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1. 发明公开

EP1318428A2 Photographic element, compound and process 审中-公开
标题翻译：照相元件，化合物和工艺
公开(公告)号：EP1318428A2
公开(公告)日：2003-06-11
申请号：EP02079888.0
申请日：2002-11-25
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William James , Russo, Gary M.
IPC分类号： G03C7/34
CPC分类号： G03C7/346
摘要： Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a cyan "NB coupler" having the formula (I):
wherein :

the term "NB coupler" represents a coupler of formula (I) that forms a dye for which the left bandwidth (LBW) using spin-coating is at least 5nm less than that of the same dye in solution form;

X is selected from O, NR* or S and R* is an alkyl, carbocyclic or heterocyclic group;
L is a linking group and a is 0 or 1;
Y is H or a coupling-off group;
Z* is a substituent group and p is 0 to 2; and
R' and R 2 are independently selected H or substituents;

provided that the combined sum of the aliphatic carbon atoms in R 1 , R 2 , R*, L and all Z* is at least 8.
摘要翻译：公开了包含感光卤化银乳剂层的照相元件，所述感光卤化银乳剂层具有与其结合的具有式（I）的青色“NB成色剂”：其中：术语“NB成色剂”表示形成染料的式为此，使用旋涂的左带宽（LBW）比溶液形式的相同染料小至少5nm; X选自O，NR *或S且R *是烷基，碳环或杂环基团; L是连接基团，a是0或1; Y是H或偶合脱离基团; Z *是取代基，p是0-2; 并且R'和R2独立地选自H或取代基; 条件是R1，R2，R *，L和全部Z *中脂族碳原子的总和至少为8。

2. 发明公开

EP1113332A1 Photographic element, compound, and process 有权
标题翻译：照相元件，化合物和工艺
公开(公告)号：EP1113332A1
公开(公告)日：2001-07-04
申请号：EP00204570.6
申请日：2000-12-18
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William J. , Coms, Franks D. , Russo, Gary M.
IPC分类号： G03C7/34 , C07D209/42 , C07D213/82 , C07D231/14 , C07D231/16 , C07D231/56 , C07D233/90 , C07D235/24 , C07D249/06 , C07D263/58 , C07D307/68 , C07D401/14 , C07D403/12 , C07D471/04
CPC分类号： C07D213/82 , C07D209/42 , C07D231/14 , C07D231/56 , C07D233/90 , C07D235/24 , C07D249/06 , C07D263/58 , C07D307/68 , C07D401/12 , C07D403/12 , C07D471/04 , G03C7/3212 , G03C7/346
摘要： Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a cyan coupler having the formula:
wherein:

V is a sulfone or sulfoxide containing group;
Y is H or a coupling-off group;
W 2 represents the atoms necessary to complete a carbocyclic or heterocyclic ring group;
each Z", Z* and Z # is an independently selected substituent group where n and r are independently 0 to 4 and p is 0 to 2; and
X is a halogen atom, and s is 1 to 5;
provided that the combined sum of the aliphatic carbon atoms in V, all Z", all Z # , and all Z* is at least 8. The element exhibits improved cyan dye stability.
摘要翻译：本发明公开了一种照相元件，其包含感光卤化银乳剂层，所述感光卤化银乳剂层具有与其结合的具有下式的青色成色剂：其中：V是含砜或亚砜的基团; Y是H或偶合脱离基团; W2表示完成碳环或杂环基团所需的原子; 每个Z“，Z *和Z＃是独立选择的取代基，其中n和r独立地为0-4且p为0-2; X为卤原子，s为1-5; 的V中的脂族碳原子，全部Z“，全部Z＃和全部Z *至少为8.该元件表现出改进的青色染料稳定性。

3. 发明授权

EP1113327B1 Photographic element, compound, and process 有权
标题翻译：一种照相元件，化合物和方法
公开(公告)号：EP1113327B1
公开(公告)日：2005-05-11
申请号：EP00204548.2
申请日：2000-12-15
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William J. , Russo, Gary M. , Curt, Denis T.
IPC分类号： G03C7/34 , C07C317/44 , C07D213/70 , C07D217/24 , C07D231/16 , C07D401/12
CPC分类号： G03C7/346 , C07C317/44 , C07C2603/74 , C07D263/56 , G03C7/30523

