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1. 发明公开

EP2831032A1 RADIATION CURABLE (METH)ACRYLATED COMPOUNDS 有权转让
标题翻译：丙烯腈（甲基）丙烯酸酯
公开(公告)号：EP2831032A1
公开(公告)日：2015-02-04
申请号：EP13713132.2
申请日：2013-03-22
申请人： Allnex Belgium, S.A. , Daicel-Allnex Ltd.
发明人： LINDEKENS, Luc , ARCENEAUX, JoAnn , CLEYMANS, Ruben , NAGAKAWA, Ichiro , TANABIKI, Fumio , HIBIU, Hideo
IPC分类号： C07C69/54 , C07D493/04 , C09D133/14
CPC分类号： C09D133/14 , C07C69/54 , C07D493/04 , C08K3/36 , C09D7/61
摘要： The present invention relates to (meth)acrylated compounds (A) prepared from (a) at least one cyclic ether polyol, (b) at least one linking compound (b1) and/or (b2), wherein the linking compound (b1) is selected from cyclic compounds (b11) containing at least one group in the cycle where X = O or NH, from hydroxy acids (b12) and/or from alkylene oxides (b13) containing from 2 to 4 carbon atoms and the linking compound (b2) is selected from epihalohydrins or polyisocyanates, (c) a (meth)acrylating compound; and to their use in radiation curable compositions for the coatings, inks, overprint varnishes, adhesives and composites.
摘要翻译：本发明涉及由（a）至少一种环醚多元醇，（b）至少一种连接化合物（b1）和/或（b2）制备的（甲基）丙烯酸酯化的化合物（A），其中连接化合物（b1）选自含有至少一个基团的环状化合物（b11），其中X = O或NH，羟基酸（b12）和/或含有2至4个碳原子的氧化烯（b13）和连接化合物（ b2）选自表卤代醇或多异氰酸酯，（c）（甲基）丙烯酸酯化合物; 以及它们在用于涂料，油墨，套印清漆，粘合剂和复合材料的可辐射固化组合物中的用途。

2. 发明授权

EP2657293B1 WATER-ABSORBABLE RESIN COMPOSITION AND LAMINATE PRODUCED USING SAME 有权转让
公开(公告)号：EP2657293B1
公开(公告)日：2019-03-27
申请号：EP11852160.8
申请日：2011-12-16
申请人： Daicel-Allnex Ltd. , Daicel Finechem Ltd.
发明人： TANABIKI, Fumio , OKAZAKI, Akira , NIJUKKEN, Toshihiko
IPC分类号： C08L33/24 , B32B27/30 , B32B27/34 , C08F2/44 , C08F220/14 , C08F220/54 , C08K5/103 , C09D5/00 , C09D133/26 , C09D4/06

3. 发明授权

EP2831032B1 RADIATION CURABLE (METH)ACRYLATED COMPOUNDS 有权转让
公开(公告)号：EP2831032B1
公开(公告)日：2018-06-13
申请号：EP13713132.2
申请日：2013-03-22
申请人： Allnex Belgium S.A. , Daicel-Allnex Ltd.
发明人： LINDEKENS, Luc , ARCENEAUX, JoAnn , CLEYMANS, Ruben , NAGAKAWA, Ichiro , TANABIKI, Fumio , HIBIU, Hideo
IPC分类号： C07C69/54 , C07D493/04 , C09D133/14
CPC分类号： C09D133/14 , C07C69/54 , C07D493/04 , C08K3/36 , C09D7/61
摘要： The present invention relates to (meth)acrylated compounds (A) prepared from (a) at least one cyclic ether polyol, (b) at least one linking compound (b1) and/or (b2), wherein the linking compound (b1) is selected from cyclic compounds (b11) containing at least one group in the cycle where X = O or NH, from hydroxy acids (b12) and/or from alkylene oxides (b13) containing from 2 to 4 carbon atoms and the linking compound (b2) is selected from epihalohydrins or polyisocyanates, (c) a (meth)acrylating compound; and to their use in radiation curable compositions for the coatings, inks, overprint varnishes, adhesives and composites.

