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1. 发明公开

EP2949739A1 CLOCK LUBRICATING-OIL COMPOSITION AND CLOCK 有权
标题翻译： SCHMIERÖLZUSAMMENSETZUNGFÜREINE UHR UND UHR
公开(公告)号：EP2949739A1
公开(公告)日：2015-12-02
申请号：EP14743589.5
申请日：2014-01-14
申请人： Citizen Holdings Co., Ltd. , Citizen Watch Co., Ltd.
发明人： AKAO, Yuji
IPC分类号： C10M169/04 , C10M105/18 , C10M105/38 , C10M107/02 , C10M129/40 , C10M133/12 , C10M133/38 , C10M133/40 , C10M137/02 , C10M137/04 , C10M143/06 , C10N10/02 , C10N30/06 , C10N30/10 , C10N30/12 , C10N40/00
CPC分类号： C10M161/00 , C10M141/10 , C10M169/04 , C10M2201/041 , C10M2201/066 , C10M2203/1025 , C10M2205/026 , C10M2205/0285 , C10M2205/046 , C10M2207/0406 , C10M2207/1285 , C10M2207/2835 , C10M2209/062 , C10M2209/084 , C10M2209/0866 , C10M2209/1026 , C10M2209/108 , C10M2209/1085 , C10M2213/062 , C10M2215/064 , C10M2215/221 , C10M2215/223 , C10M2223/04 , C10M2223/041 , C10M2223/049 , C10N2210/01 , C10N2220/021 , C10N2220/082 , C10N2230/06 , C10N2240/06 , C10N2250/10
摘要： [Problem] To provide a lubricating oil composition for a timepiece, said composition being excellent in wear resistance and extreme pressure properties. [Solution] The lubricating oil composition for a timepiece according to the present invention contains a lubricant component (A) containing a base oil (A1), at least one antiwear agent (B) selected from a neutral phosphate ester (B-1) and a neutral phosphite ester (B-2), and an antioxidant (C), and is characterized in that the total acid number of the composition is not more than 0.8 mgKOH/g, the antiwear agent (B) is contained in an amount of 0.1 to 15 parts by mass based on 100 parts by mass of the lubricant component (A), and the antioxidant (C) is contained in an amount of 0.01 to 3 parts by mass based on 100 parts by mass of the lubricant component (A), and the neutral phosphate ester (B-1) is represented by the following general formula (b-1) and the neutral phosphite ester (B-2) is represented by the following general formula (b-2).
摘要翻译：为了提供一种用于钟表的润滑油组合物，所述组合物具有优异的耐磨性和极压性能。 [解决方案]本发明的钟表用润滑油组合物含有含有基油（A1）的润滑剂成分（A），选自中性磷酸酯（B-1）和中性亚磷酸酯（B-2）和抗氧化剂（C），其特征在于，组合物的总酸值不大于0.8mgKOH / g，抗磨剂（B）的含量为相对于100质量份的润滑剂成分（A）为0.1〜15质量份，相对于100质量份的润滑剂成分（A），含有0.01〜3质量份的抗氧化剂（C）），中性磷酸酯（B-1）由以下通式（b-1）表示，中性亚磷酸酯（B-2）由以下通式（b-2）表示。

2. 发明授权

EP2949739B1 CLOCK LUBRICATING-OIL COMPOSITION AND CLOCK 有权
标题翻译：时钟润滑油组合物和时钟
公开(公告)号：EP2949739B1
公开(公告)日：2017-06-28
申请号：EP14743589.5
申请日：2014-01-14
申请人： Citizen Watch Co., Ltd.
发明人： AKAO, Yuji
IPC分类号： C10M169/04 , C10M141/10 , C10N10/02 , C10N30/06 , C10N40/06 , C10N20/04 , C10N20/02
CPC分类号： C10M161/00 , C10M141/10 , C10M169/04 , C10M2201/041 , C10M2201/066 , C10M2203/1025 , C10M2205/026 , C10M2205/0285 , C10M2205/046 , C10M2207/0406 , C10M2207/1285 , C10M2207/2835 , C10M2209/062 , C10M2209/084 , C10M2209/0866 , C10M2209/1026 , C10M2209/108 , C10M2209/1085 , C10M2213/062 , C10M2215/064 , C10M2215/221 , C10M2215/223 , C10M2223/04 , C10M2223/041 , C10M2223/049 , C10N2210/01 , C10N2220/021 , C10N2220/082 , C10N2230/06 , C10N2240/06 , C10N2250/10

