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    • 3. 发明公开
    • Resin-impregnated superconducting magnet coil and process for it production
    • Supraleitende Magnetspule und darin verwendetehärtbareHarzzusammensetzung。
    • EP0488275A2
    • 1992-06-03
    • EP91120374.3
    • 1991-11-28
    • HITACHI, LTD.
    • Koyama, ToruHonjo, KooSuzuki, MasaoTakahashi, AkioMukoh, AkioFukushi, KeijiNumata, Seiji
    • H01F6/06
    • H01F6/06Y10S428/93Y10S505/705Y10S505/813Y10S505/884Y10S505/887Y10T428/31678Y10T428/31681Y10T428/31721Y10T428/31725
    • A superconducting magnet coil contains a coil of superconducting wire (2) and a cured product (3) of a curable resin composition with which the coil has been impregnated, the cured product having a thermal shrinkage factor of 1.5-0.3%, preferably 1.0-0.3%, when cooled from the glass transition temperature to 4.2 K, a bend-breaking strain of 2.9-3.9%, preferably 3.2-3.9%, at 4.2 K and a modulus of 500-1,000 kg/mm² at 4.2 K, or undergoing a thermal stress of 0-10 kg/mm² when cooled from the glass transition temperature to 4.2 K and resisting to quench during superconducting operation.
      It is produced by winding a superconducting wire (2) to form a coil; impregnating the coil with a curable resin composition of low viscosity which contains for example at least one epoxy resin selected from the group consisting of diglycidyl ether of bisphenol A, diglycidyl ether of bisphenol F and diglycidyl ether of bisphenol AF, all having a number-average molecular weight of 350-1,000, a flexibilizer and a curing catalyst, to obtain a curable-resin composition-impregnated coil; and heating the curable-resin-composition-impregnated coil to cure the composition.
    • 超导磁体线圈包含超导线圈(2)和已经浸渍线圈的固化树脂组合物的固化产物(3),固化产物的热收缩率为1.5-0.3%,优选为1.0- 0.3%,当从玻璃化转变温度冷却至4.2K时,在4.2K时的断裂应变为2.9-3.9%,优选3.2-3.9%,在4.2K时的弯曲应变为500-1,000kg / mm 2 ,或者当从玻璃化转变温度冷却至4.2K并且在超导操作期间耐骤冷时,经历0-10kg / mm 2的热应力。 通过缠绕超导线(2)以形成线圈来产生; 用低粘度的可固化树脂组合物浸渍线圈,其包含例如至少一种选自双酚A的二缩水甘油醚,双酚F的二缩水甘油醚和双酚AF的二缩水甘油醚的环氧树脂,全部具有数均分子量 分子量为350〜1,000,增韧剂和固化催化剂,得到固化树脂组合物浸渍线圈; 并加热固化树脂组合物浸渍的线圈以固化组合物。