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    • 1. 发明公开
    • USE OF AN ADDITIVE COMPOSITION FOR THE PREPARATION OF POLYCONDENSATION POLYMERS
    • 使用添加剂组合物制备多缩合聚合物
    • EP3263639A1
    • 2018-01-03
    • EP16176384.2
    • 2016-06-27
    • Clariant International Ltd
    • STEFFANUT, PascalSIDQI, MohamedDONGIOVANNI, ErnestoABRAHMI, Jerome
    • C08K5/3435C08G63/00C08G69/00C08K5/526C08K5/5393
    • C08K5/3435C08G63/00C08G69/16C08K5/526C08K5/5393
    • The present invention relates to the use of an additive composition for the preparation of polycondensation polymers wherein the additive combination is present in the polycondensation reaction and wherein the additive combination comprises one or more compounds of the formula (A)

      wherein
      R 11 , R 12 , R 13 , R 14 , R 15 , R 16 , R 17 , and R 18 are independently selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert.-butyl, linear or branched pentyl, linear or branched hexyl, linear or branched heptyl, linear or branched octyl or linear and branched nonyl groups, and
      R 21 and R 22 are independently selected from the group consisting of hydrogen, methyl, O(C 1 -C 6 -Acyl) and O-R 3 , wherein R 3 is selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert.-butyl linear or branched pentyl, linear or branched hexyl, linear or branched heptyl, linear or branched octyl or linear and branched nonyl groups, and
      one or more sterically hindered organic phosphorous(III) compounds selected from the group consisting of sterically hindered phenyl phosphonites and sterically hindered phosphites.
    • 本发明涉及添加剂组合物用于制备缩聚聚合物的用途,其中添加剂组合存在于缩聚反应中,并且其中添加剂组合包含一种或多种式(A)的化合物,其中R 11,R 12,R 13, R14,R15,R16,R17和R18独立地选自甲基,乙基,丙基,异丙基,丁基,异丁基,叔丁基,直链或支链戊基,直链或支链己基, 直链或支链的辛基或直链和支链壬基,R 21和R 22独立地选自氢,甲基,O(C 1 -C 6酰基)和O-R 3,其中R 3选自甲基 ,乙基,丙基,异丙基,丁基,异丁基,叔丁基直链或支链戊基,直链或支链己基,直链或支链庚基,直链或支链辛基或直链和支链壬基,和一个或多个空间位阻 d有机磷(III)化合物,其选自位阻苯基亚膦酸酯和位阻亚磷酸酯。
    • 2. 发明公开
    • OXYGEN BARRIER PLASTIC MATERIAL
    • 氧气阻隔塑料材料
    • EP3157993A1
    • 2017-04-26
    • EP15716743.8
    • 2015-04-13
    • Clariant International LtdClariant Masterbatches (Italia) S.p.A.
    • DESCORTES, AntonelloSTEFFANUT, PascalMARSON, AngelicaFAVA, FlavioMULLER, Thierry
    • C08K5/20C08L23/00C08L25/00
    • C08K5/20B65D65/40B65D81/266C08K5/098C08K2201/008C08K2201/012C08L23/04C08L25/06C08L2310/00
    • The invention relates to use of an additive as oxygen barrier in a plastic material wherein (a) the plastic material is a polyolefin, a polyolefin copolymer or a polystyrene, and the additive is (b) and optionally (c): (b) a compound of formula (I); wherein Ra represents C 7 -C 20 alkyl, C 6 -C 10 aryl, C 4 -C 10 heteroaryl, wherein the heteroatoms are N, O and/or S, (C 2 -C 6 )-alkenylen-(C 6 -C 10 ) aryl, C 1 -C 6 -alkylen-C 6 -C 10 -aryl, the aryl and heteroaryl radicals optionally being substituted by: hydroxyl, C 1 -C 6 -alkyl, C 1 -C 6 alkoxyl, C 6 -C 10 aryloxy, halogen, cyano, nitro, C 6 -C 10 -aryl, di(C 1 -C 6 )alkylamino, (C 1 -C 6 )alkylthio, C 6 -C 10 -arylthio, =O, =S, SO 3 H, SO 2 NR 1 R 2 , CO 2 R 3 , CONR 1 R 2 , NHCOR 4 , CO-C 6 -C 10 -aryl or a combination thereof, wherein R 1 , R 2 , R 3 , R 4 are the same or different and independently represent hydrogen or C 1 -C 6 -alkyl; Rb represents a group selected from the moieties of formula (II), (III), (IV), (V), (VI) and (VII); wherein each Rc can be the same or different and independently represents hydrogen, C 1 -C 20 alkyl or C 6 -C 10 -aryl, (C 2 -C 4 ) alkenylen (C 6 -C 10 ) aryl, C 1 -C 4 -alkylen-C 6 -C 10 -aryl, the aryl radicals optionally being substituted by hydroxyl, C 1 -C 4 -alkyl, C 1 -C 4 alkoxyl, C 6 -C 10 aryloxy, Cl, cyano, C 6 -C 10 -aryl, or CO-C 6 -C 10 -aryl; Rd represents hydrogen, C 1-30 alkyl, C 6 -C 10 -aryl or halogen; Re represents hydrogen, C 1-30 alkyl, C 6 -C 10 -aryl or a halogen and can be on ortho (o) or meta (m) position to Rd; X can be O or N-Rf where Rf represents hydrogen, C 1 -C 20 alkyl or phenyl; Y can be O or S; n is a number from 1 to 30; (c) a transition metal catalyst.
    • (a)塑料材料是聚烯烃,聚烯烃共聚物或聚苯乙烯,并且添加剂是(b)和任选的(c):(b) 式(I)化合物; 其中Ra表示C 7 -C 20烷基,C 6 -C 10芳基,C 4 -C 10杂芳基,其中杂原子是N,O和/或S,(C 2 -C 6) - 亚烯基 - (C 6 - C10)芳基,C1-C6-亚烷基-C6-C10-芳基,所述芳基和杂芳基任选被羟基,C1-C6-烷基,C1-C6烷氧基,C6- C 1 -C 6烷基氨基,(C 1 -C 6)烷硫基,C 6 -C 10芳基硫基,= O,= C 1 -C 6烷氧基, S,SO 3 H,SO 2 NR 1 R 2,CO 2 R 3,CONR 1 R 2,NHCOR 4,CO-C 6 -C 10 - 芳基或其组合,其中R 1,R 2,R 3, R 4相同或不同并且独立地表示氢或C 1 -C 6烷基; Rb表示选自式(II),(III),(IV),(V),(VI)和(VII)的基团的基团; (C 2 -C 4)亚烯基(C 6 -C 10)芳基,C 1 -C 20烷基或C 6 -C 10芳基, 所述芳基可选地被羟基,C 1 -C 4烷基,C 1 -C 4烷氧基,C 6 -C 10芳氧基,Cl,氰基,C 6 -C 10芳基, C 10 - 芳基或CO-C 6 -C 10 - 芳基; Rd代表氢,C 1-30烷基,C 6 -C 10 - 芳基或卤素; Re代表氢,C 1-30烷基,C 6 -C 10 - 芳基或卤素并且可以在Rd的邻位(o)或间位(m)上; X可以是O或N-Rf,其中Rf代表氢,C 1 -C 20烷基或苯基; Y可以是O或S; n是从1到30的数字; (c)过渡金属催化剂。