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1. 发明公开

EP0522371A1 Photographic material and process comprising dir coupler 失效
标题翻译：材料sowie Verfahren mit Dirkuppler。
公开(公告)号：EP0522371A1
公开(公告)日：1993-01-13
申请号：EP92110833.8
申请日：1992-06-26
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William James, c/o EASTMAN KODAK COMPANY , Ling, Hans Gway, c/o EASTMAN KODAK COMPANY
IPC分类号： G03C7/305
CPC分类号： G03C7/30517 , G03C7/30552 , G03C7/30576 , Y10S430/158
摘要： A photographic DIR (development inhibitor-releasing) acetanilide coupler containing a carboxy group on the anilide moiety or a DIR naphtholic coupler containing on the 2-position a -CONH₂ or -CONHCH₃ group, capable upon oxidative coupling of forming a dye capable of being washed out of a photographic element upon processing, contains, in the coupling position, a coupling-off group comprising, in sequence, at least one ballasted linking group and at least one releasable development-inhibitor group (INH) which is a mercaptotetrazole group which enables a Log P in a pH 10 buffer of lower than -0.8. Such a DIR coupler is especially useful in a color photographic silver halide material and process which enables the dye formed from the DIR coupler to be washed out of the photographic material upon processing and enhanced color saturation through interimage effects.
摘要翻译：在酰苯胺部分含有羧基的摄影DIR（显影抑制剂释放）乙酰苯胺偶联剂或包含在2-位上的-CONH 2或-CONHCH 3基团的DIR萘酚成色剂，能够在氧化偶联时形成能够洗涤的染料在加工时，在照相元件中，在偶联位置含有偶联离子基团，其顺序地包含至少一个压载连接基团和至少一个可释放的显影抑制剂基团（INH），其是巯基四唑基团，其使得能够 log P在pH10缓冲液中低于-0.8。这样的DIR耦合器在彩色照相卤化银材料和方法中特别有用，其使得能够在处理时从DIR耦合器形成的染料从照相材料中洗出，并通过图像效果增强色彩饱和度。

2. 发明公开

EP0444502A2 Photographic material and process 失效
标题翻译：摄影材料和Verfahren。
公开(公告)号：EP0444502A2
公开(公告)日：1991-09-04
申请号：EP91102368.7
申请日：1991-02-19
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William James, c/o EASTMAN KODAK COMPANY , Chen, Teh-Hsuan, c/o EASTMAN KODAK COMPANY
IPC分类号： G03C7/305
CPC分类号： C07D257/04 , G03C7/30576 , Y10S430/158
摘要： Photographic compound (A) capable of releasing a development inhibitor group by means of a displacement reaction enables increased image acutance when the compound contains in a coupling position a coupling-off group represented by the formula:

wherein X, R₁, R₂, R₃, R₄, and Q are as defined in the application. Such a compound (A) is useful in a photographic silver halide material and process.
摘要翻译：能够通过置换反应释放显影抑制剂基团的摄影化合物（A）使化合物在偶合位置含有由下式表示的偶联离去基团时可以提高图像浓度：其中X，R 1，R 2， R3，R4和Q如申请中所定义。这种化合物（A）可用于照相卤化银材料和方法。

3. 发明公开

EP0525396A1 Method and photographic material and process comprising a benzotriazole compound 失效
标题翻译： Verfahren und photoisches材料sowie Verfahren mit einer Benzotriazolverbindung。
公开(公告)号：EP0525396A1
公开(公告)日：1993-02-03
申请号：EP92110834.6
申请日：1992-06-26
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William James, c/o EASTMAN KODAK COMPANY
IPC分类号： C07D249/18 , G03C7/305
CPC分类号： C07D249/18 , G03C7/30558 , Y10S430/158
摘要： A new method of preparation of a single isomer of a benzotriazole compound comprises the step of reacting a benzotriazole compound containing symmetrical substituents on the benzo ring with phosgene to produce the corresponding carbamyl chloride. The carbamyl chloride can be reacted with a timing group of a coupling-off group of a photographic coupler to form a photographic development inhibitor releasing coupler. Such compounds are useful in photographic materials and processes.
摘要翻译：制备苯并三唑化合物的单一异构体的新方法包括使苯并环上含有对称取代基的苯并三唑化合物与光气反应以产生相应的氨基甲酰氯的步骤。氨基甲酰氯可以与照相偶合剂的偶联离去基团的定时基团反应，形成照相显影抑制剂释放成色剂。这些化合物可用于照相材料和方法。