3. 发明公开

EP2949734A1 CLOCK LUBRICATING-OIL COMPOSITION AND CLOCK 有权
标题翻译：时钟润滑油组合物和时钟
公开(公告)号：EP2949734A1
公开(公告)日：2015-12-02
申请号：EP14743825.3
申请日：2014-01-14
申请人： Citizen Holdings Co., Ltd. , Citizen Watch Co., Ltd.
发明人： AKAO, Yuji
IPC分类号： C10M105/38 , C10M105/18 , C10M107/02 , C10M133/38 , C10M133/40 , C10M137/04 , C10M143/00 , C10M143/06 , C10M143/10 , C10M145/14 , C10M145/16 , C10M145/22 , C10M159/12 , C10N20/00 , C10N20/02 , C10N30/02 , C10N30/06 , C10N40/06 , C10N40/08
CPC分类号： C10M169/044 , C10M141/10 , C10M169/04 , C10M2201/041 , C10M2201/066 , C10M2205/026 , C10M2205/0285 , C10M2205/046 , C10M2207/0406 , C10M2207/2835 , C10M2209/062 , C10M2209/084 , C10M2209/0866 , C10M2209/1026 , C10M2209/1085 , C10M2213/062 , C10M2215/064 , C10M2215/221 , C10M2215/223 , C10M2223/04 , C10M2223/041 , C10M2223/049 , C10N2220/021 , C10N2220/082 , C10N2230/06 , C10N2240/06
摘要： [Problem] To provide a lubricating oil composition for a timepiece, said composition being excellent in durability. [Solution] The lubricating oil composition for a timepiece according to the present invention contains a lubricant component (A) containing a base oil (A1), at least one antiwear agent (B) selected from a neutral phosphate ester and a neutral phosphite ester, and an antioxidant (C), and is characterized in that the total acid number of the composition is not more than 0.8 mgKOH/g, the antiwear agent (B) is contained in an amount of 0.1 to 15 parts by mass based on 100 parts by mass of the lubricant component (A), the antioxidant (C) is contained in an amount of 0.01 to 3 parts by mass based on 100 parts by mass of the lubricant component (A), and the composition contains a diphenylamine derivative (C-1) represented by the following general formula (c-1) and a hindered amine compound (C-2) represented by the following general formula (c-2) as the antioxidants (C).
摘要翻译：本发明的目的在于提供一种钟表用润滑油组合物，其耐久性优异。本发明的钟表用润滑油组合物含有包含基础油（A1），选自中性磷酸酯和中性亚磷酸酯中的至少一种抗磨剂（B）的润滑剂成分（A）和抗氧化剂（C）的组合物，其特征在于，组合物的总酸值为0.8mgKOH / g以下，抗磨剂（B）的含量为0.1〜15质量份，（A）的抗氧化剂（C）的含量相对于100质量份的润滑剂成分（A）为0.01〜3质量份，该组合物含有二苯胺衍生物（C （c-1）表示的受阻胺化合物（C-2）和由下述通式（c-2）表示的受阻胺化合物（C-2）作为抗氧化剂（C）。

4. 发明授权

EP1201734B1 Use of a LUBRICATING OIL COMPOSITION in a watch AND WATCH CONTAINING THE SAME 有权
标题翻译：在手表使用的油组合物和观看该组合物
公开(公告)号：EP1201734B1
公开(公告)日：2006-06-14
申请号：EP01904351.2
申请日：2001-02-08
申请人： CITIZEN WATCH CO. LTD.
发明人： AKAO, Yuji
IPC分类号： C10M169/04 , C10M105/38 , C10M107/02 , C10M129/10 , C10M133/44 , C10M137/02 , C10M137/04 , C10M143/02 , C10M143/06 , C10M143/10 , C10M143/12 , C10M145/14 , C10M145/16 , C10M145/22 , C10M149/10 , C10M105/18 , C10M107/34 , C10M129/14 , C10M133/12 , C10N40/00
CPC分类号： C10M169/044 , C10M169/04 , C10M2203/0206 , C10M2205/02 , C10M2205/0206 , C10M2205/022 , C10M2205/026 , C10M2205/0285 , C10M2205/04 , C10M2207/026 , C10M2207/04 , C10M2207/0406 , C10M2207/2825 , C10M2207/2835 , C10M2207/2845 , C10M2207/2865 , C10M2209/062 , C10M2209/084 , C10M2209/086 , C10M2209/102 , C10M2209/1033 , C10M2209/1085 , C10M2215/062 , C10M2215/064 , C10M2215/223 , C10M2219/082 , C10M2223/04 , C10M2223/041 , C10M2223/043 , C10M2223/045 , C10M2223/049 , C10M2223/06 , C10M2229/0415 , C10N2210/02 , C10N2210/06 , C10N2220/022 , C10N2230/00 , C10N2230/02 , C10N2230/06 , C10N2240/06 , G04B31/08 , C10M2205/028
摘要： A first lubricating oil composition which comprises a polyol ester (A) as a base oil, a viscosity index improver (B), and an antiwearing agent (C) in a specific proportion; and a second lubricating oil composition which comprises a paraffinic hydrocarbon oil (F) having at least 30 carbon atoms and a viscosity index improver (B) in a specific proportion. These compositions have the following effects. They enable watch batteries to retain a long life, can function in the range of -30 to 80 DEG C even when used alone, and do not alter over long. Also provided is a third lubricating oil composition which comprises an ether oil (G) as a base oil, a specific amount of an antiwearing agent (C) comprising a neutral phosphoric ester and/or a neutral phosphorous ester, and an antioxidant (E). This composition does not alter over long and is suitable for use as a lubricating oil for watches. The watch is made by using in the sliding parts at least one composition selected from the group consisting of these compositions.