4. 发明授权

EP2810968B1 ACTIVE ENERGY RAY CURABLE RESIN COMPOSITION 有权
公开(公告)号：EP2810968B1
公开(公告)日：2017-10-04
申请号：EP12867644.2
申请日：2012-12-18
申请人： Daicel-Allnex Ltd.
发明人： TANABIKI, Fumio
IPC分类号： C08G18/67 , C08G18/75 , C08G18/79 , C09D7/12 , C08K3/36 , C09D133/14 , C09D175/16 , C08G18/32 , C08F299/06
CPC分类号： C09D133/14 , C08F299/065 , C08G18/3206 , C08G18/3212 , C08G18/672 , C08G18/673 , C08G18/755 , C08G18/792 , C08K3/36 , C09D7/61 , C09D7/67 , C09D175/16
摘要： Provided is an active energy ray curable resin composition for the formation of a hard coating layer on a thermoplastic resin product, where the hard coating layer is one having good resistance to scratches and abrasion and strong resistance to impact and weather or one having very good resistance to scratches and abrasion. The composition contains a urethane (meth)acrylate (A) having an average number of functional groups of 3 to 6 and having, in molecular skeleton, an organic group corresponding to a tricyclodecanedimethanol represented by following Formula (1), except for removing two hydrogen atoms of two hydroxyl groups therefrom; and a microparticulate silica (S) having a volume median diameter of 1 to 100 nm as determined by dynamic light scattering. The composition contains 10 to 40 percent by weight of the urethane (meth)acrylate (A) and 10 to 60 percent by weight of the microparticulate silica (S) based on the total weight of non-volatile matter in the composition.

5. 发明公开

EP2990428A1 URETHANE (METH)ACRYLATE AND ACTIVE ENERGY RAY-CURABLE RESIN COMPOSITION 审中-公开
标题翻译：氨基甲酸酯（甲基）丙烯酸酯，并通过活性能量射线固化树脂组合物
公开(公告)号：EP2990428A1
公开(公告)日：2016-03-02
申请号：EP14788610.5
申请日：2014-01-23
申请人： Daicel-Allnex Ltd.
发明人： TANABIKI, Fumio
IPC分类号： C08G18/67 , C08F299/06 , C09D175/14
CPC分类号： C09D175/14 , C08F299/065 , C08G18/3206 , C08G18/3212 , C08G18/3218 , C08G18/672 , C08G18/673 , C08G18/755 , C08G18/792 , C08G18/8016 , C08G18/8175 , C09D175/16
摘要： Provided is a compound capable of forming a coating layer that has excellent scratch resistance and still has stain resistance (in particular, stain resistance against hair dyes) and workability (impact resistance) both at satisfactory levels.
The urethane (meth)acrylate has a cyclic structure in a molecule. The urethane (meth)acrylate has a total weight of carbon, oxygen, nitrogen, and sulfur atoms constituting the ring or rings of the cyclic structure of 10 percent by weight or more based on the total amount (100 percent by weight) of the urethane (meth)acrylate. The urethane (meth)acrylate also has an average number of functional groups of 3.5 to 4.5.

6. 发明公开

EP2810968A1 ACTIVE ENERGY RAY CURABLE RESIN COMPOSITION 有权
标题翻译：活性能量射线固化树脂组合物
公开(公告)号：EP2810968A1
公开(公告)日：2014-12-10
申请号：EP12867644.2
申请日：2012-12-18
申请人： Daicel-Allnex Ltd.
发明人： TANABIKI, Fumio
IPC分类号： C08F290/06 , C08F299/06 , C09D5/00 , C09D7/12 , C09D175/16
CPC分类号： C09D133/14 , C08F299/065 , C08G18/3206 , C08G18/3212 , C08G18/672 , C08G18/673 , C08G18/755 , C08G18/792 , C08K3/36 , C09D7/61 , C09D7/67 , C09D175/16
摘要： Provided is an active energy ray curable resin composition for the formation of a hard coating layer on a thermoplastic resin product, where the hard coating layer is one having good resistance to scratches and abrasion and strong resistance to impact and weather or one having very good resistance to scratches and abrasion. The composition contains a urethane (meth)acrylate (A) having an average number of functional groups of 3 to 6 and having, in molecular skeleton, an organic group corresponding to a tricyclodecanedimethanol represented by following Formula (1), except for removing two hydrogen atoms of two hydroxyl groups therefrom; and a microparticulate silica (S) having a volume median diameter of 1 to 100 nm as determined by dynamic light scattering. The composition contains 10 to 40 percent by weight of the urethane (meth)acrylate (A) and 10 to 60 percent by weight of the microparticulate silica (S) based on the total weight of non-volatile matter in the composition.
摘要翻译：本发明提供一种用于在热塑性树脂产品上形成硬涂层的活性能量射线固化型树脂组合物，其中所述硬涂层具有良好的耐刮擦性和耐磨损性，并且具有很强的耐冲击性和耐候性，或者具有非常好的耐受性划痕和磨损。该组合物含有平均官能团数为3〜6的氨基甲酸酯（甲基）丙烯酸酯（A），在分子骨架中具有与下述式（1）所示的三环癸烷二甲醇对应的有机基团，除去2个氢来自两个羟基的原子; 和通过动态光散射测定的体积中值粒径为1〜100nm的微粒状二氧化硅（S）。基于组合物中不挥发性物质的总重量，组合物包含10至40重量％的氨基甲酸酯（甲基）丙烯酸酯（A）和10至60重量％的微粒状二氧化硅（S）。

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