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1. 发明授权

EP1712520B1 LAYERED POROUS TITANIUM OXIDE, PROCESS FOR PRODUCING THE SAME, AND CATALYST COMPRISING THE SAME 有权
标题翻译： LAYER形多孔氧化钛和工艺用于生产催化剂，该催化剂
公开(公告)号：EP1712520B1
公开(公告)日：2016-05-11
申请号：EP03786319.8
申请日：2003-12-25
申请人： CHIYODA CORPORATION
发明人： INOUE, Shinichi , MUTOU, Akihiro , WADA, Yukitaka , KUDOU, Hidehiko , ONO, Tateo , NOMURA, Hisashi
IPC分类号： C01B13/14 , C01B33/159 , C01F7/02 , C01G23/047 , B01J27/19 , B01J21/06 , B01J35/00 , B01J37/02 , C01G23/053 , C10G45/00
CPC分类号： C01G23/0532 , B01J21/063 , B01J27/19 , B01J35/002 , B01J37/0215 , C01G23/047 , C01G23/0536 , C01P2002/72 , C01P2006/12 , C01P2006/14 , C10G45/00

2. 发明公开

EP2875864A1 METHOD FOR REACTIVATING USED HYDROGENATION TREATMENT TITANIA CATALYST, AND REGENERATED HYDROGENATION TREATMENT TITANIA CATALYST 审中-公开
标题翻译：方法用过的再生钛氧化物的加氢催化剂和氢化催化剂的二氧化钛的再活化
公开(公告)号：EP2875864A1
公开(公告)日：2015-05-27
申请号：EP13819518.5
申请日：2013-05-16
申请人： Chiyoda Corporation
发明人： INOUE, Shinichi , WADA, Yukitaka , MUTOU, Akihiro
IPC分类号： B01J38/48 , B01J27/19 , B01J27/28 , B01J38/12 , B01J38/52 , B01J38/68 , C10G45/08
CPC分类号： B01J38/52 , B01J21/04 , B01J21/063 , B01J21/20 , B01J23/882 , B01J27/19 , B01J27/28 , B01J27/285 , B01J31/38 , B01J31/4053 , B01J38/02 , B01J38/12 , B01J38/48 , B01J38/50 , C10G45/04 , C10G2300/708
摘要： Provided is a method of reactivating a used titania catalyst for hydrogenation treatment, capable of improving the catalytic activity of the used titania catalyst for hydrogenation treatment that is obtained by supporting a catalyst component on a titania support and exhibits reduced catalytic activity after having been used for hydrogenation treatment of a hydrocarbon oil, to a level comparable to that of a newly prepared fresh titania catalyst before use. The method of reactivating a used titania catalyst for hydrogenation treatment, the used titania catalyst for hydrogenation treatment being obtained by supporting a catalyst component on a titania support and exhibiting reduced catalytic activity after having been used for hydrogenation treatment of a hydrocarbon oil, includes: a coke removal step of removing a carbonaceous component on a surface of the used catalyst by heating the catalyst in an oxygen-containing gas atmosphere; an impregnation step of impregnating the carbonaceous component-removed catalyst obtained by the coke removal step with a saccharide-containing solution; and a drying step of drying the saccharide-impregnated catalyst obtained by the impregnation step, to obtain a catalyst in which a saccharide is supported.
摘要翻译：提供被重新激活用于氢化处理用过的二氧化钛催化剂，能够提高使用的二氧化钛催化剂氢化处理的催化活性的并通过在二氧化钛载体和展品负载催化剂成分而得到的方法已经用于后催化活性降低氢化处理的烃油，至与没有使用前新制备的新鲜二氧化钛催化剂的水平。重新激活用于氢化处理用过的二氧化钛催化剂的方法中，用于加氢处理所使用的二氧化钛催化剂通过在二氧化钛载体负载催化剂组分和已经用于加氢处理烃油的后表现出降低的催化活性获得，包括：一除去到含氧气体气氛中加热催化剂使用的催化剂的表面上的碳质成分的除焦步骤; 到浸渍通过用含糖溶液中除去焦炭步骤中获得的碳质成分-除去催化剂的浸渍步骤; 和干燥由所述浸渍步骤中获得的糖 - 浸渍的催化剂的干燥步骤，以获得其中的糖类被支承的催化剂。

