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1. 发明公开

EP0398503A2 Rare-earth barium copper oxide superconducting materials 失效
标题翻译： Oxid von seltenen Erden，Barium und Kupfer als supraleitende Materialien。
公开(公告)号：EP0398503A2
公开(公告)日：1990-11-22
申请号：EP90304155.6
申请日：1990-04-18
申请人： HER MAJESTY THE QUEEN IN RIGHT OF NEW ZEALAND
发明人： Tallon, Jeffery Lewis , Pooke, Donald Mark , Presland, Murray Robert
IPC分类号： C01G3/00 , C04B35/00
CPC分类号： C04B35/4504 , C01B13/185 , C01G3/006 , C01P2002/72 , C01P2002/76 , C01P2002/77 , C01P2006/36 , H01L39/126
摘要： The invention comprises metal oxide materials which exhibit bulk superconductivity at a T c in excess of 85K in some cases, within the formula
R 1-x Ba 2-y A x+y Cu a O 8-δ
where:
O≦x
-0.25
3.9
R is Y, La, Nd, Sm, Eu, Gd, Ho, Er, Tm or Yb or any combination thereof,
Ba is Ba or Ba partially substituted by either or both of Sr and La,
A is most preferably Ca but may be Li, Na, K, Rb or Cs, or any combination thereof,
Cu is Cu or Cu partially substituted by Ag, Au, Hg, Tl, Bi, Pb, Sb or Ga, or any Periodic Table transition metal element or Group 3A, 4A or 5A metal or any combination thereof, and
O is O or O partially substituted by N, P, S, Se, or F or any combination thereof.
Novel processes for preparation of the materials comprising reacting precursor materials for between 1 and 300 hours at a temperature T and oxygen partial pressure Po₂ satisfying the equation T
摘要翻译：本发明包括金属氧化物材料，其在一些情况下在一些情况下在式R1-xBa2-yAx + yCuaO8-δ中表现出超过85K的体积超导性，其中：O ，其中L = log10Po2反应前体材料的新方法也被公开并要求保护。制备反应可以以化学计量比例的前体材料的固态或液体通量反应进行，并且可以使用包含碱的氧化物，氯化物，硝酸盐，氢氧化物或碳酸盐的碱金属助熔剂，催化剂或反应速率增强剂。

2. 发明授权

EP0411943B1 Metal oxide 247 superconducting materials 失效
标题翻译：超导金属氧化物-247
公开(公告)号：EP0411943B1
公开(公告)日：1997-10-15
申请号：EP90308526.4
申请日：1990-08-02
申请人： HER MAJESTY THE QUEEN IN RIGHT OF NEW ZEALAND
发明人： Tallon, Jeffrey Lewis , Buckley, Robert George , Pooke, Donald Mark
IPC分类号： C04B35/00 , H01L39/24
CPC分类号： H01L39/12 , C04B35/4504 , C04B35/64 , H01L39/126 , Y10S505/725 , Y10S505/776 , Y10S505/779 , Y10S505/78

3. 发明公开

EP0398503A3 Rare-earth barium copper oxide superconducting materials 失效
标题翻译：稀土钡铜氧化物超导材料
公开(公告)号：EP0398503A3
公开(公告)日：1991-09-25
申请号：EP90304155.6
申请日：1990-04-18
申请人： HER MAJESTY THE QUEEN IN RIGHT OF NEW ZEALAND
发明人： Tallon, Jeffery Lewis , Pooke, Donald Mark , Presland, Murray Robert
IPC分类号： C01G3/00 , C04B35/00
CPC分类号： C04B35/4504 , C01B13/185 , C01G3/006 , C01P2002/72 , C01P2002/76 , C01P2002/77 , C01P2006/36 , H01L39/126
摘要： The invention comprises metal oxide materials which exhibit bulk superconductivity at a T c in excess of 85K in some cases, within the formula
R 1-x Ba 2-y A x+y Cu a O 8-δ
where:
O≦x
-0.25
3.9
R is Y, La, Nd, Sm, Eu, Gd, Ho, Er, Tm or Yb or any combination thereof,
Ba is Ba or Ba partially substituted by either or both of Sr and La,
A is most preferably Ca but may be Li, Na, K, Rb or Cs, or any combination thereof,
Cu is Cu or Cu partially substituted by Ag, Au, Hg, Tl, Bi, Pb, Sb or Ga, or any Periodic Table transition metal element or Group 3A, 4A or 5A metal or any combination thereof, and O is O or O partially substituted by N, P, S, Se, or F or any combination thereof. Novel processes for preparation of the materials comprising reacting precursor materials for between 1 and 300 hours at a temperature T and oxygen partial pressure Po₂ satisfying the equation T