5. 发明公开

EP3594304A1 POWDERY COMPOSITION FOR HEXAVALENT CHROMIUM TREATMENT, TABLET, AND METHOD FOR PRODUCING LEATHER 审中-公开
公开(公告)号：EP3594304A1
公开(公告)日：2020-01-15
申请号：EP18763250.0
申请日：2018-01-22
申请人： Citizen Watch Co., Ltd.
发明人： AKAO, Yuji
IPC分类号： C09K3/00 , C14C3/06
摘要： A powdery composition for hexavalent chromium treatment contains a hexavalent chromium reducing compound component capable of reducing hexavalent chromium into trivalent chromium, and a component capable of trapping moisture in air and dissolving in water. The hexavalent chromium reducing compound component contains an organic compound (A) having the structure represented by chemical formula (1) and capable of acting on hexavalent chromium for reduction into trivalent chromium, having a hydroxyphenyl group, and having no aldehyde groups and no carboxy groups.

6. 发明授权

EP2949734B1 CLOCK LUBRICATING-OIL COMPOSITION AND CLOCK 有权
公开(公告)号：EP2949734B1
公开(公告)日：2017-06-28
申请号：EP14743825.3
申请日：2014-01-14
申请人： Citizen Watch Co., Ltd.
发明人： AKAO, Yuji
IPC分类号： C10M141/10 , C10M169/04 , C10N20/06 , C10N30/06 , C10N40/06 , C10N40/08
CPC分类号： C10M169/044 , C10M141/10 , C10M169/04 , C10M2201/041 , C10M2201/066 , C10M2205/026 , C10M2205/0285 , C10M2205/046 , C10M2207/0406 , C10M2207/2835 , C10M2209/062 , C10M2209/084 , C10M2209/0866 , C10M2209/1026 , C10M2209/1085 , C10M2213/062 , C10M2215/064 , C10M2215/221 , C10M2215/223 , C10M2223/04 , C10M2223/041 , C10M2223/049 , C10N2220/021 , C10N2220/082 , C10N2230/06 , C10N2240/06
摘要： [Problem] To provide a lubricating oil composition for a timepiece, said composition being excellent in durability. [Solution] The lubricating oil composition for a timepiece according to the present invention contains a lubricant component (A) containing a base oil (A1), at least one antiwear agent (B) selected from a neutral phosphate ester and a neutral phosphite ester, and an antioxidant (C), and is characterized in that the total acid number of the composition is not more than 0.8 mgKOH/g, the antiwear agent (B) is contained in an amount of 0.1 to 15 parts by mass based on 100 parts by mass of the lubricant component (A), the antioxidant (C) is contained in an amount of 0.01 to 3 parts by mass based on 100 parts by mass of the lubricant component (A), and the composition contains a diphenylamine derivative (C-1) represented by the following general formula (c-1) and a hindered amine compound (C-2) represented by the following general formula (c-2) as the antioxidants (C).

