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    • 7. 发明公开
      EP1566398A1 Method for drying nonionic alkylene oxide-type water soluble resin, method for packaging it, and method for transporting it 审中-公开
    • Method for drying nonionic alkylene oxide-type water soluble resin, method for packaging it, and method for transporting it
    • 用于干燥的烯化氧类型的非离子，水溶性树脂的方法，其用于包装和运输的方法
    • EP1566398A1
    • 2005-08-24
    • EP05003336.4
    • 2005-02-16
    • DAI-ICHI KOGYO SEIYAKU CO., LTD. , NIPPON SHOKUBAI CO., LTD.
    • Kono, Michiyuki , Kikuta, Manabu , Tezuka, Masaki , Tanaka, Hiroshi , Yokohashi, Takao , Nishihata, Takao , Murata, Kazuhiko , Toba, Taketo , Tamura, Fumihide , Kitada, Ritsuo
    • C08G65/34 , C08G65/46 , C08G65/02 , C08G65/30
    • C08G65/30 , Y10T428/1348
    • For efficiently drying a nonionic alkylene oxide-type water-soluble resin to make it have a low water content within a short period of time, the resin is put into a container, then the container is degassed to a vacuum degree of at most 150 mmHg, and while the vacuum degree is kept as such, a dry gas having a dew point not higher than the dew point DP calculated according to the following formula (1) is introduced into the container at an introduction rate not lower than the introduction rate V calculated according to the following formula (2). For efficiently removing minor volatiles from a nonionic alkylene oxide-type water-soluble resin, used is a drying device that comprises an evaporation tank where the resin is put in and a stirring blade which revolves inside the evaporation tank as it rotates on its own axis. For protecting a dried nonionic alkylene oxide-type water-soluble resin from water, a preferred method comprises introducing a dry gas into a packing line that runs from a dry resin-feeding zone to a packaging container, thereby introducing the dry gas into the empty packaging container just before packed with the resin along with purging away the air initially existing in the container, then packing the packaging container with the resin, and sealing up the opening of the packaging container. A method of transporting a nonionic alkylene oxide-type water-soluble resin that ensures good processability of the resin and prevents the resin from being deteriorated comprises controlling the resin so as to have a solvent content of from 0.001 to 50 % by weight and a viscosity at 40°C of at most 10,000 Pa·sec, and loading it into a transportation container equipped with a temperature control capability and/or unloading it out of the transportation container by the use of a pump. DP (°C) = -21.6 log 10 Vac V (L/min) = 0.5 × [Vac/(273 + T)] × V 0 wherein Vac indicates the vacuum degree (mm Hg), T indicates the temperature inside the container (°C), V 0 indicates the volume of the container (ml).
    • 为了有效地进行干燥的非离子烯属烃氧化物型水溶性树脂，使之具有很短的时间周期内的低水含量时，树脂放入容器中，然后将容器脱气至至多150毫米汞柱的真空度 ，并且在真空度保持为搜索，具有露点不大于计算雅丁以下公式露点DP高的干燥气体（1）在引入速率不大于导入速度V下引入容器 计算gemäß下面的公式（2）。 为有效地从非离子烯属烃氧化物型水溶性树脂，使用除去次要挥发物是干燥装置确实将树脂放入蒸发罐的包括和搅拌叶片在其旋转时在其自身的轴线的蒸发罐内哪个旋转 ， 用于保护干燥的非离子烯属烃氧化物类水溶性树脂选自水，优选的方法包括从干树脂进料区引入干燥气体进入包装线并延伸到包装容器中，从而引入干燥气体送入空 包装容器刚刚填充了树脂非常久远吹扫出空气初始存在于容器中，然后用树脂填充的包装容器，和密封起来包装容器的开口部之前。 确实输送非离子烯属烃氧化物型水溶性树脂的方法，确保了树脂的良好加工性和的恶化包括控制树脂，以便通过重量和粘度以具有从0.001％至50％的溶剂含量防止树脂 在40℃下至多万帕·秒，并且加载到配备有温度控制能力和/或通过使用泵的卸出来的运输容器的运输容器。 DP（℃）= -21.6日志10伏交流 V（升/分钟）= 0.5×AVAC /（273 + T）ÜX V0 worin吸尘器指示真空度（毫米汞柱），T表示所述容器（℃）内部的温度，V0表示所述容器（毫升）的体积。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 8. 发明公开
      EP0825206A1 Thermoplastic resin composition and compatibilizing agent used therein 失效
    • Thermoplastic resin composition and compatibilizing agent used therein
    • 热塑性树脂和大理石
    • EP0825206A1
    • 1998-02-25
    • EP97306163.3
    • 1997-08-13
    • DAI-ICHI KOGYO SEIYAKU CO., LTD.
