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1. 发明授权

EP0446989B1 Supported catalyst for ethylene polymerization and the copolymerization of ethylene with alpha-olefins, its preparation and use 失效
标题翻译：用于乙烯聚合反应或共聚合的α-烯烃，其制备及其使用负载的催化剂
公开(公告)号：EP0446989B1
公开(公告)日：1996-05-22
申请号：EP91200481.9
申请日：1991-03-06
申请人： ENICHEM S.p.A.
发明人： Luciani, Luciano , Invernizzi, Renzo , Masi, Francesco , Pondrelli, Maddalena , Polesello, Mario , Borghi, Italo
IPC分类号： C08F4/655 , C08F10/02
CPC分类号： C08F10/00 , Y10S526/909 , C08F4/6567 , C08F4/6557 , C08F4/6555

2. 发明授权

EP0421525B1 Process for the preparation of ethylene-propylene copolymers 失效
标题翻译：一种用于乙烯 - 丙烯共聚物的制备方法。
公开(公告)号：EP0421525B1
公开(公告)日：1995-08-30
申请号：EP90202580.8
申请日：1990-09-28
申请人： ENICHEM S.p.A.
发明人： Mirra, Mauro , Masi, Francesco , Invernizzi, Renzo , Langianni, Elio , Masini, Sergio
IPC分类号： C08F210/16 , C08F4/654
CPC分类号： C08F210/16 , C08F4/6543

3. 发明公开

EP0480435A3 Solid component of a catalyst for the (co)polymerization of ethylene 失效
标题翻译：乙烯（CO）聚合催化剂的固体成分
公开(公告)号：EP0480435A3
公开(公告)日：1992-07-15
申请号：EP91117316.9
申请日：1991-10-10
申请人： ENICHEM S.p.A.
发明人： Luciani, Luciano , Pondrelli, Maddalena , Invernizzi, Renzo , Borghi, Italo
IPC分类号： C08F10/02 , C08F4/655 , C08F4/656
CPC分类号： C08F10/00 , C08F4/6567 , C08F4/6555
摘要： A solid component of a catalyst for the (co)polymerization of ethylene which comprises a silica carrier and a catalytically active portion including titanium, magnesium, chlorine and alkoxy groups is obtained by suspending activated silica in a solution of magnesium chloride and titanium tetraalcoholate in a liquid aliphatic acid ester; eliminating the aliphatic acid ester from the resulting suspension to recover a solid; and reacting the resulting solid with an alkyl aluminium chloride.

4. 发明公开

EP0449355A3 Supported catalyst for the polymerization and copolymerization of olefinically unsarurated compounds, and a (co)polymerization process which uses it 失效
标题翻译：用于烯属不完全化合物的聚合和共聚的支持催化剂和使用它的（CO）聚合方法
公开(公告)号：EP0449355A3
公开(公告)日：1991-12-27
申请号：EP91200594.9
申请日：1991-03-19
申请人： ENICHEM S.p.A.
发明人： Masi, Francesco , Invernizzi, Renzo , Carbonaro, Antonio , Costa, Lorenzo , Moalli, Angelo
IPC分类号： C08F10/00 , C08F4/617 , C08F4/02
CPC分类号： C08F10/00 , C08F4/025 , C08F4/6145
摘要： A supported catalyst for the polymerization and copolymerization of olefinically unsaturated compounds is described, comprising an organometallic compound of aluminium and a second component obtained by bringing a magnesium compound and/or a titanium, vanadium or chromium compound and possibly at least one compound of a second metal chosen from V, Al, Zr, Hf, Mo and Nd, into contact with a porous support consisting of microbeads of aerogels of one or more inorganic oxides distinguished by low density, high porosity and the fact that at least 90% of the pores have a diameter lying within a very narrow range of values. The process for the polymerization or copolymerization of olefinically unsaturated compounds based on the use of said catalyst is also described.