7. 发明公开

EP3178947A1 LEATHER OR LEATHER ARTICLE AND METHOD FOR PRODUCING SAME, HEXAVALENT CHROMIUM TREATMENT AGENT, METHOD FOR TREATING HEXAVALENT CHROMIUM IN CRUDE LEATHER OR CRUDE LEATHER ARTICLE 审中-公开
标题翻译：皮革或皮革制品及其制造方法，处理剂六价铬，方法六价铬的ROHLEDER或任何ROHLEDERARTIKEL的治疗
公开(公告)号：EP3178947A1
公开(公告)日：2017-06-14
申请号：EP15830021.0
申请日：2015-07-29
申请人： Citizen Watch Co., Ltd.
发明人： AKAO, Yuji
IPC分类号： C14C3/06 , A62D3/37 , C07C39/08 , C07C39/10 , C07C39/14 , C07C69/84 , C07D307/33 , C07D311/72 , C07H3/02 , C14C11/00 , A62D101/43
CPC分类号： C14C11/00 , A62D3/37 , A62D2101/43 , C07C39/08 , C07C39/10 , C07C39/14 , C07C69/84 , C07D307/33 , C07D311/72 , C14C3/06 , C14C9/00
摘要： An object of the invention is to provide a heat-resistant hexavalent chromium removal agent, which is capable of remaining in a leather or leather article for a long period of time and stably detoxifying hexavalent chromium over the long term even when a leather or leather article contains hexavalent chromium, and a leather or leather article, in which the hexavalent chromium content is less than 3 ppm. The leather or leather article of the present invention contains at least: an organic compound (A) having a structure shown in chemical formula (1) and hydroxyphenyl but not aldehyde and carboxyl, which organic compound has a property to reduce hexavalent chromium to trivalent chromium; and trivalent chromium, and the hexavalent chromium content determined in accordance with ISO 17075: 2008-02 is less than 3 ppm.
摘要翻译：本发明的一个目的是提供具有耐热性的六价铬去除剂，所有这些是能够保持在相当长的时间周期的皮革或皮革制品和在长期甚至当皮革或皮革制品稳定地解毒的六价铬含有六价铬，和皮革或皮革制品，其中，所述六价铬含量小于3ppm。本发明的皮革或皮革制品至少含有：一种有机化合物（A）在化学式（1）和羟基苯基但不是醛和羧基，其中有机化合物具有属性，以减少六价铬至三价铬具有所示的结构 ; 和三价铬，六价铬和雅舞蹈确定性开采符合ISO 17075的内容：2008-02是小于3ppm。

8. 发明公开

EP1386982A1 PEAK TORQUE LOWERING COMPOSITION, PART WITH SLIDING PART USING THE COMPOSITION, AND PRESS-FITTING METHOD USING THE COMPOSITION 有权
标题翻译： ZUSAMMENSETZUNG ZUR SPITZENDREHMOMENTERNIEDRIGUNG，TEIL MIT GLEITTEIL AUS DIESER ZUSAMMENSETZUNG
公开(公告)号：EP1386982A1
公开(公告)日：2004-02-04
申请号：EP02769213.6
申请日：2002-05-08
申请人： Citizen Watch Co. Ltd.
发明人： AKAO, Yuji , KOIKE, Masayuki
IPC分类号： C23C26/00 , G04B13/02 , F16D7/02
CPC分类号： F16D7/021 , C10M141/10 , C10M2203/0206 , C10M2203/045 , C10M2203/065 , C10M2207/0406 , C10M2207/287 , C10M2207/289 , C10M2223/041 , C10M2223/049 , C10N2230/06 , C10N2240/06 , C10N2250/121 , C23C2/04 , C23C26/00 , C23F11/10 , F16D7/02 , G04B13/023
摘要： The peak-torque descending composition of the present invention contains a certain amount of an extreme pressure agent comprising at least neutral phosphate esters and/or neutral phosphite esters in a solvent comprising hydrocarbons and/or ethers. Further, a certain corrosion inhibitor may be contained. The part having a sliding portion of the present invention is surface-treated with the above composition. The process for producing a component or precision machine having a sliding portion comprises immersing a part having a sliding portion in the above composition to adhere or absorb the composition onto the surface of the part, then immediately, taking out the part from the composition, followed by drying, and subsequently assembling a component or precision machine using the part. The press fit method of the present invention comprises in pressing a metal shaft into a metal plate, preliminarily immersing the metal plate or the metal shaft in the peak-torque descending composition to adhere or absorb the composition onto an inner surface of a hole for press fit of the metal plate or the surface of the shaft, then immediately, taking out the metal plate or the shaft from the composition, and drying.
According to the process for the production of a component or precision machine having a sliding portion of the present invention, the peak-torque descending composition of the invention is used as the surface treating agent, so that the gearwheel body having a slip mechanism which can be made from metallic materials with a simple structure wherein a large peak torque does not produce in an initial stage when slipped and wheel teeth of the gearwheel are not chipped even when the plastic gearwheel is used, can be efficiently produced. According to the present invention, there can be provided a press fit method wherein the occurrence of a burr phenomenon is prevented when the shaft is pressed into the metal plate.
摘要翻译：本发明的峰值扭矩下降组合物含有一定量的极压剂，其在包含烃和/或醚的溶剂中至少包含中性磷酸酯和/或中性亚磷酸酯。此外，可以含有某种腐蚀抑制剂。具有本发明滑动部分的部分用上述组成进行表面处理。用于制造具有滑动部件的部件或精密机器的方法包括将具有滑动部分的部件浸入上述组合物中以将组合物粘附或吸收到部件的表面上，然后立即从组合物中取出部件，随后通过干燥，然后组装使用该部件的部件或精密机器。本发明的压入方法包括将金属轴压入金属板中，将金属板或金属轴预先浸入峰值扭矩下降组合物中以将组合物粘附或吸收到压制孔的内表面上金属板或轴的表面，然后立即从组合物中取出金属板或轴，并干燥。根据本发明的具有滑动部件的部件或精密机械的制造方法，使用本发明的峰值扭矩下降组合物作为表面处理剂，使得齿轮体具有滑动机构可以由具有简单结构的金属材料制成，其中即使当使用塑料齿轮时，在滑动时初始阶段不产生大的峰值扭矩并且齿轮的轮齿也不会碎裂，可以有效地产生。根据本发明，可以提供一种压配合方法，其中当轴被压入金属板时，防止产生毛刺现象。

