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    • 4. 发明公开
    • Chemically sensitized aqueous-based photothermographic emulsions and materials and methods of using same
    • 含水化学敏化的光热敏成像乳剂和这些材料和方法中所使用
    • EP1283441A1
    • 2003-02-12
    • EP02078033.4
    • 2002-07-25
    • EASTMAN KODAK COMPANY
    • Gysling, Henry JamesDickinson, David AlanLelental, MarkBoettcher, John William
    • G03C1/498G03C1/09
    • G03C1/49845G03C1/08G03C1/09G03C1/498G03C2001/098Y10S430/145Y10S430/165
    • Photothermographic materials prepared using aqueous formulations include silver halides that are chemically sensitized using certain tellurium-containing compounds. Such tellurium-containing chemical sensitizing compounds arc generally provided in aqueous solution or in an aqueous solid particulate dispersion and can be represented by the following Structure I, II, or III:


      wherein X represents the same or different COR, CSR, CNRR a , CR, PRR a , or P(OR) 2 groups, R and R a are independently alkyl, alkenyl, or aryl groups, L is a ligand derived from a neutral Lewis base, X 1 and X 2 independently represent a halo, OCN, SCN, S 2 CNRR a, S 2 COR, S 2 CSR S 2 P(OR) 2 , S 2 PRR a, SeCN, TeCN, CN, SR, OR, alkyl, aryl, N 3 , or O 2 CR group, R' is an alkyl or aryl group, p is 2 or 4, m is 0, 1, 2, or 4, and n is 2 or 4 provided that when m is 0 or 2, n is 2 or 4, and when m is 1 or 4, n is 2.
    • 光热敏成像材料使用wässrige式蒸发散包括银卤化物没有使用某些含碲化合物是化学增感来制备。 含碲搜索化学敏化化合物在wässrige固体颗粒分散在wässrige溶液中或在提供电弧基因反弹和可以由以下结构表示I,II,或III: worin X darstellt相同或 不同COR,CSR,CNRRa,CR,PRRA,或P(OR)2个基团,R和R a独立地是烷基,烯基或芳基,L是从中性路易斯碱衍生的配位体,X <1>和X < 2>独立地表示卤素,OCN,SCN,S2CNRRa,S2COR,S2CSR S2P(OR)2,S2PRRa,SECN,TECN,CN,SR,OR,烷基,芳基,N 3,或O 2 CR基团,R“是烷基或 芳基,p是2或4,m为0,1,2,或4,且n是提供2或4那样当m是0或2,n是2或4,当m是1或4,N 是所述第二
    • 7. 发明公开
    • Cobalt (III) complex-containing image-forming compositions
    • Cobalt-III-Komplexe enthaltende,bilderzeugende Zusammensetzungen。
    • EP0044729A1
    • 1982-01-27
    • EP81303297.6
    • 1981-07-17
    • EASTMAN KODAK COMPANY (a New Jersey corporation)
    • Adin, AnthonyBoettcher, John WilliamFleming, James Charles
    • G03C1/72
    • B41M5/32Y10S430/137
    • A thermally-activatable image-forming composition contains a cobalt (III) complex having releasable ligands, an amplifier compound which reacts with cobalt (II) or released ligands to form an agent for the conversion of the complex to cobalt (II) and released ligands, a material which generates an image by dye formation or dye destruction in response to imagewise conversion of the complex, and a destabilizer which facilitates conversion of the complex, and hence the image-forming reaction, by heating, is characterized by containing as the destabilizer two destabilizer compounds which are present at concentrations such that the temperature required for initiating the image-forming reaction is lower than the initiation temperature obtainable using either destabilizer compound alone. Images can be produced in coatings of the composition by imagewise thermal exposure or by incorporating a photoinhibitor in the composition and exposing the coating imagewise prior to heating overall.
    • 可热激活的成像组合物包含具有可释放配体的钴(III)络合物,与钴(II)或释放配体反应以形成用于将络合物转化为钴(II)和释放配体的试剂的放大化合物 响应于复合物的成像转化而通过染料形成或染料破坏产生图像的材料,以及促进络合物转化并因此加热形成图像形成反应的去稳定剂的特征在于含有作为去稳定剂 两种去稳定剂化合物的存在浓度使得起始成像反应所需的温度低于使用去稳定化合物单独获得的起始温度。 可以通过成像热曝光或通过在组合物中并入光抑制剂并在整体加热之前使成像曝光来使图像在涂层中产生图像。