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    • 3. 发明公开
    • Two-component type developer and image forming method
    • Zwei-Komponenten-Entwickler und Bildherstellungsverfahren
    • EP0999478A1
    • 2000-05-10
    • EP99122164.9
    • 1999-11-05
    • CANON KABUSHIKI KAISHA
    • Okado, KenjiFujita, RyoichiMikuriya, YushiYachi, ShinyaYoshizaki, Kazumi
    • G03G9/107G03G9/113
    • G03G9/097G03G9/0819G03G9/10G03G9/107G03G9/113
    • A two-component type developer has a negatively chargeable toner having toner particles and an external additive and a magnetic-fine-particle-dispersed resin carrier. The magnetic-fine-particle-dispersed resin carrier has composite particles containing at least inorganic compound particles and a binder resin. The inorganic compound particles have been surface-treated with a lipophilic-treating agent having at least one type of functional group (A) selected from the group consisting of an epoxy group, an amino group, a mercapto group, an organic acid group, an ester group, a ketone group, an alkyl halide group and an aldehyde group, or a mixture of the agent. The composite particles have been surface-coated with at least one type of coupling agent having at least one type of functional group (B) different from the functional group (A) the lipophilic-treating agent. The functional group (B) the coupling agent has being a functional group or groups selected from the group consisting of an epoxy group, an amino group and a mercapto group. The negatively chargeable toner has a weight-average particle diameter of from 3 µm to 9 µm.
    • 双组分型显影剂具有带负电荷的调色剂,其具有调色剂颗粒和外部添加剂和磁性微粒分散树脂载体。 磁性粒子分散树脂载体具有至少含有无机化合物粒子和粘合剂树脂的复合粒子。 无机化合物颗粒已经用具有至少一种选自环氧基,氨基,巯基,有机酸基,官能团(A)的官能团(A)的亲脂性处理剂进行表面处理 酯基,酮基,烷基卤基和醛基,或者该试剂的混合物。 所述复合颗粒已经用至少一种具有至少一种类型的与所述亲脂性处理剂的官能团(A)不同的官能团(B)的偶联剂进行表面涂覆。 官能团(B)偶联剂是选自环氧基,氨基和巯基的官能团或基团。 带负电荷的调色剂的重均粒径为3μm〜9μm。
    • 9. 发明公开
    • Toner
    • 爽肤水
    • EP2378364A1
    • 2011-10-19
    • EP11002636.6
    • 2011-03-30
    • Canon Kabushiki Kaisha
    • Kaneko, HidekiYachi, ShinyaNakayama, KenichiKaburagi, TakeshiKuroki, Shiro
    • G03G9/08G03G9/087
    • G03G9/0802G03G9/0821G03G9/08708G03G9/08711G03G9/08793G03G9/08795G03G9/08797
    • A toner includes toner particles each containing a binder resin, a colorant, and a carboxy-containing styrene-based resin, in which the toner particles are produced in an aqueous medium, each of the toner particles has a styrene-acrylic-based resin component content of 50.0% by mass or more, cyclohexane-insoluble matter A obtained by subjecting the toner to Soxhlet extraction with cyclohexane for 4 hours is 70.0% by mass or more, and cyclohexane-insoluble matter B obtained by subjecting the toner to Soxhlet extraction with cyclohexane for 24 hours is 40.0% by mass or less, and wherein when the z-average molecular weight and the weight-average molecular weight of tetrahydrofuran-soluble matter of the carboxy-containing styrene-based resin determined by gel permeation chromatography measurement are represented by Mz and Mw, respectively, Mz and Mw satisfy the following expressions:
      10,000 ≤ Mw ≤ 30,000, and
      1.62 ≤ Mz/Mw ≤ 5.00.
    • 调色剂包括各自含有粘合剂树脂,着色剂和含羧基的苯乙烯基树脂的调色剂颗粒,其中调色剂颗粒在水性介质中制备,每个调色剂颗粒具有苯乙烯 - 丙烯酸类树脂组分 含量为50.0质量%以上的环己烷不溶物质A为70.0质量%以上,环己烷不溶性物质A为70.0质量%以上,通过将调色剂进行索格利特萃取而得到的环己烷不溶性物质A, 环己烷24小时为40.0质量%以下,并且当通过凝胶渗透色谱测量确定的含羧基苯乙烯基树脂的四氢呋喃可溶物质的平均分子量和重均分子量表示时 分别为Mz和Mw,Mz和Mw满足以下表达式:10,000‰¤Mw‰³30,000,¤。¤¤¤¤¤¤¤¤¤¤¤¤¤¤¤¤¤¤¤¤