9. 发明公开

EP1201734A1 LUBRICATING OIL COMPOSITIONS AND WATCH CONTAINING THE SAME 有权
标题翻译：在手表使用的油组合物和观看该组合物
公开(公告)号：EP1201734A1
公开(公告)日：2002-05-02
申请号：EP01904351.2
申请日：2001-02-08
申请人： Citizen Watch Co. Ltd.
发明人： AKAO, Yuji
IPC分类号： C10M169/04 , C10M107/30 , C10M107/02
CPC分类号： C10M169/044 , C10M169/04 , C10M2203/0206 , C10M2205/02 , C10M2205/0206 , C10M2205/022 , C10M2205/026 , C10M2205/0285 , C10M2205/04 , C10M2207/026 , C10M2207/04 , C10M2207/0406 , C10M2207/2825 , C10M2207/2835 , C10M2207/2845 , C10M2207/2865 , C10M2209/062 , C10M2209/084 , C10M2209/086 , C10M2209/102 , C10M2209/1033 , C10M2209/1085 , C10M2215/062 , C10M2215/064 , C10M2215/223 , C10M2219/082 , C10M2223/04 , C10M2223/041 , C10M2223/043 , C10M2223/045 , C10M2223/049 , C10M2223/06 , C10M2229/0415 , C10N2210/02 , C10N2210/06 , C10N2220/022 , C10N2230/00 , C10N2230/02 , C10N2230/06 , C10N2240/06 , G04B31/08 , C10M2205/028
摘要： The first lubricating oil composition of the invention comprises a polyol ester (A) as a base oil, a specific amount of a viscosity index improver (B) and a specific amount of an anti-wear agent (C), and the second lubricating oil composition of the invention comprises a paraffinic hydrocarbon oil (F) having at least 30 carbon atoms and a specific amount of a viscosity index improver (B), so that these compositions exert effects that they enable a life of watch battery to last long, they enable a watch to operate in the temperature range of -30 to 80°C with one kind of a lubricating oil, and they are free from change of properties over a long period of time. The third lubricating oil composition of the invention comprises an ether oil (G) as a base oil, a specific amount of an anti-wear agent (C) comprising a neutral phosphoric ester and/or a neutral phosphorous ester, and an antioxidant (E), so that this composition is free from change of properties over a long period of time and is favorable as a watch lubricating oil. The watch of the invention is a watch having a movable portion for which at least one composition selected from the above compositions is used.
摘要翻译：本发明的第一种润滑油组合物包括多元醇酯（A）作为基油，粘度指数改进剂（B）和抗磨损剂（C）的特定量的特定量，并且所述第二润滑油本发明的组合物包含具有至少30个碳原子和粘度指数改进剂（B）的特定量的链烷烃系烃油（F），所以没合成的组合物发挥的效果thatthey使手表电池的寿命持续很长时间，他们使手表中的温度范围为-30与一种润滑油的操作至80℃，并且它们是从在一段长时间特性变化自由的。醚油的本发明包括的第三种润滑油组合物（G），其为基础油，其包括一个中性磷酸酯和/或中性亚磷酸酯的抗磨损剂（C）的特定量，以及抗氧化剂（E ），所以thatthis组合物是来自的很长一段时间的特性变化自由和是如钟表润滑油有利。本发明的手表是具有针对其使用从上述组合物中的至少一种组合物的可动部分的手表。

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