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    • 6. 发明公开
    • High viscosity nylon
    • Hochviskoses尼龙。
    • EP0315408A1
    • 1989-05-10
    • EP88310262.6
    • 1988-11-01
    • Du Pont Canada Inc.
    • Besso, Erica Marie-Jose
    • C08G69/04C08K5/51
    • C08K3/32C08G69/04C08G69/28C08K5/5313C08L77/00
    • A process for producing a polyamide with a relative viscosity of at least 100 is dislosed. The process comprises adding a catalyst selected from the group consisting of ortho-phosphoric acid, meta-phosphoric acid, alkali-metal hypophosphite and phenylphosphinic acid to the polyamide, which has a relative viscosity of from 30 to 70, mixing the catalyst and polyamide at a temperature above the melting temperature of the polyamide under reduced pressure and for a time sufficient to increase the relative viscosity of the polyamide to at least 100, and extruding the resulting polyamide into shaped form and quenching said polyamide. The catalyst is present in amounts of at least 0.01 wt.% and increases in relative viscosity may develop in times as short as about one minute.
    • 生产相对粘度至少为100的聚酰胺的方法是闭合的。 该方法包括向聚酰胺中加入选自正磷酸,间磷酸,碱金属次磷酸盐和苯基次膦酸的催化剂,其相对粘度为30〜70,将催化剂和聚酰胺混合在 温度高于聚酰胺在减压下的熔融温度,并且足以将聚酰胺的相对粘度提高至至少100的时间,并将所得聚酰胺挤出成形并淬火所述聚酰胺。 催化剂的存在量为至少0.01重量%,相对粘度的增加可能在短至约1分钟的时间内发生。