    • Kikuta, Manabu , Hotta, Hiroshi , Teramoto, Makato
    • C08F212/06 , C08F220/12 , C08L77/00 , C08L67/00 , C08L69/00
    • C08L69/00 , C08F226/02 , C08L67/02 , C08L77/00 , C08L2666/02 , C08L25/00 , C08L71/00
    • The thermoplastic resin composition comprising at least one resin selected from a polycarbonate resin, a polyamide resin and a polyester resin, at least one of a styrene type resin and a polyphenylene ether resin, and further, a copolymer, as a compatibilizing agent, comprising monomers consisting essentially of a monomer having a formamide group represented by the following general formula (1) and an aromatic vinyl type monomer:
      wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 , which are the same or different, represent a hydrogen atom, an alkyl group with 1 to 8 carbon atoms, a cycloalkyl group with 6 to 10 carbon atoms, an alkyl aryl group with 6 to 10 carbon atoms, or an arylalkyl group with 6 to 10 carbon atoms.
      The resultant thermoplastic resin composition is excellent in melt fluidity when molded, and a molded product using the thermoplastic resin composition as a molding material presents good appearance without interlaminar cleavage and is excellent in impact resistance. As a result, the thermoplastic resin compositions may be used for molding materials for molded products in the forms of sheet, film and the like in various molding methods such as injection molding, extrusion molding and the like.
    • 包含选自聚碳酸酯树脂，聚酰胺树脂和聚酯树脂中的至少一种树脂，苯乙烯类树脂和聚苯醚树脂中的至少一种的热塑性树脂组合物，以及作为相容剂的共聚物，其包含单体 基本上由具有由以下通式（1）表示的甲酰胺基团和芳香族乙烯基类单体：CHEM的单体组成，其中相同或不同的R 1，R 2，R 3，R 4，R 5和R 6表示 氢原子，碳原子数1〜8的烷基，碳原子数6〜10的环烷基，碳原子数6〜10的烷基芳基，碳原子数6〜10的芳烷基。 得到的热塑性树脂组合物在成型时的熔融流动性优异，使用热塑性树脂组合物作为成型材料的成型体，没有层间裂开，外观良好，耐冲击性优异。 结果，热塑性树脂组合物可以以各种成型方法如注射成型，挤出成型等方式用于片材，薄膜等形式的成型制品的成型材料。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 9. 发明公开
      EP0525793A1 Formamide group-containing copolymer, process for producing the same, and thermoplastic resin composition containing the same 失效
    • Formamide group-containing copolymer, process for producing the same, and thermoplastic resin composition containing the same
    • 含甲酰胺共聚物，工艺及其制造和含有该共聚物的热塑性树脂组合物。
    • EP0525793A1
    • 1993-02-03
    • EP92113094.4
    • 1992-07-31
    • DAI-ICHI KOGYO SEIYAKU CO., LTD.
    • Kitazawa, Naoki , Hotta, Hiroshi , Sumi, Hideyuki , Kikuta, Manabu , Sugita, Yasuhisa, c/o Udemitsu Petroch. Co., Ltd. , Ohta, Katsutoshi, c/o Udemitsu Petroch. Co., Ltd.
