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1. 发明授权

EP2909155B1 PROCESS FOR THE PREPARATION OF BENZENE DERIVATIVES FROM FURAN DERIVATIVES 有权
标题翻译：由呋喃衍生物制备苯衍生物的方法
公开(公告)号：EP2909155B1
公开(公告)日：2018-01-31
申请号：EP13784017.9
申请日：2013-10-22
申请人： Furanix Technologies B.V. , The Coca-Cola Company
发明人： WANG, Bing , GRUTER, Gerardus Johannes Maria , DAM, Matheus Adrianus , KRIEGEL, Robert Michael
IPC分类号： C07C2/86 , C07C15/06 , C07C15/08
CPC分类号： C07C51/25 , C07C2/865 , C07C51/265 , C07C51/353 , C07C51/50 , C07C2521/08 , C07C2521/18 , C07C2523/44 , C07C2523/745 , C07C2523/89 , Y02P20/582 , C07C15/08 , C07C15/06 , C07C63/26
摘要： Benzene derivatives of the formula (I); wherein R1 and R2, are the same or different and independently are selected from the group consisting of hydrogen, alkyl, aralkyl, —CHO, —CH2OR3, —CH(OR4)(OR5) and —COOR6, wherein R3, R4 and R5 are the same or different and are selected from hydrogen, alkyl, aryl, alkaryl, aralkyl, alkylcarbonyl or arylcarbonyl, or wherein R4 and R5 together form an alkylene group and wherein R6 is selected from hydrogen, alkyl and aryl, are prepared in a process, which comprises: reacting a furan derivative of formula (II): wherein R1 and R2 have the meanings above, with ethylene under cycloaddition reaction conditions in the presence of an acid solvent to produce the benzene derivative, wherein the acid solvent is a carboxylic acid and is present in a weight ratio acid solvent to furan derivative from 1:1 to 250:1.

2. 发明公开

EP2909155A1 PROCESS FOR THE PREPARATION OF BENZENE DERIVATIVES FROM FURAN DERIVATIVES 有权
标题翻译： VERFAHREN ZUR HERSTELLUNG VON BENZOLDERIVATEN AUS FURANDERIVATEN
公开(公告)号：EP2909155A1
公开(公告)日：2015-08-26
申请号：EP13784017.9
申请日：2013-10-22
申请人： Furanix Technologies B.V. , The Coca-Cola Company
发明人： WANG, Bing , GRUTER, Gerardus Johannes Maria , DAM, Matheus Adrianus , KRIEGEL, Robert Michael
IPC分类号： C07C2/86 , C07C15/06 , C07C15/08 , C07C51/265 , C07C51/353 , C07C63/26
CPC分类号： C07C51/25 , C07C2/865 , C07C51/265 , C07C51/353 , C07C51/50 , C07C2521/08 , C07C2521/18 , C07C2523/44 , C07C2523/745 , C07C2523/89 , Y02P20/582 , C07C15/08 , C07C15/06 , C07C63/26
摘要： Benzene derivatives of the formula (I); wherein R1 and R2, are the same or different and independently are selected from the group consisting of hydrogen, alkyl, aralkyl, —CHO, —CH2OR3, —CH(OR4)(OR5) and —COOR6, wherein R3, R4 and R5 are the same or different and are selected from hydrogen, alkyl, aryl, alkaryl, aralkyl, alkylcarbonyl or arylcarbonyl, or wherein R4 and R5 together form an alkylene group and wherein R6 is selected from hydrogen, alkyl and aryl, are prepared in a process, which comprises: reacting a furan derivative of formula (II): wherein R1 and R2 have the meanings above, with ethylene under cycloaddition reaction conditions in the presence of an acid solvent to produce the benzene derivative, wherein the acid solvent is a carboxylic acid and is present in a weight ratio acid solvent to furan derivative from 1:1 to 250:1.
摘要翻译：式（I）的苯衍生物; 其中R 1和R 2相同或不同且独立地选自氢，烷基，芳烷基，-CHO，-CH 2 OR 3，-CH（OR 4）（OR 5）和-COOR 6，其中R 3，R 4和R 5是相同或不同，选自氢，烷基，芳基，烷芳基，芳烷基，烷基羰基或芳基羰基，或其中R4和R5一起形成亚烷基，其中R6选自氢，烷基和芳基，其包括：在酸溶剂的存在下，在环加成反应条件下使式（II）的呋喃衍生物（其中R 1和R 2具有上述含义）与乙烯反应，得到苯衍生物，其中酸溶剂为羧酸，以1：1至250：1的比例存在于酸溶剂与呋喃衍生物的重量比中。