4. 发明公开

EP0520498A1 Method of preparation of photographic coupler 失效
标题翻译：维尔法赫尔·赫尔斯特隆摄影师库普勒。
公开(公告)号：EP0520498A1
公开(公告)日：1992-12-30
申请号：EP92110838.7
申请日：1992-06-26
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William James, c/o EASTMAN KODAK COMPANY , Chen, Teh-Hsuan, c/o EASTMAN KODAK COMPANY
IPC分类号： G03C7/305
CPC分类号： G03C7/30576
摘要： A method of preparing a photographic coupler that comprises a parent coupler moiety (COUP) containing a phenoxy coupling-off group having an animomethyl group in the 2-position of the phenoxy coupling-off group comprises (A) reacting (a) a coupler moiety containing a phenoxy coupling-off group having a hydroxyalkyl or hydroxyaryl group in the 2-position wherein the hydroxy is on the alpha carbon atom of the alkyl or aryl group, with (b) a halogenating agent under ambient conditions; then, (B) reacting the product from step (A) with an amine compound. The product can be reacted with phosgene or a bis-thio compound to form an intermediate that is also useful for forming photographic couplers. The resulting products are useful in photographic silver halide materials and processes.
摘要翻译：制备包含苯氧基离去基团的2位上含有animomethyl基的苯氧基离去基团的母体成色剂部分（COUP）的照相成色剂的方法包括（A）使（a）成色剂部分在2-位上含有羟基烷基或羟基芳基的苯氧基离去基团，其中羟基在烷基或芳基的α碳原子上，与（b）卤化剂在环境条件下反应; 然后，（B）使来自步骤（A）的产物与胺化合物反应。该产物可以与光气或双 - 硫代化合物反应形成也可用于形成照相成色剂的中间体。所得产物可用于照相卤化银材料和方法。

5. 发明授权

EP0522371B1 Photographic material and process comprising DIR coupler 失效
标题翻译：一种照相材料和工艺与DIR成色
公开(公告)号：EP0522371B1
公开(公告)日：1998-08-26
申请号：EP92110833.8
申请日：1992-06-26
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William James, c/o EASTMAN KODAK COMPANY , Ling, Hans Gway, c/o EASTMAN KODAK COMPANY
IPC分类号： G03C7/305
CPC分类号： G03C7/30517 , G03C7/30552 , G03C7/30576 , Y10S430/158

6. 发明授权

EP0520498B1 Method of preparation of photographic coupler 失效
标题翻译：一种用于照相成色剂的制备方法
公开(公告)号：EP0520498B1
公开(公告)日：1997-12-17
申请号：EP92110838.7
申请日：1992-06-26
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William James, c/o EASTMAN KODAK COMPANY , Chen, Teh-Hsuan, c/o EASTMAN KODAK COMPANY
IPC分类号： G03C7/305
CPC分类号： G03C7/30576

7. 发明授权

EP0444502B1 Photographic material and process 失效
标题翻译：一种照相材料和方法
公开(公告)号：EP0444502B1
公开(公告)日：1997-06-04
申请号：EP91102368.7
申请日：1991-02-19
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William James, c/o EASTMAN KODAK COMPANY , Chen, Teh-Hsuan, c/o EASTMAN KODAK COMPANY
IPC分类号： G03C7/305
CPC分类号： C07D257/04 , G03C7/30576 , Y10S430/158

