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    • 6. 发明公开
    • A PROCESS FOR REFINING GLYCERIDE OIL COMPRISING A BASIC QUATERNARY AMMONIUM SALT TREATMENT
    • VERFAHREN ZUM RAFFINIENEN VONGLYCERIDÖLMIT EINER BEHANDLUNG MIT BASISCHEMQUATERNÄREMAMMONIUMSALZ
    • EP3098292A1
    • 2016-11-30
    • EP15169311.6
    • 2015-05-27
    • Evonik Degussa GmbH
    • FEDOR, GabrielaATKINS, Martin PhilipGOODRICH, PeterKLATT HAMER, ChristopherWITTHAUT, DanielBOES, Ulrich
    • C11B3/00C11B3/04C11B3/10C11B3/12
    • C11B3/06C11B3/001C11B3/04C11B3/10C11B3/12C11B3/14
    • The present invention relates to a process for refining glyceride oil comprising the steps of:
      (i) contacting glyceride oil with a liquid comprising a basic quaternary ammonium salt to form a treated glyceride oil; wherein the quaternary ammonium salt comprises a basic anion selected from hydroxide, alkoxide, alkylcarbonate, hydrogen carbonate, carbonate, serinate, prolinate, histidinate, threoninate, valinate, asparaginate, taurinate and lysinate; and a quaternary ammonium cation;
      (ii) separating the treated glyceride oil from a salt comprising the quaternary ammonium cation; and
      (iii) subjecting the treated glyceride oil after the separation step to at least one further refining step;
      and to the use of contacting a glyceride oil with the basic quaternary ammonium salt for preventing or reducing the formation of fatty acid esters of chloropropanols and/or glycidol upon heating of the glyceride oil.
    • 本发明涉及一种精制甘油酯油的方法,包括以下步骤:(i)使甘油酯油与包含碱性季铵盐的液体接触以形成经处理的甘油酯油; 其中季铵盐包括选自氢氧化物,醇盐,烷基碳酸盐,碳酸氢盐,碳酸盐,丝氨酸盐,脯氨酸盐,组氨酸盐,苏氨酸盐,缬氨酸盐,天冬酰胺酸盐,牛磺酸盐和赖氨酸盐的碱性阴离子; 和季铵阳离子; (ii)从包含季铵阳离子的盐分离经处理的甘油酯油; 和(iii)在分离步骤之后对经处理的甘油酯油进行至少一个进一步的精制步骤; 并且使用甘油酯油与碱性季铵盐接触,以防止或减少加热甘油酯油时氯丙醇和/或缩水甘油的脂肪酸酯的形成。