3. 发明公开

EP2981528A1 PROCESS FOR THE PREPARATION OF 2,5-FURAN-DICARBOXYLIC ACID 有权
标题翻译： VERFAHREN ZUR HERSTELLUNG VON 2,5-FURAN-DICARBONSÄURE
公开(公告)号：EP2981528A1
公开(公告)日：2016-02-10
申请号：EP14717508.7
申请日：2014-04-04
申请人： Furanix Technologies B.V.
发明人： MAZOYER, Etienne , DE SOUSA DIAS, Ana Sofia Vagueiro , MCKAY, Benjamin , BAARS, Hendrikus Jacob , VREEKEN, Victor Peter Charles , GRUTER, Gerardus Johannes Maria , SIKKENGA, David Lee
IPC分类号： C07D307/68
CPC分类号： C07D307/68 , Y02P20/582
摘要： 2,5-Furandicarboxylic acid and methyl acetate are prepared in a continuous process, comprising -introducing a 5-methoxymethylfurfural-containing feedstock, an oxygen-containing gas, an oxidation catalyst and an acetic acid-containing solvent into a reactor; -allowing 5-methoxymethylfurfural to react with oxygen and acetic acid in the presence of the oxidation catalyst to yield 2,5-furandicarboxylic acid as main product and methyl acetate; -withdrawing 2,5-furandicarboxylic acid-containing product from the reactor and recovering 2,5-furandicarboxylic acid product; and -withdrawing a vaporous stream containing methyl acetate from the reactor.
摘要翻译：通过将5-甲氧基甲基糠醛的原料，含氧气体，氧化催化剂和含乙酸的溶剂引入反应器，在连续方法中制备2,5-呋喃二甲酸和乙酸甲酯; 在氧化催化剂存在下使5-甲氧基甲基糠醛与氧和乙酸反应，得到2,5-呋喃二羧酸为主要产物，并加入乙酸甲酯; 从反应器中取出2,5-呋喃二羧酸的产物并回收2,5-呋喃二羧酸产物; 并从反应器中取出含有乙酸甲酯的蒸气流。

4. 发明授权

EP2486027B1 METHOD FOR THE PREPARATION OF 2,5-FURANDICARBOXYLIC ACID AND ESTERS THEREOF 有权
标题翻译：用于生产2,5-呋喃二及其酯类
公开(公告)号：EP2486027B1
公开(公告)日：2014-06-04
申请号：EP10770891.9
申请日：2010-10-06
申请人： Furanix Technologies B.V
发明人： MUÑOZ DE DIEGO, Cesar , SCHAMMEL, Wayne Paul , DAM, Matheus Adrianus , GRUTER, Gerardus Johannes Maria
IPC分类号： C07D307/40 , C07D307/44 , C07D307/46
CPC分类号： C07D307/44 , C07D307/40 , C07D307/46