5. 发明公开

EP0421525A2 Process for the preparation of ethylene-propylene copolymers 失效
标题翻译： Verfahren zur Herstellung von Ethylen-Propylenolyolymere。
公开(公告)号：EP0421525A2
公开(公告)日：1991-04-10
申请号：EP90202580.8
申请日：1990-09-28
申请人： ENICHEM S.p.A.
发明人： Mirra, Mauro , Masi, Francesco , Invernizzi, Renzo , Langianni, Elio , Masini, Sergio
IPC分类号： C08F210/16 , C08F4/654
CPC分类号： C08F210/16 , C08F4/6543
摘要： A process is described for the preparation of ethylene-propylene copolymers having density values from 0.880 to 0.915 g/ml, for the copolymerization of ethylene and propylene, at a high pressure and at a high temperature, in a reactor vessel or tubular reactor, in the presence of a catalyst consisting of an aluminium trialkyl and a solid catalyst component containing 0.4 to 4.0 wt% titanium on a microspherical magnesium chloride support, in which the titanium is present partially in the trivalent and partially in the tetravalent form.
The copolymers thus obtained are used for the production of film or for mixing with other polymers or with bitumen, in the production of bituminous casings for waterproofing, in the expanded foam sector and as a blending material for modifying the rheological characteristics of LLDPE.
摘要翻译：描述了一种制备在反应器容器或管式反应器中在高压和高温下共聚乙烯和丙烯的密度值为0.880至0.915g / ml的乙烯 - 丙烯共聚物的方法，由三价烷基铝和含有0.4至4.0重量％钛的固体催化剂组分的催化剂在微球状氯化镁载体上的存在，其中钛部分以三价或部分为四价形式存在。由此获得的共聚物用于生产膜或与其他聚合物或沥青混合，在生产用于防水的沥青套管中，在膨胀的泡沫塑料领域中以及用于改变LLDPE的流变特性的共混材料。

6. 发明授权

EP0536840B1 Catalysts for the polymerization of olefins 失效
标题翻译：的烯烃聚合催化剂
公开(公告)号：EP0536840B1
公开(公告)日：1995-12-20
申请号：EP92203029.1
申请日：1992-10-02
申请人： ENICHEM S.p.A.
发明人： Luciani, Luciano , Polesello, Mario , Milani, Federico , Invernizzi, Renzo , Soverini, Giovanni
IPC分类号： C08F10/00 , C08F4/635
CPC分类号： C08F10/00 , C08F4/6355

7. 发明公开

EP0618239A3 Ethylene (co)polymerization process 失效
标题翻译：一种用于乙烯聚合工艺。
公开(公告)号：EP0618239A3
公开(公告)日：1995-09-20
申请号：EP94200783.2
申请日：1994-03-25
申请人： ENICHEM S.p.A.
发明人： Masi, Francesco , Calderazzo, Fausto , Menconi, Francesco , Pampaloni, Guido , Poidomani, Marcello , Ferrero, Cesare , Moalli, Angelo , Invernizzi, Renzo , Monichino, Alberto
IPC分类号： C08F10/02 , C08F4/685
CPC分类号： C08F10/00 , C08F4/685
摘要： Ethylene is homopolymerized, or copolymerized with an alpha-olefin, in the presence of a catalytic composition formed from:
i) a solid catalyst component (procatalyst), containing titanium, vanadium and chlorine in the following molar proportions:
Ti (1), V (0.3-3), Cl (4-12); ii) a trialkylaluminium or an alkylaluminium chloride cocatalyst; and iii) an activator chosen from particular classes of organic chlorine derivatives.