    • C08F8/32
    • C08F8/32 , C08F2800/10 , C08F8/48 , C08F212/08 , C08F210/10 , C08F222/06
    • A copolymer or a salt thereof is disclosed, containing in the molecule thereof:

      (A) from 20 to 99.8 mole% of a recurring unit represented by formula (I),
      (B) from 50 to 0 mole% of a recurring unit represented by formula (II), and
      (C) a recurring unit containing a unit represented by formula (III), (D) a recurring unit containing a unit represented by formula (IV), and (E) a recurring unit containing a unit represented by formula (V) in a total amount of from 60 to 0.2 mole%, provided that the amount of said recurring unit (C) is at least 0.2 mole%:






      wherein R 1 and R 2 each independently represents a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, a cycloalkyl group having from 3 to 8 carbon atoms, an aryl group having from 6 to 10 carbon atoms, an alkenyl group having from 2 to 4 carbon atoms, an alkoxy group having from 1 to 4 carbon atoms, an alkoxycarbonyl group having from 1 to 18 carbon atoms, an alkylcarboxyl group having from 1 to 17 carbon atoms, an alkylcarbonyl group having from 1 to 6 carbon atoms, an arylcarbonyl group having from 6 to 8 carbon atoms, a halogen atom, or a nitrile group; R 3 and R 4 each independently represents a hydrogen atom, an alkyl group having from 1 to 4 carbon atoms, an alkenyl group having from 2 to 4 carbon atoms, or a halogen atom; R 5 and R 6 each independently represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, or an aryl group having from 6 to 8 carbon atoms; R 7 represents an alkylene group having from 1 to 12 carbon atoms, a cycloalkylene group having from 5 to 17 carbon atoms, an arylene group having from 6 to 12 carbon atoms, an arylalkylene group having from 7 to 12 carbon atoms, or a polyoxyalkylene group having from 4 to 30 carbon atoms; R 1 to R 7 may be each the same or different in each of the recurring units; and X 1 and X 2 each independently represents NH 2 or NH-CHO. A process for producing the above-described copolymer or its salt is also disclosed. A thermoplastic resin composition comprising the above-described copolymer or its salt is further disclosed.
    • 的共聚物或它们的盐盘游离缺失，其分子中含有：（A）从20到的由式（I）表示的重复单元，（B）的99.8摩尔％为50〜表示的重复单元的0摩尔％ 式（II），和（C）的重复单元含有由式表示的单元（III），（d）含有一个单元的重复单元的由式（IV），和（e）的重复单元含有由表示的单元代表 式（V）摩尔为60〜0.2％的总量，提供没有说的量重复单元（C）为至少0.2摩尔％： worin - [R <1>和R <2> 各自独立地darstellt氢原子，在具有从1至10个碳原子的烷基，具有3至8个碳原子，以6至10个碳原子具有2至4个碳原子的链烯基具有芳基的环烷基 在1至4个碳原子具有1至18个碳原子具有烷基羧基从1至17个碳原子基团具有烷氧基羰基烷氧基， 在具有1至6个碳原子到具有6至8个碳原子，卤原子或腈基芳基羰基烷基羰基; [R <3>和R <4>各自独立地darstellt氢原子，在具有1至4个碳原子具有2至4个碳原子，或卤素原子的链烯基烷基; [R <5>和R <6>各自独立地darstellt氢原子，在具有从1至6个碳原子，或在具有从6-8个碳原子的芳基烷基; [R <7>在darstellt具有1至12个碳原子的亚烷基，具有5至17个碳原子的亚芳具有6至12个碳原子基团的亚环烷基组，芳基亚从7至12个碳原子具有基团，或 具有4至30个碳原子的聚氧化烯基团; [R <1>至R <7>可以是在每个重复单元中的每个相同或不同的; 和X <1>和X <2>每个unabhängigdarstellt NH 2或NH-CHO。 一种用于生产上述共聚物或其盐的方法是这样游离缺失盘。 一种热塑性树脂组合物，含有上述共聚物或其盐是Furtherwirt游离缺失盘。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
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