4. 发明公开

EP0394015A3 Methods for producing high temperature superconducting materials 失效
标题翻译：生产高温超导材料的方法
公开(公告)号：EP0394015A3
公开(公告)日：1991-09-25
申请号：EP90304156.4
申请日：1990-04-18
申请人： HER MAJESTY THE QUEEN IN RIGHT OF NEW ZEALAND
发明人： Tallon, Jeffery Lewis , Pooke, Donald Mark , Presland, Murray Robert
IPC分类号： C04B35/00 , C01G3/00 , C01G1/00
CPC分类号： C04B35/4504 , C01B13/185 , C01G3/006 , C01P2002/72 , C01P2002/76 , C01P2002/77 , C01P2006/36 , H01L39/126
摘要： A method of preparing a binary, ternary or higher metal oxide material containing copper and as one or more cations Y and/or any lanthanide rare earth element and capable of displaying superconductivity above 77K, comprising preparing said material such that said Y or lanthanide rare earth cation(s) is/are partially substituted by a substituent cation or cations which exhibit chemical valency lower than that of the substituted cation, to an amount of the substituent(s) effective to achieve a rate of oxygen diffusion or rate of oxygen exchange within an oxygen-containing atmosphere sufficient to enable oxygen exchange or oxygen diffusion into or out of said material to achieve the oxygen stoichiometry in said material whereby the material exhibits said superconductivity above 77K in a reduced time relative to that required to produce the equivalent unsubstituted material of the same porosity exhibiting superconductivity at the same temperature by otherwise the same method, including carrying out said oxygen diffusion or exchange in said reduced time.
摘要翻译：本发明包括金属氧化物材料，其在一些情况下在一些情况下在式R1-xBa2-yAx + yCuaO8-δ中表现出超过85K的体积超导性，其中：O ，其中L = log10Po2反应前体材料的新方法也被公开并要求保护。制备反应可以以化学计量比例的前体材料的固态或液体通量反应进行，并且可以使用包含碱的氧化物，氯化物，硝酸盐，氢氧化物或碳酸盐的碱金属助熔剂，催化剂或反应速率增强剂。

5. 发明授权

EP0398503B1 Rare-earth barium copper oxide superconducting materials 失效
标题翻译：稀土，钡和铜作为超导材料的氧化物
公开(公告)号：EP0398503B1
公开(公告)日：1996-03-06
申请号：EP90304155.6
申请日：1990-04-18
申请人： HER MAJESTY THE QUEEN IN RIGHT OF NEW ZEALAND
发明人： Tallon, Jeffery Lewis , Pooke, Donald Mark , Presland, Murray Robert
IPC分类号： C01G3/00 , C04B35/00
CPC分类号： C04B35/4504 , C01B13/185 , C01G3/006 , C01P2002/72 , C01P2002/76 , C01P2002/77 , C01P2006/36 , H01L39/126