3. 发明授权

EP2554260B1 HYDROTREATING CATALYST FOR HYDROCARBON OIL AND METHOD FOR PRODUCING SAME, AND HYDROCARBON OIL HYDROTREATING METHOD USING SAME 有权
标题翻译：烃加氢处理催化剂及其制备方法，以及使用该方法的烃油加氢处理方法
公开(公告)号：EP2554260B1
公开(公告)日：2018-05-02
申请号：EP11762619.2
申请日：2011-03-22
申请人： Chiyoda Corporation
发明人： INOUE, Shinichi , WADA, Yukitaka , MUTOU, Akihiro , ONO, Takeo
IPC分类号： B01J31/34 , B01J35/10 , B01J37/02 , C10G45/08
CPC分类号： B01J31/38 , B01J21/04 , B01J21/063 , B01J23/88 , B01J23/882 , B01J23/883 , B01J27/19 , B01J35/002 , B01J35/0026 , B01J35/0033 , B01J35/1019 , B01J35/1038 , B01J35/1047 , B01J35/1061 , B01J35/1085 , B01J37/0207 , B01J37/0219 , B01J37/0221 , B01J37/06 , C10G45/08
摘要： Provided are: a hydrotreating catalyst for hydrocarbon oil having a hydrodesulfurization activity additionally improved by: simultaneously and continuously adding an aqueous solution of an acidic compound containing titanium and an aqueous solution containing an alkaline compound to a hydrosol containing an alumina hydrate particle at a temperature of 10 to 100°C and a pH of 4.5 to 6.5; washing the resultant to remove a contaminating ion; forming the washed product after dehydration so as to have a moisture content at which it is formable; drying the resultant; impregnating the driedproduct with a catalytic component aqueous solution containing at least one kind of periodic table group 6 metal compound, at least one kind of periodic table group 8-10 metal compound, at least one kind of phosphorus compound, and at least one kind of saccharide; and drying the resultant; a manufacturing method for the catalyst; and a hydrodesulfurization treatment method for hydrocarbon oil using the catalyst.

4. 发明公开

EP1712520A1 LAYERED POROUS TITANIUM OXIDE, PROCESS FOR PRODUCING THE SAME, AND CATALYST COMPRISING THE SAME 有权
标题翻译： SCHICHTFÖRMIGESPORÖSESTITANOXID，HERSTELLUNGSVERFAHRENDAFÜRUND KATALYSATOR DAMIT
公开(公告)号：EP1712520A1
公开(公告)日：2006-10-18
申请号：EP03786319.8
申请日：2003-12-25
申请人： CHIYODA CORPORATION
发明人： INOUE, Shinichi , MUTOU, Akihiro , WADA, Yukitaka , KUDOU, Hidehiko , ONO, Tateo , NOMURA, Hisashi
IPC分类号： C01B13/14 , C01B33/159 , C01F7/02 , C01G23/047 , B01J27/19
CPC分类号： C01G23/0532 , B01J21/063 , B01J27/19 , B01J35/002 , B01J37/0215 , C01G23/047 , C01G23/0536 , C01P2002/72 , C01P2006/12 , C01P2006/14 , C10G45/00
摘要： This invention provides layered porous titanium oxide comprising an inorganic oxide as a core and titanium oxide deposited on the surface of the inorganic oxide, wherein the titanium localization index B/A represented by the ratio of the proportion of titanium (Ti) to the sum of the constituent metal (M) of the inorganic oxide and titanium (Ti) determined by X-ray photoelectron spectroscopy (XPS) [B = Ti XPS /(Ti XPS + M XPS )] to the bulk mixing molar ratio of titanium (Ti) to the sum of the constituent metal (M) of the inorganic oxide and titanium (Ti) [A = Ti/(Ti + M)] is 1.6 or more and the titanium oxide is deposited on the surface of the inorganic oxide so as to be chemically and/or microscopically united to the inorganic oxide and also provides a process for producing the same and a catalyst comprising the same. The layered porous titanium oxide of this invention has a regulated pore structure, a large specific surface area, and excellent mechanical strength and is useful as a catalyst or a catalyst carrier.
摘要翻译：本发明提供了以无机氧化物为芯和沉积在无机氧化物表面上的氧化钛的层状多孔氧化钛，其中钛定位指数B / A以钛（Ti）的比例与钛无机氧化物的组成金属（M）和通过X射线光电子能谱（XPS）[B = Ti XPS /（Ti XPS + M XPS）]测定的钛（Ti）与钛（Ti）的体积混合摩尔比相对于无机氧化物的组成金属（M）和钛（Ti）[A = Ti /（Ti + M）]的组成金属的总和为1.6以上，氧化钛沉积在无机氧化物的表面上，在化学和/或显微镜下与无机氧化物结合，并提供其制备方法和包含该方法的催化剂。本发明的层状多孔氧化钛具有调节的孔结构，大的比表面积和优异的机械强度，并且可用作催化剂或催化剂载体。

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