4. 发明公开

EP1318428A3 Photographic element, compound and process 审中-公开
标题翻译：照相元件，化合物和工艺
公开(公告)号：EP1318428A3
公开(公告)日：2003-09-17
申请号：EP02079888.0
申请日：2002-11-25
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William James , Russo, Gary M.
IPC分类号： G03C7/34
CPC分类号： G03C7/346
摘要： Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a cyan "NB coupler" having the formula (I): wherein : the term "NB coupler" represents a coupler of formula (I) that forms a dye for which the left bandwidth (LBW) using spin-coating is at least 5nm less than that of the same dye in solution form;X is selected from O, NR* or S and R* is an alkyl, carbocyclic or heterocyclic group;L is a linking group and a is 0 or 1;Y is H or a coupling-off group;Z* is a substituent group and p is 0 to 2; andR' and R2 are independently selected H or substituents; provided that the combined sum of the aliphatic carbon atoms in R1, R2, R*, L and all Z* is at least 8.
摘要翻译：公开了包含感光卤化银乳剂层的照相元件，所述感光卤化银乳剂层具有与其结合的具有式（I）的青色“NB成色剂”：其中：术语“NB成色剂”表示形成染料的式其中使用旋涂的左带宽（LBW）比溶液形式的相同染料的至少小5nm; X选自O，NR *或S，并且R *是烷基，碳环或杂环基团; L 是连接基团，a是0或1; Y是H或偶合脱离基团; Z *是取代基并且p是0-2; 和R'和R2独立地选自H或取代基; 条件是R1，R2，R *，L和全部Z *中脂族碳原子的总和至少为8。

5. 发明公开

EP1113333A1 Photographic element, compound, and process 审中-公开
标题翻译：照相元件，化合物和工艺
公开(公告)号：EP1113333A1
公开(公告)日：2001-07-04
申请号：EP00204772.8
申请日：2000-12-27
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William J. , Russo, Gary M. , Curt, Dennis T.
IPC分类号： G03C7/34 , C07C311/29 , C07D213/70 , C07D231/14 , C07D401/12
CPC分类号： G03C7/346
摘要： Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a "NB coupler" having the formula (I):
wherein :

the term "NB coupler" represents a coupler of formula (I) that forms a dye for which the left bandwidth (LBW) using spin-coating is at least 5nm less than that of the same dye in solution form;
Y is H or a coupling-off group;
each Z* is an independently selected substituent group where p is 0 to 2;
V is a substituent group containing a sulfonamido group;
R 4 is hydrogen or a group bonded to the carbonamido group by an aliphatic carbon atom;
provided that the combined sum of the aliphatic carbon atoms in V, R 4 and all Z* is at least 8. The element provides a dye of improved hue.
摘要翻译：公开了包含感光卤化银乳剂层的照相元件，所述感光卤化银乳剂层具有与其结合的具有式（I）的“NB成色剂”：其中：术语“NB成色剂”表示形成染料的式（I）其中使用旋涂的左带宽（LBW）比溶液形式的相同染料的至少小5nm; Y是H或偶合脱离基团; 每个Z *是独立选择的取代基，其中p是0-2; V是含磺酰氨基的取代基; R4是氢或通过脂族碳原子与碳酰氨基键合的基团; 条件是V，R4和所有Z *中的脂族碳原子的总和至少为8.该元素提供改善色调的染料。

6. 发明公开

EP1113327A1 Photographic element, compound, and process 有权
标题翻译：照相元件，化合物和工艺
公开(公告)号：EP1113327A1
公开(公告)日：2001-07-04
申请号：EP00204548.2
申请日：2000-12-15
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William J. , Russo, Gary M. , Curt, Denis T.
IPC分类号： G03C7/34 , C07C317/44 , C07D213/70 , C07D217/24 , C07D231/16 , C07D401/12
CPC分类号： G03C7/346 , C07C317/44 , C07C2603/74 , C07D263/56 , G03C7/30523
摘要： Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a "NB coupler" having the formula (I):
wherein :

the term "NB coupler" represents a coupler of formula (I) that forms a dye for which the left bandwidth (LBW) using spin-coating is at least 5nm less than that of the same dye in solution form;
Y is H or a coupling-off group;
each Z* is an independently selected substituent group where p is 0 to 2;
V is a substituent group containing a sulfone group;
R 4 is represented by the formula

wherein each of R 5 , R 6 and R 7 is hydrogen or an independently selected substituent with no more than one being hydrogen;
provided that two or more of R 5 , R 6 and R 7 may join to form a ring or rings and provided that the combined sum of the aliphatic carbon atoms in V, R 4 and all Z* is at least 8, and provided further that R 4 is not a fully fluorinated alkyl group. Such elements provide improved hue.
摘要翻译：公开了包含感光卤化银乳剂层的照相元件，所述感光卤化银乳剂层具有与其结合的具有式（I）的“NB成色剂”：其中：术语“NB成色剂”表示形成染料的式（I）其中使用旋涂的左带宽（LBW）比溶液形式的相同染料的至少小5nm; Y是H或偶合脱离基团; 每个Z *是独立选择的取代基，其中p是0-2; V是含有砜基的取代基; R4由下式表示：其中R5，R6和R7各自为氢或独立选择的取代基，其中不超过一个为氢; 条件是R5，R6和R7中的两个或多个可以连接形成一个或多个环，并且条件是V，R4和所有Z *中的脂族碳原子的总和至少为8，并且进一步提供R4不是完全氟化的烷基。这些元素提供改善的色调。

