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    • 3. 发明公开
    • FLUORORUBBER COMPOSITION
    • 氟树脂组合物
    • EP2804905A1
    • 2014-11-26
    • EP13751700.9
    • 2013-02-22
    • Daikin Industries, Ltd.
    • OTA, DaisukeUEDA, AkinoriKADOWAKI, YuuTAEDA, MayukoKITAICHI, MasanoriYAMAMURA, KazuhiroDOI, MichikoFUKUOKA, Shoji
    • C08L27/12B29C33/02B29C35/02C08K3/04B29K27/12B29K105/24B29L30/00
    • C08K3/04C08L27/16
    • Provided is a fluororubber composition having excellent tensile properties at high temperatures. The fluororubber composition comprises a fluororubber (A) and a carbon black (B), and the fluororubber (A) is a vinylidene fluoride-based fluororubber comprising a structural unit (VdF unit) derived from vinylidene fluoride and a structural unit derived from at least one monomer selected from the group consisting of hexafluoropropylene (HFP), 2,3,3,3-tetrafluoro propylene, and perfluoro(alkyl vinyl ether) (PAVE), and the molar ratio of the VdF unit to the structural unit derived from at least one monomer selected from the group consisting of HFP, 2,3,3,3-tetrafluoro propylene, and PAVE is 50/50 to 78/22, wherein the fluororubber composition a difference δG' (G'(1%) - G'(100%)) of not lower than 120 kPa and not higher than 3,000 kPa, where G'(1%) denotes a modulus of shearing elasticity at a dynamic strain of 1%, G'(100%) denotes a modulus of shearing elasticity at a dynamic strain of 100%, and G'(1%) and G'(100%) are determined by a dynamic viscoelasticity test carried out on an unvulcanised rubber with a rubber process analyzer (RPA)in a condition that the measurement frequency is 1 Hz and the measurement temperature is 100°C.
    • 本发明提供高温下的拉伸特性优异的氟橡胶组合物。 氟橡胶组合物包含氟橡胶(A)和炭黑(B),氟橡胶(A)是包含来自偏二氟乙烯的结构单元(VdF单元)和至少来源于结构单元的偏氟乙烯类氟橡胶 选自由六氟丙烯(HFP),2,3,3,3-四氟丙烯和全氟(烷基乙烯基醚)(PAVE)组成的组中的一种单体,以及VdF单元与衍生自 选自由HFP,2,3,3,3-四氟丙烯和PAVE组成的组中的至少一种单体为50/50至78/22,其中所述氟橡胶组合物的差δG'(G'(1%)-G (1%)表示在1%的动态应变下的剪切弹性模量,G'(100%)表示模量为(100%))不低于120kPa且不高于3,000kPa, 在100%的动态应变下的剪切弹性和G'(1%)和G'(100%)通过对未涂覆的橡胶进行的动态粘弹性测试来确定 在测量频率为1 Hz,测量温度为100°C的条件下使用橡胶加工分析仪(RPA)测量橡胶胶料。