8. 发明授权

EP0361598B1 Process for polymerizing ethylene and copolymerizing ethylene with alpha-olefins and relevant catalyst 失效
标题翻译：一种用于乙烯或α-烯烃的乙烯共聚的聚合及由此verwendenbarer催化剂的方法。
公开(公告)号：EP0361598B1
公开(公告)日：1994-01-26
申请号：EP89202371.4
申请日：1989-09-20
申请人： ENICHEM S.p.A.
发明人： Ciardelli, Francesco , Masi, Francesco , Malquori, Stefano , Ferrero, Cesare , Barazzoni, Lia , Menconi, Francesco , Moalli, Angelo , Invernizzi, Renzo
IPC分类号： C08F10/02 , C08F4/656
CPC分类号： C08F10/02 , C08F4/6367

9. 发明公开

EP0525857A1 Procedure for the producing of vanadium bis-arenes from vanadium oxychloride 失效
标题翻译： Verfahren zur Herstellung von钒 - bisarenen aus钒氧氯化物。
公开(公告)号：EP0525857A1
公开(公告)日：1993-02-03
申请号：EP92202086.2
申请日：1992-07-08
申请人： ENICHEM S.p.A.
发明人： Calderazzo, Fausto , Pampaloni, Guido , Masi, Francesco , Moalli, Angelo , Cassani, Maria Christina , Invernizzi, Renzo
IPC分类号： C07F9/00
CPC分类号： C07F9/00
摘要： A procedure is described for the preparation of vanadium bis-arene, [V(arene) 2] , starting from vanadium oxychloride, aluminium metal, aluminium trichloride and an arene, wherein:

- (a) vanadium oxychloride (VOCl 3 ), active aluminium metal, and aluminium trichloride are put in contact with each other, in a liquid arene, to transform the vanadium oxychloride into the complex compound [V(arene)2] [AlCl 4 ] - ;
- (b) a liquid cyclic or acyclic ether is added to the reaction product of step (a) to reduce [V-(arene) 2 ] + to [V(arene) 2 ]; and
- (c) the vanadium bis-arene [V(arene) 2] is recovered from the reaction product of step (b). The vanadium bis-arenes thus obtained are used in the preparation of catalysts for the polymerisation of olefins.
摘要翻译：描述了从氯氧化钒，铝金属，三氯化铝和芳烃开始制备钒双芳烃[V（芳烃）2]的方法，其中：（a）氯氧化钒（VOCl 3），活性铝金属，和三氯化铝在液体芳烃中相互接触，将氯氧化钒转化成络合物[V（芳烃）2] + [AlCl 4] - ; （b）向步骤（a）的反应产物中加入液态环状或非环状醚以将[V（芳烃）2] +还原为[V（芳烃）2]; 和（c）从步骤（b）的反应产物中回收钒双芳烃[V（芳烃）2]。由此获得的钒双芳烃用于制备用于烯烃聚合的催化剂。

10. 发明公开

EP0480435A2 Solid component of a catalyst for the (co)polymerization of ethylene 失效
标题翻译： Feste Komponente eines Katalysatorsfür（Ko）-Polymerisation vonÄthylen。
公开(公告)号：EP0480435A2
公开(公告)日：1992-04-15
申请号：EP91117316.9
申请日：1991-10-10
申请人： ENICHEM S.p.A.
发明人： Luciani, Luciano , Pondrelli, Maddalena , Invernizzi, Renzo , Borghi, Italo
IPC分类号： C08F10/02 , C08F4/655 , C08F4/656
CPC分类号： C08F10/00 , C08F4/6567 , C08F4/6555
摘要： A solid component of a catalyst for the (co)polymerization of ethylene which comprises a silica carrier and a catalytically active portion including titanium, magnesium, chlorine and alkoxy groups is obtained by suspending activated silica in a solution of magnesium chloride and titanium tetraalcoholate in a liquid aliphatic acid ester; eliminating the aliphatic acid ester from the resulting suspension to recover a solid; and reacting the resulting solid with an alkyl aluminium chloride.
摘要翻译：通过将活性二氧化硅悬浮在氯化镁和四氢化钛中的溶液中，得到包含二氧化硅载体和包含钛，镁，氯和烷氧基的催化活性部分的乙烯（共）聚合催化剂的固体组分液体脂肪酸酯; 从所得悬浮液中除去脂族酸酯以回收固体; 并使所得固体与烷基氯化铝反应。

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