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    • 8. 发明公开
    • RADICALLY CURABLE RESIN COMPOSITIONS
    • 自由基固化型树脂组合物
    • EP1756190A1
    • 2007-02-28
    • EP05735073.8
    • 2005-04-06
    • DSM IP Assets B.V.
    • JANSEN, Johan Franz Gradus AntoniusDRIESSEN, Marco, Marcus, MatheusVAN DIJCK, Michael, Alphonsus, Cornelis, Johannes
    • C08G61/00C08G75/00
    • C08G61/00C08G61/02
    • The present invention relates to resin compositions for radical curing comprising a component (I) containing reactive carbon-carbon unsaturations and a component (ll) containing XH-groups, with X not being C or O., which resin compositions (a) are substantially free of photoinitiators; (b.) have an average number of reactive carbon-carbon unsaturations of component (I) higher than 2; (c) have an average number of XH-groups of component (II) equal to or higher than 2, with at least one of the XH-groups of the XH-component being a thiol group, and; (d) whereby at least one of the average numbers of (b) and (c) is higher than 2; (e) and at most 5 mol% of the reactive unsaturations is capable of undergoing homopolymerisation; (f) respectively is present in the form of a mono-ene functional alkylene; and (g) the molar ratio of the XH-groups and of the reactive unsaturations is in the range of from 4 : 1 to 1 : 4; with the proviso that the RU component is not tris-(norborn-5-ene-2-carboxy) propoxypropane. The present invention also relates to processes for curing such resin compositions, in particular by cold curing. And finally, the present invention also relates to a new process for the synthesis of Diels-Alder adducts of cyclopentadiene and a resin component containing telechelic carbon-carbon unsaturation. The resin compositions are capable of providing constructive materials with tack-free surfaces by fast, and tunable, radical curing, and without any problems of so-called oxygen inhibition. Suitable applications are in chemical anchoring, roofing, flooring, (re)-lining, SMCs and BMCs.