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1. 发明公开

EP2949679A1 THERMOMECHANICALLY REPROCESSABLE EPOXY COMPOSITES AND PROCESSES FOR THEIR MANUFACTURING 审中-公开
标题翻译： Thermomechanisch wiederverarbeitbare Epoxidverbundwerkstoffe und Verfahren zur Herstellung davon
公开(公告)号：EP2949679A1
公开(公告)日：2015-12-02
申请号：EP14382184.1
申请日：2014-05-26
申请人： Fundación Cidetec
发明人： Odriozola, Ibon , Ruiz De Luzuriaga, Alaitz , Rekondo, Alaitz , Martin, Roberto , Markaide, Nerea , Cabanero, German , Grande, Hans-Jürgen
IPC分类号： C08G59/40 , C08J5/24
CPC分类号： C08J5/24 , C08G59/4064 , C08J2363/00 , C08J2463/00 , C08K5/375 , C08L63/00
摘要： The composite comprises (i) a reinforcement phase comprising fibres, this phase being in a volume percentage comprised from 25 to 70% with respect to the total volume of the composite, and (ii) a matrix phase which is in a volume percentage comprised from 30 to 75% with respect to the total volume of the composite, being the sum of volumes of both phases forming the composite 100%, and wherein the matrix phase comprises a cured epoxy resin in a percentage comprised from 50-100% by weight with respect to the total weight of the matrix phase, and the cured epoxy resin being obtainable by: (a) mixing an epoxide-functionalised resin with a functionality equal to or higher than 2 with a cross-linking agent of formula (I), and (b) curing the reaction mixture at a temperature comprised from 10 to 200 °C, this step being performed in the absence of a catalyst.
The composite is reprocessable, reparable and recyclable and shows mechanochromic behaviour, being useful in the manufacture of an article.

Ar-S-S-Ar (I)
摘要翻译：复合材料包括（i）包含纤维的增强相，该相的体积百分比相对于复合材料的总体积为25至70％，和（ii）基体相的体积百分比为相对于复合材料的总体积为30至75％，其为形成复合材料的两相的体积的总和100％，并且其中基质相包含固化的环氧树脂，其含量为50-100重量％相对于基质相的总重量，固化的环氧树脂可以通过以下方法获得：（a）用式（I）的交联剂将具有等于或高于2的官能团的环氧官能化树脂混合，以及（b）在10至200℃的温度下固化反应混合物，该步骤在不存在催化剂的情况下进行。复合材料是可再加工的，可修复的和可回收的，并显示出机械色彩行为，用于制造制品。 €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒAr-S-S-Ar€ƒ€ƒ€ƒ€ƒ（I）

2. 发明公开

EP3015482A1 A process for preparing water-dispersable single-chain polymeric nanoparticles 审中-公开
标题翻译： Verfahren zur Herstellung wasserdispergierbarer einkettiger Polymernanopartikel
公开(公告)号：EP3015482A1
公开(公告)日：2016-05-04
申请号：EP14382433.2
申请日：2014-11-03
申请人： Fundación Cidetec
发明人： Aiertza Otxotorena, Miren Karmele , Sanchez Abella, Laura , Benito Collado, Ana Belén , Loinaz Bordonabe, Iraida , Cabanero, Germán , Grande, Hans-Jürgen
IPC分类号： C08F220/34 , A61K9/51
CPC分类号： C08F8/32 , A61K47/6933 , A61K47/6939 , A61K49/0093 , A61K49/1818 , C08F220/34 , C08G75/12
摘要： The present invention comprises a process for preparing water-dispersable single-chain polymeric nanoparticles, which comprises cross-linking a polymer having a solubility equal to or higher than 100 mg per litre of water, and an amount of complementary reactive groups comprised from 5 to 60 molar % of the total amount of monomer units present in the polymer chain; with a crosslinking agent having crosslinkable groups; at a temperature comprised from 20 to 25°C in the absence of a catalyst; to obtain water-dispersable conjugates and compositions containing the nanoparticle; and the use thereof.
摘要翻译：本发明包括一种制备水分散性单链聚合物纳米颗粒的方法，其包括将溶解度等于或高于100mg /升水的聚合物交联，以及一定量的互补反应性基团，其包含5至存在于聚合物链中的单体单元总量的60摩尔％具有可交联基团的交联剂; 在不存在催化剂的情况下在20至25℃的温度下进行; 以获得含有纳米颗粒的水分散性缀合物和组合物; 及其用途。

3. 发明公开

EP2597110A1 Self-healing material and method for the preparation thereof 审中-公开
标题翻译： Selbstheilendes材料和Verfahren zu seiner Herstellung
公开(公告)号：EP2597110A1
公开(公告)日：2013-05-29
申请号：EP11382365.2
申请日：2011-11-28
申请人： Fundación Cidetec
发明人： Odriozola, Ibon , Casuso, Pablo , Díaz, Natividad , Loinaz, Iraida , Cabañero, Germán , Grande, Hans-Jürgen
IPC分类号： C08G65/334 , C08L71/02 , A61L27/52
CPC分类号： C08K3/08 , C07C323/12 , C07K14/78 , C08B37/0072 , C08F222/38 , C08G18/3863 , C08G18/7657 , C08G65/326 , C08G65/334 , C08G77/28 , C08K2003/0806 , C08K2003/0831 , C08K2003/085 , C08L71/02 , C08L2203/02 , C09D133/26 , C09D175/08 , C09D183/08
摘要： It is provided a self-healing polymer network comprising transition metal thiolates, particularly thiolates of a transition metal that is able to self-assemble by metallophilic attractions, and more particularly Au(I), Ag(I), Cu(I) thiolates, or a mixture thereof, and, optionally, disulfide bonds, thiol and other thiolate groups. It is also provided several processes for the preparation of the self-healing polymer networks of the invention, as well as uses thereof.
摘要翻译：提供了一种自愈性聚合物网络，其包含过渡金属硫醇盐，特别是能够通过金属亲电势点自组装的过渡金属的硫醇盐，更具体地为Au（I），Ag（I），Cu（I）硫醇盐，或其混合物，以及任选的二硫键，硫醇和其它硫醇盐基团。还提供了用于制备本发明的自愈合聚合物网络的几种方法及其用途。

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