8. 发明公开

EP0523423A1 Photographic silver halide material and process comprising water-solubilized naphtholic coupler 失效
标题翻译：摄影师Silasshalogenidmaterial sowie Verfahren mit in Wasserlösbarennaphtholischen Kupplern。
公开(公告)号：EP0523423A1
公开(公告)日：1993-01-20
申请号：EP92110837.9
申请日：1992-06-26
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William James, c/o EASTMAN KODAK COMPANY , Chen, Teh-Hsuan, c/o EASTMAN KODAK COMPANY
IPC分类号： G03C7/305
CPC分类号： G03C7/30541 , Y10S430/156 , Y10S430/158
摘要： A photographic silver halide material and process comprises at least one image dye-forming coupler and at least one coupler (A) represented by the formula SOL-COUP-LINK-PUG wherein SOL is a water solubilizing amide group, COUP is a naphtholic coupler moiety that, upon reaction with oxidized developer is capable of releasing LINK-PUG and capable of forming a compound that is washed out of the photographic material during photographic processing; LINK-PUG is in turn capable of releasing a photographically useful group (PUG) during photographic processing; and wherein LINK is a carbamate linking group comprising a photographic ballast group on the nitrogen atom of the carbamate group. Such a photographic silver halide material enables formation of improved images.
摘要翻译：一种照相卤化银材料和方法包括至少一种成像染料成色剂和至少一种由SOL-COUP-LINK-PUG表示的偶联剂（A），其中SOL是水溶性酰胺基，COUP是萘酚成色剂部分当与氧化显影剂反应时，能够释放LINK-PUG并且能够在照相处理期间形成从照相材料中洗出的化合物; LINK-PUG依然能够在照相处理过程中释放摄影有用的组（PUG）; 并且其中LINK是在氨基甲酸酯基团的氮原子上包含照相镇流剂基团的氨基甲酸酯连接基团。这种照相卤化银材料能够形成改进的图像。

9. 发明授权

EP0523423B1 Photographic silver halide material and process comprising water-solubilized naphtholic coupler 失效
标题翻译：卤化银照相材料和方法与水可溶解的萘酚成色剂
公开(公告)号：EP0523423B1
公开(公告)日：2000-09-13
申请号：EP92110837.9
申请日：1992-06-26
申请人： EASTMAN KODAK COMPANY
发明人： Begley, William James, c/o EASTMAN KODAK COMPANY , Chen, Teh-Hsuan, c/o EASTMAN KODAK COMPANY
IPC分类号： G03C7/305
CPC分类号： G03C7/30541 , Y10S430/156 , Y10S430/158

10. 发明公开

EP0606953A3 Image formation in color reversal materials using strong inhibitors 失效
标题翻译：在彩色反转材料中图像生成，所使用的强抑制剂。
公开(公告)号：EP0606953A3
公开(公告)日：1995-02-15
申请号：EP94200055.5
申请日：1994-01-12
申请人： EASTMAN KODAK COMPANY
发明人： Harder, John William, c/o EASTMAN KODAK COMPANY , Burns, Paul Andrew, c/o EASTMAN KODAK COMPANY , Vargas, J. Ramon, c/o EASTMAN KODAK COMPANY , Bowne, Arlyce Tolman, c/o EASTMAN KODAK COMPANY , Knight, Phillip Dean, c/o EASTMAN KODAK COMPANY , Begley, William James, c/o EASTMAN KODAK COMPANY , Ling, Hans Gway, c/o EASTMAN KODAK COMPANY
IPC分类号： G03C7/305
CPC分类号： G03C7/30558 , Y10S430/158
摘要： An improved color reversal element comprising:
a support having thereon at least two light-sensitive silver halide emulsion layers and a compound capable of releasing a development inhibitor, the element comprising a compound having the structural formula
CAR -(TIME) n -INH
wherein:
CAR is a carrier moiety from which -(TIME) n -INH is released during color development;
TIME is a timing group;
INH is comprised of a development inhibitor moiety selected from the group consisting of oxazole, thiazole, diazole, oxathiazole, triazole, thiatriazole, benzotriazole, tetrazole, benzimidazole, indazole, isoindazole, mercaptotriazole, mercaptothiadiazole, mercaptotetrazole, selenotetrazole, mercaptothiazole, selenobenzothiazole, mercaptobenzoxazole, selenobenzoxazole, mercaptobenzimidazole, mercaptobenzothiazole, selenobenzimidazole, benzodiazole, mercaptooxadiazole, or benzisodiazole, the INH having an inhibitor strength greater than 1 (one), and
n is 0, 1 or 2.

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