5. 发明公开

EP3011086A1 PROCESS FOR THE PREPARATION OF A FIBER, A FIBER AND A YARN MADE FROM SUCH A FIBER 有权转让
标题翻译：方法用于从这种纤维的纤维，纤维和纱线
公开(公告)号：EP3011086A1
公开(公告)日：2016-04-27
申请号：EP14737041.5
申请日：2014-06-20
申请人： Furanix Technologies B.V.
发明人： KOLSTAD, Jeffrey John , GRUTER, Gerardus Johannes Maria
IPC分类号： D01F6/00 , D01F6/62
CPC分类号： D01D5/088 , D01D5/08 , D01F6/62 , D01F6/84 , D01F6/94 , D06P3/52 , D10B2321/021 , D10B2331/04 , D10B2401/06
摘要： A fiber comprising polyethylene-2,5-furan-dicarboxylate, is prepared by melt spinning in a process wherein a molten composition comprising polyethylene-2,5-furan-dicarboxylate having an intrinsic viscosity of at least 0.55 dl/g, determined in dichloroacetic acid at 25° C., is passed through one or more spinning openings to yield molten threads; wherein the molten threads are cooled to below the melting temperature of the composition to yield spun fibers; and wherein the spun fibers are drawn to a linear density in the range of 0.05 to 2.0 tex per fiber. The invention also proves a fiber comprising polyethylene-2,5-furan-dicarboxylate having a linear density of 0.05 to 2.0 tex, wherein the polyethylene-2,5-furan-dicarboxylate has an intrinsic viscosity of at least 0.45 dl/g, determined in dichloroacetic acid at 25° C.
摘要翻译：包括聚乙烯 - 2,5-呋喃二羧酸酯的纤维，其是通过熔融纺丝的方法制备worin一个熔融的组合物，其包含具有在至少0点55分升/克的特性粘度，在确定性开采双氯聚2,5-呋喃二羧酸酯酸在25℃下，通过一个或更多个纺纱孔传递到产生熔融的线; worin熔融线程冷却至低于该组合物，得到纺丝纤维的熔化温度; 和worin纺成纤维被吸引到在每根纤维0:05到2.0特的范围内的线性密度。因此，本发明证明了一个纤维包括具有0:05的线密度到2.0特的聚乙烯 - 2,5-呋喃二羧酸酯，worin聚乙烯-2,5-呋喃二羧酸酯具有至少00:45分升/克的特性粘度，确定性开采在在25℃下二氯乙酸

6. 发明公开

EP2658849A1 PROCESS FOR THE CONVERSION OF A CARBOHYDRATE-CONTAINING FEEDSTOCK 有权
标题翻译：处理对碳水化合物转化含有原料
公开(公告)号：EP2658849A1
公开(公告)日：2013-11-06
申请号：EP11817491.1
申请日：2011-12-28
申请人： Furanix Technologies B.V
发明人： DE SOUSA DIAS, Ana Sofia Vagueiro , GRUTER, Gerardus Johannes Maria , VAN PUTTEN, Robert-Jan
IPC分类号： C07D307/46 , C07C59/185 , C07C69/716 , C07H15/04
CPC分类号： C07D307/58 , C07C67/00 , C07D307/46 , C07H15/04 , C07C69/716
摘要： A carbohydrate-containing feedstock is converted in a process by contacting the feedstock in a first step with an alcohol in the presence of a first acid catalyst at a temperature below 100° C. to yield an intermediate product, and contacting at least part of the intermediate product in a second step with an alcohol in the presence of a second acid catalyst at a temperature of at least 100° C. Products of such conversion may include hydroxymethylfurfural, hydroxymethylfurfural ethers, levulinic acid, esters thereof and furfural.