6. 发明公开

EP0411943A3 Metal oxide 247 superconducting materials 失效
标题翻译：金属氧化物247超级材料
公开(公告)号：EP0411943A3
公开(公告)日：1991-05-29
申请号：EP90308526.4
申请日：1990-08-02
申请人： HER MAJESTY THE QUEEN IN RIGHT OF NEW ZEALAND
发明人： Tallon, Jeffrey Lewis , Buckley, Robert George , Pooke, Donald Mark
IPC分类号： C04B35/00 , H01L39/24
CPC分类号： H01L39/12 , C04B35/4504 , C04B35/64 , H01L39/126 , Y10S505/725 , Y10S505/776 , Y10S505/779 , Y10S505/78
摘要： The present invention comprises novel oxide materials exhibiting bulk superconductivity up to and exceeding 85K and processes for their synthesis. The oxides are within the formula R a Ba b Cu c O d wherein 1.9

7. 发明公开

EP0411943A2 Metal oxide 247 superconducting materials 失效
标题翻译： Supraleitende 247-Metalloxidzusammensetzungen。
公开(公告)号：EP0411943A2
公开(公告)日：1991-02-06
申请号：EP90308526.4
申请日：1990-08-02
申请人： HER MAJESTY THE QUEEN IN RIGHT OF NEW ZEALAND
发明人： Tallon, Jeffrey Lewis , Buckley, Robert George , Pooke, Donald Mark
IPC分类号： C04B35/00 , H01L39/24
CPC分类号： H01L39/12 , C04B35/4504 , C04B35/64 , H01L39/126 , Y10S505/725 , Y10S505/776 , Y10S505/779 , Y10S505/78
摘要： The present invention comprises novel oxide materials exhibiting bulk superconductivity up to and exceeding 85K and processes for their synthesis. The oxides are within the formula R a Ba b Cu c O d wherein 1.9
摘要翻译：本发明包括表现出超过85K的超导体积的新型氧化物材料及其合成方法。氧化物在式RaBabCucOd中，其中1.9

8. 发明公开

EP0394015A2 Methods for producing high temperature superconducting materials 失效
标题翻译： Verfahren zur Herstellung von Hochtemperatur-Supraleitermaterialien。
公开(公告)号：EP0394015A2
公开(公告)日：1990-10-24
申请号：EP90304156.4
申请日：1990-04-18
申请人： HER MAJESTY THE QUEEN IN RIGHT OF NEW ZEALAND
发明人： Tallon, Jeffery Lewis , Pooke, Donald Mark , Presland, Murray Robert
IPC分类号： C04B35/00 , C01G3/00 , C01G1/00
CPC分类号： C04B35/4504 , C01B13/185 , C01G3/006 , C01P2002/72 , C01P2002/76 , C01P2002/77 , C01P2006/36 , H01L39/126
摘要： A method of preparing a binary, ternary or higher metal oxide material containing copper and as one or more cations Y and/or any lanthanide rare earth element and capable of displaying superconductivity above 77K, comprising preparing said material such that said Y or lanthanide rare earth cation(s) is/are partially substituted by a substituent cation or cations which exhibit chemical valency lower than that of the substituted cation, to an amount of the substituent(s) effective to achieve a rate of oxygen diffusion or rate of oxygen exchange within an oxygen-containing atmosphere sufficient to enable oxygen exchange or oxygen diffusion into or out of said material to achieve the oxygen stoichiometry in said material whereby the material exhibits said superconductivity above 77K in a reduced time relative to that required to produce the equivalent unsubstituted material of the same porosity exhibiting superconductivity at the same temperature by otherwise the same method, including carrying out said oxygen diffusion or exchange in said reduced time.
摘要翻译：一种制备二元，三元或更高金属氧化物材料的方法，其包含铜和一种或多种阳离子Y和/或任何镧系元素稀土元素并且能够显示高于77K的超导性，包括制备所述材料，使得所述Y或镧系稀土阳离子部分被取代阳离子部分或化学价低于取代阳离子的阳离子部分地取代成有效地达到氧扩散速率或氧气交换速率的取代基的量足以使氧气交换或氧气扩散进入或流出所述材料的含氧气体，以实现所述材料中的氧化学计量，由此该材料相对于产生等效的未取代材料所需的时间在缩短的时间内显示超过77K的超导性相同的孔隙率在相同的温度下表现出超导性，否则以相同的方法，包括汽车在所述减少的时间内消除所述氧气扩散或交换。

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