7. 发明授权

EP1113332B1 Photographic element, compound, and process 有权
标题翻译：一种照相元件，化合物和方法
公开(公告)号：EP1113332B1
公开(公告)日：2004-10-06
申请号：EP00204570.6
申请日：2000-12-18
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William J. , Coms, Franks D. , Russo, Gary M.
IPC分类号： G03C7/34 , C07D209/42 , C07D213/82 , C07D231/14 , C07D231/16 , C07D231/56 , C07D233/90 , C07D235/24 , C07D249/06 , C07D263/58 , C07D307/68 , C07D401/14 , C07D403/12 , C07D471/04
CPC分类号： C07D213/82 , C07D209/42 , C07D231/14 , C07D231/56 , C07D233/90 , C07D235/24 , C07D249/06 , C07D263/58 , C07D307/68 , C07D401/12 , C07D403/12 , C07D471/04 , G03C7/3212 , G03C7/346

8. 发明公开

EP1113331A1 Photographic element, compound, and process 审中-公开
标题翻译：一种照相元件，化合物和方法
公开(公告)号：EP1113331A1
公开(公告)日：2001-07-04
申请号：EP00204569.8
申请日：2000-12-18
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William J. , Russo, Gary M. , Curt, Denis T.
IPC分类号： G03C7/34 , C07C311/19 , C07C311/29 , C07C317/44 , C07D209/42 , C07D213/81 , C07D213/82 , C07D231/14 , C07D233/90
CPC分类号： G03C7/346
摘要： Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a "NB coupler" having the formula (I):
wherein :

the term "NB coupler" represents a coupler of formula (I) that forms a dye for which the left bandwidth (LBW) using spin-coating is at least 5nm less than that of the same dye in solution form;
Y is H or a coupling-off group;
each Z" and Z* is an independently selected substituent group where n is 0 to 5 and p is 0 to 2;
W 2 represents the atoms necessary to complete a carbocyclic or heterocyclic ring group; and
V is a substituent group containing a sulfonamido group;
provided that the combined sum of the aliphatic carbon atoms in V, all Z" and all Z* is at least 8. The element provides a dye of improved hue.

9. 发明公开

EP1113329A1 Photographic element, compound, and process 审中-公开
标题翻译：照相元件，化合物和工艺
公开(公告)号：EP1113329A1
公开(公告)日：2001-07-04
申请号：EP00204566.4
申请日：2000-12-18
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William J. , Coms, Frank D. , Russo, Gary M.
IPC分类号： G03C7/34 , C07C317/44 , C07D213/70 , C07D215/36 , C07D209/30 , C07D231/14 , C07D235/24 , C07D401/12
CPC分类号： G03C7/346
摘要： Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a cyan "NB coupler" having the formula (I):
wherein :

the term "NB coupler" represents a coupler of formula (I) that forms a dye for which the left bandwidth (LBW) using spin-coating is at least 5nm less than that of the same dye in solution form;
Y is H or a coupling-off group;
each Z" and Z* is an independently selected substituent group where n is 1 to 4 and p is 0 to 2;
W 2 represents the atoms necessary to complete a carbocyclic or heterocyclic ring group; and
V is a sulfone or sulfoxide containing group;
provided that the combined sum of the aliphatic carbon atoms in V, all Z" and all Z* is at least 8;
provided further that there is one and only one Z" substituent ortho to the carbonamido group linking the W 2 ring to the rest of the coupler; and
provided still further that when W 2 forms a carbocyclic aromatic ring, at least one Z" is selected from the group consisting of alkyl, alkoxy, hydroxy, aryl, aryloxy, oxycarbonyl, oxysulfonyl, sulfoxide, sulfamoyl, thio, carbamoyl, carboxy, carbonamido, ureido, cyano, nitro, and halogen groups. The element exhibits improved cyan dye hue.
摘要翻译：公开了包含感光卤化银乳剂层的照相元件，所述感光卤化银乳剂层具有与其结合的具有式（I）的青色“NB成色剂”：其中：术语“NB成色剂”表示形成染料的式为此，使用旋涂的左带宽（LBW）比溶液形式的相同染料小至少5nm; Y是H或偶合脱离基团; 每个Z“和Z *是独立选择的取代基，其中n是1至4并且p是0至2; W2表示完成碳环或杂环基团所需的原子;并且V是含砜或亚砜的基团;提供 V，所有Z“和全部Z *中的脂肪族碳原子的总和至少为8; 进一步提供了在连接W 2环和成色剂其余部分的碳酰氨基的位置上有一个且仅有一个Z“取代基;并且还提供了当W 2形成碳环芳香环时，至少一个Z”选自由烷基，烷氧基，羟基，芳基，芳氧基，氧羰基，氧磺酰基，亚砜，氨磺酰基，硫代，氨基甲酰基，羧基，碳酰氨基，脲基，氰基，硝基和卤素组成的基团。该元件表现出改进的青色染料色调。

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