7. 发明公开

EP2300572A1 FUEL COMPOSITION 审中-公开
标题翻译：燃料组成
公开(公告)号：EP2300572A1
公开(公告)日：2011-03-30
申请号：EP09749656.6
申请日：2009-05-19
申请人： Furanix Technologies B.V
发明人： GRUTER, Gerardus Johannes Maria , DE JONG, Edserd
IPC分类号： C10L1/18 , C10L10/12 , C07D307/12
CPC分类号： C10L1/02 , C07D307/12 , C10L1/1855 , C10L10/12 , Y02T50/678
摘要： The invention provides a fuel component, based on or comprising a ring-hydrogenated alkyl furfuryl ether of the general formula (I): €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ (I)€ƒ€ƒ€ƒ€ƒ€ƒR"-TF-CH2-O-R wherein TF represents a 2,5-substituted tetrahydrofuran ring, wherein each R independently represents an alkyl group having from 1 to 20 carbon atoms and wherein each R" independently represents a hydrogen atom, a methyl group, a hydroxymethyl group, the product of an aldol condensation reaction or an alkoxymethyl group of the general formula (II): €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ (II)€ƒ€ƒ€ƒ€ƒ€ƒ-CH2-O-R' wherein each R' independently represents an alkyl group having from 1 to 20 carbon atoms. The invention also provides novel and useful ring-hydrogenated alkoxymethyltetrahydrofuran ethers such as 2-(alkoxymethyl)tetrahydrofuran, 5-methyl-2-(alkoxymethyl)tetrahydrofuran, 5-hydroxymethyl-2-(alkoxymethyl)tetrahydrofuran and 2,5-bis(alkoxymethyl)tetrahydrofuran of the general formula (I) above. Moreover, these ring-hydrogenated alkoxymethyltetrahydrofuran ethers disclosed herein have never been used as fuel component, and therefore the use of these ethers has also been claimed as an invention. A further embodiment of the current invention is the process for preparing these components. Finally, the use of a 5-(alkoxymethyl)furfural, 2-alkoxymethylfuran and/or a 2,5-bis(alkoxymethyl)furan as hydrogen storage molecules, in particular for fuel purposes is claimed as a further embodiment of the current invention.
摘要翻译：本发明提供了一种基于或包含通式（I）的环氢化烷基糠基醚的燃料组分：通式（I）的环氢化烷基糠基醚：（I）€¬€¬€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ 其中TF表示2,5-取代的四氢呋喃环，其中每个R独立地表示具有1至20个碳原子的烷基，并且其中每个R“独立地表示氢原子，甲基，羟甲基，醇醛缩合反应的产物或通式（II）的烷氧基甲基：（II） - CH2-OR'，其中每个R'独立地代表具有1至20个碳原子的烷基。本发明还提供了新的和有用的环氢化烷氧基甲基四氢呋喃醚，例如2-（烷氧基甲基）四氢呋喃，5-甲基-2-（烷氧基甲基）四氢呋喃，5-羟甲基-2-（烷氧基甲基）四氢呋喃和2,5-双）以上通式（I）的四氢呋喃。而且，这里公开的这些环氢化的烷氧基甲基四氢呋喃醚从未用作燃料组分，因此这些醚的用途也被认为是一项发明。本发明的另一个实施方案是制备这些组分的方法。最后，作为本发明的另一个实施方案，要求使用5-（烷氧基甲基）糠醛，2-烷氧基甲基呋喃和/或2,5-双（烷氧基甲基）呋喃作为储氢分子，特别是用于燃料目的。

8. 发明授权

EP3317262B1 PROCESS FOR THE PREPARATION OF A FURFURAL DERIVATIVE COMPRISING NEUTRALIZING AN ACID REACTION MIXTURE 有权转让
公开(公告)号：EP3317262B1
公开(公告)日：2020-04-22
申请号：EP16745529.4
申请日：2016-07-01
申请人： Furanix Technologies B.V.
发明人： SIJBEN, Johannes Maria Franciscus , MAZOYER, Etienne , DE SOUSA DIAS, Ana Sofia Vagueiro , GRUTER, Gerardus Johannes Maria
IPC分类号： C07D307/46 , C07D307/48

9. 发明授权

EP3004126B1 PROCESS FOR PRODUCING A FRUCTOSIDE-CONTAINING PRODUCT 有权
公开(公告)号：EP3004126B1
公开(公告)日：2020-04-15
申请号：EP14732447.9
申请日：2014-06-06
申请人： Furanix Technologies B.V.
发明人： MCKAY, Benjamin , DE SOUSA DIAS, Ana Sofia Vagueiro , IQBAL, Sarwat , GRUTER, Gerardus Johannes Maria , VAN PUTTEN, Robert-Jan
IPC分类号： C07H1/00 , C07H15/04 , C13K11/00

10. 发明授权

EP2981528B1 PROCESS FOR THE PREPARATION OF 2,5-FURAN-DICARBOXYLIC ACID 有权
标题翻译：制备2,5-呋喃 - 二羧酸的方法
公开(公告)号：EP2981528B1
公开(公告)日：2016-11-30
申请号：EP14717508.7
申请日：2014-04-04
申请人： Furanix Technologies B.V.
发明人： MAZOYER, Etienne , DE SOUSA DIAS, Ana Sofia Vagueiro , MCKAY, Benjamin , BAARS, Hendrikus Jacob , VREEKEN, Victor Peter Charles , GRUTER, Gerardus Johannes Maria , SIKKENGA, David Lee
IPC分类号： C07D307/68
CPC分类号： C07D307/68 , Y02P20/582

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