides of the general formula (X)

((R⁶)₂)N)₃-P=O (X)

j) sulfonates of the general formula (XI)

R⁶-SO₂-O-R⁶ (XI)

in which formulae (II) to (XI)

R¹, R², R³ and R⁴ denote, independently of each other, H or a straight chain or branched alkyl group, or R¹ and R² together are -(CH₂)₂-, -(CH₂)₃- or -(CH₂)₄-,
R⁵ has the meaning of R¹ or is a phenyl group or a phenyl group substituted by halogen, methyl and methoxy groups, and
R⁶ has the meaning of R⁵, except H.

According to the novel process, chemically and thermally stable, high molecular weight polymers of high purity and high regularity are obtained in good yield. If the products of the novel process carry groups that undergo elimination, forming double bonds, high quality electroluminescent materials can be prepared.
摘要翻译：一种用于生产α，ω-不饱和共轭系化合物，该方法包括使式（I）的化合物的聚合物的方法，BAC（I> worin B表示SP <携带至少一个氢原子3>杂化碳原子，A 表示缀合的PI -System或CH = CH基团，和C表示携带在溶剂中的至少一个离去基团，与一种碱的碳原子，其特征在于上的化合物中的碱的反应没有式（I）的聚合物形成的所有其基本上可溶于所述溶剂和固体形成作为副产物的所有这是在所述溶剂基本上不溶性的，并且所述的溶剂包括选自下组的一个）的酰胺的化合物通式（II> - [R <1> -CO-NR <2> [R <3>（II> b）该通式（III> - [R <1>的R脲衍生物<3>的N- CO-NR <2 > - [R <4>（III> C）（通式碳酸盐IV> - [R <1> O-CO-OR <2>（通式IV> D）硝基烷烃（V> [R <6> -NO 2（ V> E）（通式VI腈> - [R <6 > -CN（VI> F），通式（VII>的R胺<5> 2-NR <6>（VII>克）通式（VIII的砜> - [R <6> -SO 2 -R <6> （VIII> h）中通式的亚砜（IX> - [R <6> -SO-R <6>（IX>ⅰ）（通式磷酰胺X>（（R <6>）2）N）3- P = O（X> j）的通式的磺酸酯（XI> - [R <6> -SO 2 OR <6>（XI）（其中，式（II）至XI）R <1>，R <2>， [R <3>和R <4>表示，海誓山盟unabhängig，H或直链或支链烷基，或R <1>和R <2>一起为 - （CH 2）2， - （CH 2）3 - 或 - （CH 2）4，R <5>具有R的含义<1>或为苯基或由卤素，甲基和甲氧基的苯基substituiertem，且R <6>具有R的含义< 5>除了H.。根据该新方法，经化学和高纯度和高的规则性热稳定的，高分子量的聚合物，获得以良好的收率。如果该新方法进位组的产品确实经历消除，形成的双键，高品质的电致发光材料可被制备。

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